The invention discloses a preparation method of highly-waterproof water-soluble
polyurethane resin. The method comprises the following steps: heating terephthalic anhydride
polyester diol and poly(1,4-
cyclohexanedimethanol adipate)
diol for melting, carrying out heat insulation, and carrying out vacuum
dehydration to obtain a material a; adding tetramethyl phenyldimethylene diisocyanate to the material a, heating, carrying out heat insulation, cooling, adding 1,5-pentanediol,
melamine-
formaldehyde resin and N-methyl pyrrolidone, adding
cobalt octoate, heating, and carrying out heat insulation to obtain a material b; cooling the material b, adding a N-propyldiethanolamine and bis(2-hydroxyethyl)
aniline mixed solution in a dropwise manner, heating, and carrying out heat insulation to obtain a material c; and adding propionic acid to the material c to neutralize, and carrying out
vacuum distillation to obtain the highly-waterproof water-soluble
polyurethane resin. The invention also discloses the highly-waterproof water-soluble
polyurethane resin. The highly-waterproof water-soluble polyurethane resin has excellent waterproof property and
hardness, and the method is stable and is easy to control.