49results about How to "Reaction process cleaning" patented technology

The novel process of hydrogenating benzoic acid to synthesize cyclohexyl formic acid includes the catalytic cyclization reaction of benzoic acid via contact with hydrogen inside supercritical CO2 and cyclohexyl formic acid without solvent in the presence of metal rhodium catalyst and under mild reaction condition; and subsequent extraction to separate product from the catalyst by means of the dissolubility of cyclohexyl formic acid in supercritical CO2. The technological process of the present invention has the advantages of mild reaction condition, clean reaction process, no side product and waste, no need of post-separation, and high product yield and quality.

The invention discloses a method for preparing benzaldehyde by catalytically oxidizing phenylcarbinol through Pt / BiOCl-metal oxide serving as a catalyst. The method comprises the following steps: by taking a noble metal Pt / BiOCl-metal oxide compound system as the catalyst, dispersing phenylcarbinol and the catalyst into water, and continuously stirring under a relatively low-temperature dark condition for 3 to 10 hours, wherein the generation selectivity of the benzaldehyde can be 99 percent or above, and the yield of the benzaldehyde is retained within a range of 80 to 100 percent according to different types of carriers. The method has the following active effects that 1, the reaction can be carried out at relatively low temperature, such as room temperature of 25 DEG C; 2, low-cost air is used as an oxidant, so that the problem of environmental pollution caused by the fact that a high-cost metal such as chromium and manganese is used as the oxidant is solved; 3, no alkaline substances serving as an auxiliary catalyst are added into a reaction system; 4, basically no side effect is caused in a reaction process, and the generation selectivity of the benzaldehyde is retained at 99 percent or above; 5, equipment devices for reaction and an operation process are simple.

A catalyst carrying ionic liquid and metallic nanoparticles for preparing high-quality arylamine by hydrocatalyzing aromatic nitro compound is prepared through preparing immobilized ionic liquid by bonding the ionic liquid onto carrier, binding it with the active component containing transition metal or precursor, and reductive exchange. Its advantages are low reaction temp, long service life andno waste generation.