58results about How to "High double bond retention" patented technology

The invention discloses a mud-proof slump-retaining type polycarboxylate superplasticizer with low shrinkage and high adaptability and a low-temperature preparation method thereof. The polycarboxylatesuperplasticizer is mainly prepared by the following steps: carrying out free radical polymerization on 4-hydroxybutylvinyl polyoxyethylene ether, unsaturated carboxylic acid, an unsaturated amide-type monomer, dipolyethylene glycol maleate, an unsaturated quaternary ammonium cationic monomer, an oxidizing agent, a catalyst, a reducing agent, a chain transfer agent and deionized water at 5-15 DEGC through an aqueous solution, regulating pH value by adding a sodium hydroxide solution, and supplementing water. The preparation method of the invention has advantages of low-temperature production, no heat source, simple equipment, no pollution, short reaction time and high production efficiency. The prepared mud-proof slump-retaining type polycarboxylate superplasticizer endows concrete withgood workability, good adaptability, low shrinkage and high strength, has excellent mud-proof slump-retaining property, and greatly reduces construction difficulty.

The invention discloses a synthesis method of methyl allyl alcohol polyethenoxy ether, which comprises the following steps: 1) reacting 5-20 wt% of prescribed methyl allyl alcohol and a catalyst, adding the reaction product into residual prescribed methyl allyl alcohol, and introducing epoxyethane to react, thereby obtaining methyl allyl alcohol polyethenoxy ether low polymer; and 2) reacting 5-20 wt% of prescribed methyl allyl alcohol polyethenoxy ether low polymer obtained in the step 1) and a catalyst, adding the reaction product into residual prescribed methyl allyl alcohol polyethenoxy ether low polymer, and introducing epoxyethane to react, thereby obtaining the methyl allyl alcohol polyethenoxy ether. The methyl allyl alcohol polyethenoxy ether product prepared by the method disclosed by the invention has the advantages of low content of byproducts (polyethyleneglycol and the like), narrow molecular weight distribution, high double-bond protective rate and the like, and is suitable for synthesizing polycarboxylic-acid high-performance water reducing agents.

The invention discloses a preparation method of a low-hydration-heat polycarboxylate water reducing agent. Unsaturated carboxylic acid or unsaturated carboxylic acid anhydride performs acidylation andesterification with alcohol amine and a compound A to simultaneously prepare unsaturated monomers with acidamide groups, unsaturated monomers with amino groups and unsaturated monomers with benzene rings and phosphate groups; then, co-polymerization is performed by excessive unsaturated carboxylic acid or unsaturated carboxylic acid anhydride, unsaturated sulphonate and polyether big monomers during acidylation and esterification; acylamide groups, amino groups, phosphate groups, carboxylate groups, sulphonate groups, polyether lateral chains and benzene rings are introduced into molecular structures, so that the product has a high initial water reducing rate. The molecular structures of the water reducing agent prepared by the preparation method comprise ester groups, phenyls and phosphate groups; the ester groups hydrolyze under the basic condition of the concrete; carboxyls with the water reducing function and hydroxy phenyl phosphate groups with the hydration heat reducing function are gradually released; the concrete hydration heat can be effectively reduced.

The invention discloses slow-release collapse-preventing type polycarboxylic water reducing agent and a preparation method thereof, and belongs to the field of preparation of the water reducing agent. The slow-release collapse-preventing type polycarboxylic water reducing agent consists of methyl allyl polyoxyethylene ether, acrylic acid, methyl acrylic polyethylene glycol monoester, imide, initiator, vitamin C, chain transfer agent and deionized water. The preparation method comprises the following steps of: preparing macromonomer methyl allyl polyoxyethylene ether, acrylic acid, methyl acrylic polyethylene glycol monoester, imide and vitamin C; under the action of the polymerization initiator and the chain transfer agent, dissolving the methyl allyl polyoxyethylene ether into deionized water, rising temperature to 40 DEG C for dissolving, adding the initiator, then respectively dripping water solution A prepared by dissolving the chain transfer agent, the acrylic acid, the methyl acrylic polyethylene glycol monoester and the imide in the deionized water and V.C water solution B, and after the dripping is finished, carrying out insulation, cooling and neutralization to obtain a finished product. The slow-release collapse-preventing type polycarboxylic water reducing agent disclosed by the invention has the advantages that the loss and the evaporation of water in concrete due to long-time transportation and higher temperature are effectively prevented, and the difficulty of excessively-fast slump loss of the concrete in engineering is solved.

