A bathing agent in thermal spring and preparation thereof are composed of (by weight) 3-25 % of sodium hydroxide, 3-25 % of sodium silicate, 3-25 % of potassium hydroxide, 2-25 % of sodium bicarbonate, 11-55 % of sublimed sulfur, 0.5-6 % of essential oil which is one or more than one kinds of lemon, jasmine, lavandula angustifolia, mint, sweet osmanthus etc. The process is that, 3-25 % of sodium hydroxide, sodium silicate, potassium hydroxide are added with 2.75-13.75 % of sublimed sulfur, mixed and reacted to molten state at 60-180 degree centigrade, then added with 0.5-6 % of essential oil and 8.25-41.25 % of sublimed sulfur, stirred to form grain or block, pressed into tablet. When dissolved in water, said bathing agent can combine with oxygen and carbon dioxide in water and air to resolve sodium hyposulfite, carbonate, sulfate etc. with function of skin beautifying, dissipating fatigue, and relieving itching and steriling.