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36 results about "Tetracyanoquinodimethane" patented technology

Tetracyanoquinodimethane (TCNQ) is the organic compound with the formula (NC)₂CC₆H₄C(CN)₂. This cyanocarbon, a relative of para-quinone, is an electron acceptor that is used to prepare charge transfer salts, which are of interest in molecular electronics.

Novel cyanine-TCNQ dye for high density data storage media

This invention is to provide a kind of cyanine-TCNQ complex dyes mixture (II, III, and IV) used as the data storage media having the structural formula (I): wherein Q and Q' denote aromatic or polyaromatic, R1 and R2 are selected from the group consisting of alkyl, arylester, alkoxy, alkylthio, and alkoxythio etc., n represents an integer of 0, 1, 2, and 3, TCNQ-m represents 7,7',8,8'-tetracyanoquinodimethane or its derivatives, and m represents an integer of 1 or 2. They can be used as the recording layer materials for the reflection optical recording media and the non-reflection fluorescent optical recording media after the suitable formulation.
Owner:LIAO WEN YIH +8

Color matching detecting and analyzing method of cobalt ion

The invention relates to a color comparison testing and analyzing method of cobalt ion. The method uses 8-hydroxyquinoline as electron donor, 7, 7, 8, 8-tetracyanoquinodimethane as electron acceptor. Colored charge transfer complex is formed in polar solvent through the charge transferring effect among molecule and is made as testing reagent. Water-soluble cobalt salt are made into water solution of definite viscosity, a definite volume of water solution and the testing reagent with same volume are mixed. The color of the solution changes obviously, and other metal ion doesn't interfere cobalt ion. With room temperature testing, the color comparison reaction of the testing reagent to cobalt ion can be identified by eyes or tested by using ultraviolet-visible spectrophotometer. The invention has very professional color comparison identifying capability to cobalt ion the preparation of solution is convenient, the operation of the color comparison is very simple, and the color changing speed of color comparison reaction is quick, which can finish the color comparison test to the tested object in very short time.
Owner:LANZHOU INST OF CHEM PHYSICS CHINESE ACAD OF SCI

Preparation method of porous composite material capable of selectively absorbing aromatic hydrocarbon

The invention discloses a preparation method of a porous composite material capable of selectively absorbing aromatic hydrocarbon. The composite material is obtained from two monomer molecules by cocrystallization. Particularly, the preparation method comprises the steps of: dissolving 1-acetyl-3-(4-methoxy phenyl)-5-(9-anthryl) pyrazoline (AMPE) and 7, 7, 8, 8-TCNQ in a non-aromatic solvent, then removing the solvent, and finally drying to obtain the composite material. The composite material provided by the invention is used for only selectively absorbing aromatic hydrocarbon from a mixture of aromatic hydrocarbon and non-aromatic hydrocarbon solvents.
Owner:SOUTHEAST UNIV

Tetracyanoquinodimethane rare earth complex and synthetic method and application thereof

InactiveCN101787044AConducive to the establishment of structure-activity relationshipGroup 3/13 element organic compoundsOrganic/organic-metallic materials magnetismTetracyanoquinodimethaneRare earth
The invention discloses a tetracyanoquinodimethane rare earth complex and a synthetic method and application thereof. The tetracyanoquinodimethane rare earth complex Ln(TCNQ) is synthesized and structurally characterized by adopting standard Schlenk technology, taking LnCl3.nH20 and LiTCNQ as raw materials, taking deoxidized methanol, ethanol and double-distilled water as solvents through slow heterogeneous solution diffusion reaction. The complex has two molecular structures, namely, zero-dimension dimeric molecular structure and zero-dimension mononuclear molecular structure. The complex and a compound thereof of which the solution is removed have good molecular magnetism. The complex and the method of the invention have wide application prospect which includes the application in the technical field of preparation of magnetic materials.
Owner:HEILONGJIANG UNIV

Preparation method of porous composite material

The invention discloses a preparation method of a porous composite material. The material is prepared by forming binary co-crystallization through utilizing two monomer organic molecules, namely by grinding chalcone molecules containing aromatic thickening rings, and 7,7,8,8-Tetracyanoquinodimethane (TCNQ) under the assistance of no solvent, or prepared by grinding under the assistance of non-aromatic hydrocarbon solvent and drying. The porous composite material can selectively absorb aromatic hydrocarbon and aromatic hydrocarbon composition after being applied to a solvent mixture of aromatic hydrocarbon and non-aromatic hydrocarbon.
Owner:SOUTHEAST UNIV

Synthesis of conducto-magnetic polymers as nano-transducers in biosensor design

A conductive polymer of polyaniline (PANi), tetracyanoquinodimethane (TCNQ) and a transferrin family member. The conductive polymer can be used in conductometric assays, including biosensor devices. One particular transferrin family member provided in the polymer is lactoferrin.
Owner:BOARD OF TRUSTEES OPERATING MICHIGAN STATE UNIV