The invention provides terminal alkenyl nonsaturated polyether shown in a formula (1), and the invention also provides a purpose of the terminal alkenyl nonsaturated polyether. According to the provided terminal alkenyl nonsaturated polyether, a polyether chain segment can be adjusted through different structural units, so that dispersion effect of a prepared water reducer on concrete is increased, and water-reducing rate of a polycarboxylic acid water reducer and slump constant are obviously increased. The preparation method has the advantages of simple operation, mild condition and easy industrial application.

The invention relates to a synthesis method of 4- hydroxybutyl vinyl ether polyoxyethylene ether, and belongs to the technical field of polyether compound synthesis in organic chemistry. The synthesis method comprises two phases, namely a primary synthesis phase and a final synthesis phase, and specifically comprises the following steps: subjecting a part of 4-hydroxybutyl vinyl ether to a pre-reaction with a primary synthesis catalyst, adding the pre-reaction product into the rest part of 4-hydroxybutyl vinyl ether, introducing ethylene oxide to carry out primary synthesis so as to obtain a primary product, adding a final synthesis catalyst into a part of the primary product to carry out a secondary pre-reaction, and subjecting the secondary pre-reaction product to final synthesis reactions with the rest part of the primary product and ethylene oxide so as to obtain the final product. The product obtained by the technical scheme provided by the invention has the advantages of low by-product content, narrow molecular weight distribution, and high double-bond protection rate.

The invention discloses a low-sensitivity anti-mud ether-ester copolymerized polycarboxylic acid water reducing agent and a preparation method thereof. The pH value is 6.0-6.5, and the solid content is 45-55%. The pH value is 6.0-7.0, and the solid content is 45-55%. The water reducing agent is composed of the following components in parts by weight: 10-100 parts of 4-hydroxybutylvinyl polyoxyvinyl ether with the molecular weight of 2000-5000, 10-100 parts of methoxypolyethylene glycol methacrylate, 6-10 parts of unsaturated monocarboxylic acid, 3-6 parts of unsaturated carboxylate monomer, 2-5 parts of dibutyl itaconate, 1-5 parts of unsaturated amphoteric quaternary alkylphosphonium salt, 0.2-0.8 part of oxidizer, 0.2-1.0 part of first reducer, 0.02-0.06 part of second reducer, 0.2-0.6 part of chain-transfer agent, a right amount of potassium hydroxide water solution, a right amount of sodium hydroxide water solution and a right amount of deionized water. The polycarboxylic acid water reducing agent has the advantages of more uniform side chain distribution and favorable slump retaining effect, and has excellent low sensitivity to the doping amount changes.

The invention discloses a low-sensitivity anti-mud polycarboxylic acid water reducing agent and a preparation method thereof. The pH value is 6.0-6.5, and the solid content is 45-55%. The water reducing agent is composed of the following components in parts by weight: 90-130 parts of 4-hydroxybutylvinyl polyoxyvinyl ether with the molecular weight of 2000-5000, 6-10 parts of unsaturated monocarboxylic acid, 3-6 parts of unsaturated carboxylate monomer, 1-5 parts of unsaturated amphoteric quaternary alkylphosphonium salt, 0.2-0.8 part of oxidizer, 0.2-1.0 part of reducer, 0.02-0.06 part of catalyst, 0.2-0.6 part of chain-transfer agent, a right amount of potassium hydroxide water solution, a right amount of sodium hydroxide water solution and a right amount of deionized water. The polycarboxylic acid water reducing agent has the advantages of more uniform side chain distribution and favorable slump retaining effect, and has excellent low sensitivity to the doping amount changes.

