The invention relates to a process method for producing
phenol by selectively oxidizing
benzene through
nitrous oxide, comprising the following steps of: placing a Fe-ZSM-5
molecular sieve catalyst on a distribution plate inside a fixed
fluidized bed reactor; firstly activating the Fe-ZSM-5
molecular sieve catalyst by using
helium at 400-600 DEG C; then introducing a gas containing the
nitrous oxide and the
benzene from the lower end inside the fixed
fluidized bed reactor at normal pressure; controlling the reaction gas velocity of the gas between 0.040m / s and 0.072m / s through the gas distribution plate so that catalyst granules contact with the gas in a suspended state in the fixed
fluidized bed reactor to carry out
continuous reaction at the temperature between 300 DEG C and 500 DEG C and the normal pressure, wherein the mol ratio of the
raw material benzene / N2O is between 4 and 16; and condensing and separating reaction products to obtain the
phenol. The invention enables the Fe-ZSM-5
molecular sieve catalyst to contact with reaction fluids in the suspended state by utilizing the fixed fluidized
bed reactor, therefore sliding velocity higher than terminal granule velocity exists between the gas and a
solid; and in addition, the invention not only has very high contact efficiency, but also is beneficial to carrying out
mass transfer between the gas and the
solid and desorbing a product, i.e. the
phenol, thereby alleviating the coking deactivation of the Fe-ZSM-5 molecular
sieve catalyst.