The invention discloses a gas-liquid mixed extraction
iodine recovery technology. According to the invention,
phosphate rock is soaked in
sulfuric acid, and
iodine-containing dilute
phosphoric acid is obtained; an
oxidizing agent is added into the dilute
phosphoric acid, such that gas-phase
iodine is obtained; the gas-phase iodine is subjected to a reaction with a
reducing agent, such that iodine is precipitated. The invention is characterized in that: iodine-containing dilute
phosphoric acid obtained by the reaction of
phosphate rock and
sulfuric acid and iodine-containing
exhaust gas are simultaneously delivered into and sufficiently mixed in a gas-liquid mixed extraction integral iodine
recovery apparatus; the
oxidizing agent is added and a reaction is carried out, such that iodine molecules are obtained; the
reducing agent is added under a condition of a controlled temperature, such that a concentrated iodine liquid is obtained; two-stage clarification,
precipitation,
filtration, and rectification purification are carried out, such that finished product iodine is obtained. The technology provided by the invention makes up for the defects of a method for extracting iodine from wastes produced in the process for producing
phosphorus products from iodine-containing
phosphorite. With the technology, iodine in iodine-containing dilute phosphoric acid and iodine-containing
exhaust gas can be recovered simultaneously. Through two-stage clarification, defluoridation is realized, and floccule and impurities are removed, such that the purity of iodine is improved. The technology is also advantaged in simple technology, high
recovery rate, and low economic cost. With the technology, iodine-containing
exhaust gas can be fully utilized, and the
pollution of
tail-gas discharging to the environment can be reduced.