The invention discloses anacardol polyoxyethylene ether and a preparation method of the anacardol polyoxyethylene ether. A prepared anacardol polyoxyethylene ether product is made to have the advantage of being high in double-bond protection rate, and therefore good using performance is achieved. The preparation method comprises the following steps that 1) anacardol is put in a reaction still, and a catalyzer is controlled to be added to react within certain time and reaction temperature; 2) after the reaction of the step 1) is finished, nitrogen is adopted to displace air in the reaction still in the step 1), reaction temperature and pressure is controlled, and ethylene oxide is guided to react; 3) after materials obtained after the reaction of the step 2) is finished are cooled to be certain temperature, acetic acid is added to the materials to neutralize the materials, kieselguhr is added, filtration is carried out, and the anacardol polyoxyethylene ether is prepared.

The invention relates to methylallyl alcohol random polyether and a preparation method thereof, and belongs to polyether compound synthesis in organic chemistry. The method comprises the following steps: firstly, ensuring methylallyl alcohol with the prescription dosage being 5 to 20 percent to be reacted with a catalyst I, putting the methylallyl alcohol into the rest methylallyl alcohol, leading ethylene oxide and propene oxide mixed according to a specific ration into the methylallyl alcohol, and obtaining methylallyl alcohol random polyether low polymer with the molecular weight being 400 to 1000 after reaction; secondly, enabling 5 to 20 percent of methylallyl alcohol random polyether low polymer obtained in the first step to be reacted with a catalyst II, putting the methylallyl alcohol random polyether low polymer into the rest methylallyl alcohol random polyether low polymer, feeding ethylene oxide and propene oxide mixed according to a specific ration into the methylallyl alcohol random polyether low polymer, and obtaining methylallyl alcohol random polyether with the molecular weight being M after reaction. The methylallyl alcohol random polyether is applied to the synthesis of a polycarboxylate superplasticizer to be applied to a concrete additive, and has the advantages of good cement dispersity and good solubility with other compounds.

The invention relates to a polycarboxylate water reducer and specifically relates to a preparation method of polycarboxylate water reducer macromonomer methallyl alcohol polyoxyethylene ether. The method comprises the following steps: performing condensation reaction with ethylene oxide by taking lithium aluminum tetrahydride as a catalyst and taking an intermediate product obtained by reaction of methallyl alcohol and lithium aluminum tetrahydride and methallyl alcohol as raw materials to obtain a methallyl alcohol oligomer, further enabling the methallyl alcohol oligomer to perform condensation reaction with the added ethylene oxide under the action of an alkaline catalyst, terminating with propylene oxide, and adding glacial acetic acid to neutralize to obtain methallyl alcohol polyoxyethylene ether. The preparation method provided by the invention has the advantages of simple process, safety, low reaction temperature, short reaction time and low production cost; and obtained methallyl alcohol polyoxyethylene ether has narrow distribution of relative molecular weight and high retention rate of double bonds.

The invention relates to a synthetic method of cumenyl polyoxyethylene ether and belongs to the technical field of organic compound synthesis. Isopropenyl cumenol and ethylene oxide are adopted as raw materials. The method includes reacting 5-20% by weight of the isopropenyl cumenol with a first catalyst, adding the reaction product into the rest of the isopropenyl cumenol, adding the ethylene oxide, reacting to prepare a cumenyl polyoxyethylene ether oligomer, reacting 5-20% by weight of the cumenyl polyoxyethylene ether oligomer with a second catalyst, adding the reaction product to the rest of the cumenyl polyoxyethylene ether oligomer, adding the ethylene oxide, and reacting to prepare the cumenyl polyoxyethylene ether. The cumenyl polyoxyethylene ether prepared by the method has advantages of low contents of byproducts such as polyethylene glycol, narrow molecular weight distribution, high double-bond protection rates, and the like, and is suitable for synthesis of high-performance polycarboxylate-type water reducing agents.

