The invention relates to a material for preventing freezing damage on the surface of concrete products, which is made of hydroxyl silicone oil, γ-aminopropyltriethoxysilane, crosslinking agent, hexamethyldisilazane and dibutyltin dilaurate to make. Add hydroxyl silicone oil, γ‑aminopropyltriethoxysilane, and crosslinking agent into the reaction kettle in sequence, start stirring, heat up, open the vacuum valve, start vacuuming, and then add hexamethyldisilazane and di Add butyl tin dilaurate into the reaction kettle in turn, continue the vacuum reaction, and finally put the product in cans and store it sealed under the protection of nitrogen to obtain the material for preventing freezing damage on the surface of finished concrete products. The material has small molecular weight, strong permeability, and can maintain good elasticity in the temperature range of 50°C-200°C. It has excellent weather aging resistance, high and low temperature resistance, and can improve the weather resistance of concrete products. When in use, the material is sprayed or painted on the surface of concrete products, which can effectively improve the anti-freeze damage performance of the surface of concrete products.