The invention relates to a compound
potassium lead borophosphate
nonlinear optical crystal as well as a preparation method and application thereof. The compound has the
chemical formula of KPbBP2O8. The preparation method comprises the following steps of: after uniformly mixing a
raw material containing K, Pb, B and P by adopting a
solid-
phase reaction method, heating for carrying out
solid-
phase reaction to obtain a compound of the
potassium lead borophosphate; and growing a
crystal on the compound by adopting a melt method to obtain the
potassium lead borophosphate
nonlinear optical crystal. The compound is the
centimeter-grade
large size nonlinear optical crystal of a
tetragonal crystal system; a
space group is I-42d;
cell parameters comprise a=7.1764(7), b=7.1764(7), c=13.9483(13), Z=4 and V=718.35; the
powder frequency doubling effect of the compound is equivalent to that of KDP (
Potassium Dihydrogen
Phosphate); the Mohs
hardness is 4 to 5; and the potassium lead borophosphate
nonlinear optical crystal has the advantages of easy
cutting,
polishing processing and storage, no deliquescence, high preparation speed, simple operation, low cost, good mechanical performance, difficult
cracking, stable physicochemical property, and the like and is suitable for manufacturing an nonlinear optical device.