The invention discloses double-branch allylamine polyethenoxy ether and a synthetic method thereof. The double-branch allylamine polyethenoxy ether is synthesized from the following raw materials in mole ratio through two steps: allylamine and epoxyethane in a mole ratio of 1:(4-100), and a catalyst which accounts for 0.08-0.2% of the total mass of allylamine and epoxyethane. The double-branch allylamine polyethenoxy ether obtained by the method disclosed by the invention is high in double-bond retention rate under a reaction condition, and can be directly applied to synthesis of a polycarboxylate superplasticizer; and a two-step method is adopted, and a water removal step is increased, so that the content of a reaction byproduct namely polyethylene glycol is reduced.

A highly-adaptive ultra-slow-release type polycarboxylate slump retaining admixture and a preparation method thereof are disclosed. The method includes an esterification step, namely a step of reacting methacrylic acid, a saturated acid and 3-bis(2-hydroxyethyl)amino-2-hydroxy propanesulfonic acid under the existence of a catalyst to obtain an unsaturated esterified small monomer; (2) subjecting 4-butanediol vinyl ether polyoxyethylene ether as a macromonomer to copolymerization under the action of a composite photoinitiator; and (3) neutralizing the obtained copolymerization product with a sodium hydroxide solution to obtain the slump retaining admixture. The prepared slump retaining admixture has good slump retaining capability at high temperature for long time, has certain anti-mud effects and has good adaptability to mud-containing ground materials.

The invention discloses a reactive emulsifier for emulsion polymerization, a preparation method and application thereof. The reactive emulsifier includes the compound(s) shown as formula (I) and / or formula (II) in the specification. The preparation method includes: carrying out ring-opening reaction on fatty primary amine and a glycidyl ether compound with unsaturated double bond, then conducting alkoxylation on the product to obtain a nonionic reactive emulsifier with a reactive double bond and an anionic reactive emulsifier derived therefrom. The emulsifier provided by the invention employs the reaction of primary amino and the glycidyl ether compound to introduce the double bond, the reaction activity and selectivity are stronger, and the reaction conditions are milder, the double bond loss in the reaction can be reduced, and the reactive double bond content of the final emulsifier product can be increased. In the process of emulsion polymerization, the emulsifier has higher reactivity with monomers, and can improve the water resistance of emulsion products more effectively.

The invention discloses a preparation method of isopentenol polyoxyethylene ether. The method comprises the steps of: 1) firstly reacting 5-20wt% of prescribed dosage isopentenol with a catalyst, then putting the product into the remaining prescribed dosage isoprene, and introducing ethylene oxide to react so as to obtain an isopentenol polyoxyethylene ether oligomer with a molecular weight of 300-500; 2) reacting the prepared 5-20wt% of prescribed dosage isopentenol polyoxyethylene ether oligomer with the catalyst, then putting the product into the remaining prescribed dosage isopentenol polyoxyethylene ether oligomer, and introducing ethylene oxide to react so as to obtain isopentenol polyoxyethylene ether with a molecular weight of 500-5000. The product prepared by the invention has the advantages of low content of polyethylene glycol and other by-products, narrow molecular weight distribution, and high double bond protection rate, and is suitable for synthesis of polycarboxylate type high performance water reducing agents.

The invention provides a macromer for preparing polycarboxylic acid water-reducer and a preparation method thereof. The macromer is synthesized by the reaction of 2-(vinyloxy)ethanol and epoxyethane as main materials. The macromer has simple molecular structure, the production process is safe and steady, and the cost is low; the reactivity is high and the conditions is easily controlled when the macromer is used for preparing polycarboxylic acid water-reducer, the obtained polycarboxylic acid water-reducer has high performance and performance and price ratio.

The invention discloses a dialkylene amine polyether and a preparation method and application thereof. The dialkylene amine polyether is expressed by adopting the following structural formula (1), (img file= 'DSA0000101280160000011.tif' wi= '1420' he= '274' / ), wherein R1 and R2 are alkenyl of which the carbon number is 3-10; m is greater than 1; n is greater than or equal to 0; q is greater than or equal to 0. The dialkylene amine polyether provided by the invention has two unsaturated chain segments and good polymerization activity, and can be applied to synthesis of polymer dispersant and polycarboxylate high-performance water-reducing admixture products, and the dispersibility of each product can be improved. The dialkylene amine polyether provided by the invention is simple in preparation method, easy to control condition, stable and safe in reaction, high in productivity, free of use of an organic solvent, and free of generation of a harmful substance to a human body, and environmental pollution is avoided. Application of the dialkylene amine polyether in synthesis of an industrial high-molecular polymer is also provided by the invention.

The invention relates to a polycarboxylic acid water reducer, and concretely relates to a preparation method of a polycarboxylic acid water reducer macromonomer ethylene glycol monovinyl polyoxyethylene ether. The method comprises the following steps: reacting ethylene glycol monovinyl ether with lithium aluminum hydride to obtain a catalyst, carrying out a condensation reaction on the ethylene glycol monovinyl ether and ethylene oxide under the action of the catalyst to obtain an ethylene glycol monovinyl ether oligomer, carrying out a condensation reaction on the ethylene glycol monovinyl ether oligomer and ethylene oxide under the action of an alkaline catalyst, performing termination with epoxypropane, and adding glacial acetic acid to neutralize in order to obtain the ethylene glycolmonovinyl polyoxyethylene ether. The ethylene glycol monovinyl polyoxyethylene ether obtained in the invention has the advantages of narrow relative molecular weight distribution, high double-bond reservation rate, simple process, safety, low reaction temperature, short reaction time and low production cost.

The invention discloses a preparation method for methyl alkenyl polyoxyethylene polyoxypropylene ether with high polymerization degree and macromonomer. The preparation method includes the following steps: 1) utilizing methyl alkenyl alcohol as a starting agent, adding ethylene oxide in the presence of a basic catalyst to carry out a condensation reaction, and performing curing at a maintained temperature after full introduction to obtain a methyl alkenyl alcohol polyoxyethylene ether oligomer; 2) adding the basic catalyst to the oligomer obtained in the step 1), adding propylene oxide for performing the condensation reaction, and performing the curing at the maintained temperature after the full introduction; and 3) continuing to introduce the ethylene oxide in a reactor for performing the condensation reaction until no pressure in the reactor, and then adding acetic acids for performing neutralization to obtain methyl alkenyl alcohol polyoxyethylene polyoxypropylene ether. Synthesisof the methyl alkenyl polyoxyethylene polyoxypropylene ether with the high degree of polymerization and the macromonomer is performed in two steps, the mass growth ratio is up to 1:100, a product is high in degree of polymerization and is high in reactivity, and a synthetic polycarboxylate-type water reducing agent is excellent in slump loss resistant property and comprehensive performance.

The present invention provides a hydrogenated reactive emulsifier with excellent stability and water resistance, and a preparation method and application thereof, the side chain of hydrogenated cardanol or hydrogenated cardanol polyether contains no double bonds, and the reactivity is mild. The reactive emulsifier is a compound comprising the structure shown as a formula (I) in the description. The hydrogenated reactive emulsifier with excellent stability and water resistance provided by the invention can react with polymerized monomers more effectively, so that an obtained polymer emulsion has excellent stability and film-forming and water resistance.

The invention provides quaternary phosphonium salt with a structural formula shown by formula I. The invention also provides application of the quaternary phosphonium salt as a reaction catalyst for preparing an amide / imide type polycarboxylic acid macromonomer. The quaternary phosphonium salt provided by the invention has the advantages of novel structure, large conjugate area, strong alkalinity (pKa=40-45) and high catalytic activity and applicability; the preparation method is simple and feasible, and a water carrying agent and a polymerization inhibitor are not needed in the reaction process; and moreover, the cost and energy consumption are low, and the method is environment-friendly and clean and has a prospect in industrial application.

The invention discloses integrated styrene acrylic latex, a preparation method and an application. The integrated styrene acrylic latex comprises, in weight percent, 10-40% of vinyl benzene, 8-30% ofalkyl methacrylate, 1-5% of allyl polyether macromonomers, 1-10% of functional water-soluble monomers, 1-5% of anionic emulsifiers, 0.5-2% of non-ionic emulsifiers, 0.1-2% of crosslinking agents, 0.05-2% of chain transfer agents, 0.5-3% of initiators and the rest deionized water. The integrated styrene acrylic latex is used without additionally combining stabilizing agents, the cementation strength between a first cementation plane and a second cementation plane of well cementation can be improved, the penetration rate of cement stones is reduced, hydrocarbon channeling is decreased, the elastic toughness of the cement stones can be increased, cracking degree of the cement stones is reduced in well cementing follow-up operations such as perforation and pressing crack, overall stability ofa cement ring is kept, and well cementation quality is improved.

The invention discloses a polyether macromonomer synthesis method, a polyether macromonomer and application, and belongs to the technical field of chemical raw material processing. The synthesis method of the polyether macromonomer has the advantages of low byproduct content, narrow molecular weight distribution, high double bond retention rate, large relative molecular weight and low potassium and sodium ion content. The molecular weight distribution coefficient of the polyether macromonomer obtained by the synthesis method is less than 1.03, and the double bond retention rate is greater than 98.6%. The polyether macromonomer has large relative molecular weight, can enable the polycarboxylic acid water reducing agent to form large steric hindrance, increases the water reducing rate and slump retaining property, and greatly improves the performance of the water reducing agent; potassium and sodium ions reach below 10ppm; the compressive strength ratio of the synthesized polycarboxylate superplasticizer is better.

The invention discloses a preparation method of a low-hydration-heat polycarboxylate water reducing agent. Unsaturated carboxylic acid or unsaturated carboxylic acid anhydride performs acidylation andesterification with alcohol amine and a compound A to simultaneously prepare unsaturated monomers with acidamide groups, unsaturated monomers with amino groups and unsaturated monomers with benzene rings and phosphate groups; then, co-polymerization is performed by excessive unsaturated carboxylic acid or unsaturated carboxylic acid anhydride, unsaturated sulphonate and polyether big monomers during acidylation and esterification; acylamide groups, amino groups, phosphate groups, carboxylate groups, sulphonate groups, polyether lateral chains and benzene rings are introduced into molecular structures, so that the product has a high initial water reducing rate. The molecular structures of the water reducing agent prepared by the preparation method comprise ester groups, phenyls and phosphate groups; the ester groups hydrolyze under the basic condition of the concrete; carboxyls with the water reducing function and hydroxy phenyl phosphate groups with the hydration heat reducing function are gradually released; the concrete hydration heat can be effectively reduced.

The invention discloses a preparation method of a low-sensitive concrete flowability stabilizer. The preparation method comprises the following steps: (1) esterification reaction; (2) monomer blending; (3) copolymerization reaction; (4) neutralization reaction. According to the preparation method disclosed by the invention, unsaturated carboxylic acid or unsaturated carboxylic acid anhydride and esterification products esterified by polyethylene glycol monomethyl ether and a compound A are used in copolymerization and synthesis of polycarboxylic acid, and a molecular chain structure having a benzene ring, an ester group and a carboxylic group at the same time is introduced in a molecular chain structure of the polycarboxylic acid; the carboxylic acid group and a sulfonic acid group which have an electrostatic repulsion effect and a polyether side chain and the benzene ring which have steric hindrance are introduced, so that a product has a higher initial water reducing rate.

The invention relates to the technical field of concrete admixtures, and in particular, relates to preparation methods of a polyether monomer and a polycarboxylate water reducer. The polyether monomeris prepared by the following method: 1) in the presence of a basic catalyst, reacting an unsaturated compound with at least one active hydrogen atom with alkylene oxide to obtain an alkoxylation product I; and 2) in the presence of a basic catalyst, reacting the alkoxylation product I with alkylene oxide to obtain an alkoxylation product II, wherein the reaction temperature of the alkoxylation product I and alkylene oxide in the step 2) is 25 DEG C or above. The polyether monomer prepared by the method disclosed by the invention has good polymerization activity and high double bond retentionrate, has lower synthesis temperature than common polyether monomers, can be stored and used for a long time without neutralization, and simplifies the synthesis process steps of the polyether monomer.