Metal organic coordination polymer thermoelectric material and preparation method and application thereof

The invention discloses a copper-7, 7, 8, 8-tetracyanoquinodimethane material and a preparation method and an application thereof. The method comprises the following steps: in an inert atmosphere, dissolving -7, 7, 8, 8-tetracyanoquinodimethane in acetonitrile; and then, adding cuprous iodide, and carrying out a reaction under reflux to obtain the material. The material prepared by the invention can be used for preparing organic thermoelectric materials. Through verification, the thermoelectricity of the copper-7, 7, 8, 8-tetracyanoquinodimethane doped by 2, 3, 5, 6-tetrafloro-7, 7', 8, 8'-tetracyanodimethyl p-benzoquinone is remarkably improved, for instance, when the dosage concentration of 2, 3, 5, 6-tetrafloro-7, 7', 8, 8'-tetracyanodimethyl p-benzoquinone under 360K is 1mol%, the power factor is improved from 1.4 mu W / mK<2> to 2.2 mu W / mK<2>. Meanwhile, the preparation method provided by the invention is simple in process, easy in preparation and low in cost.
Owner:INST OF CHEM CHINESE ACAD OF SCI

Organic electroluminescent device and preparation method thereof

An organic electroluminescent device comprises an anode, a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, an electron injection layer, and a cathode, all of which are sequentially stacked. The cathode layer is composed of a sodium salt layer, a hole injection material doped layer, and a metal doped layer. The sodium salt layer includes at least one material selected from sodium carbonate, sodium fluoride, sodium chloride, and sodium bromide. The hole injection material doped layer includes a hole injection material and titanium dioxide doped in the hole injection material, wherein the hole injection material includes at least one selected from 2, 3, 5, 6-polytetrafluoroethylene-7, 7, 8, 8-tetracyanoquinodimethane, 4, 4, 4-tri(naphthyl-1-phenyl-ammonium)triphenylamine, and dinaphthyl-N, N'-diphenyl-4, 4'-benzidine. The organic electroluminescent device has high luminous efficiency. The invention further provides a method for preparing the organic electroluminescent device.
Owner:OCEANS KING LIGHTING SCI&TECH CO LTD +2

2, 3, 5, 6-tetrafluoro-7, 7', 8, 8'-tetracyanoquinodimethane and preparation method thereof

The invention discloses 2, 3, 5, 6-tetrafluoro-7, 7', 8, 8'-tetracyanoquinodimethane and a preparation method thereof. The preparation method comprises diazotization: carrying out diazotization of a compound A and a compound B to obtain a compound C, reduction: reducing the compound C into a compound D, oxidation: oxidizing the compound D into a compound E, and condensation: condensing the compound E and malononitrile to obtain a compound F, wherein the compound F is 2, 3, 5, 6-tetrafluoro-7, 7', 8, 8'-tetracyanoquinodimethane and the compounds A, B, C, D, E and F are shown in the description. The preparation method has good environmental friendliness and a high yield of 80% or more, is simple and easy and is suitable for industrial production.
Owner:BEIJING SINEVA TECH

Composite material capable of separating mixed xylene and preparation method of composite material capable of separating mixed xylene

The invention discloses a composite material capable of separating mixed xylene. The composite material is obtained by cocrystallization of two monomer molecules obtained by dissolving 1-acetyl-3-phenyl-5-(9-anthryl) pyrazoline (APPP) and 7,7,8,8-tetracyanoquinodimethane in an aromatics solvent, and drying after the solvent is removed so that a eutectic material is obtained. The composite material disclosed by the invention is used for selectively adsorbing paraxylene in a mixture after being applied to a mixed xylene solvent.
Owner:SOUTHEAST UNIV

Thin film as well as preparation method and application thereof

The invention belongs to the field of light-emitting devices, and provides a thin film as well as a preparation method and an application thereof. According to the thin film provided by the invention,on one hand, the complex of aminated tetracyanoquinodimethane and tetramethyl benzidine can increase the work function of an anode, and hole injection is facilitated; and on the other hand, the complex of aminated tetracyanoquinodimethane and tetramethyl benzidine has a very large conjugated bond and very strong electrical conductivity, a dipole moment exists in the interior, and holes are rapidly transferred to a light-emitting layer under the action of the dipole moment, so that the efficiency is improved. When the thin film material is applied to a light emitting device, the efficiency ofthe light-emitting device can be improved by using the complex of aminated tetracyanoquinodimethane and tetramethyl benzidine as a modification layer between the anode and an organic layer.
Owner:SHENZHEN TCL IND RES INST

Hybrid and/or complex material, photoelectric conversion material, dye-sensitized solar cell, dye-sensitized solar cell device, manufacturing method of photoelectric conversion device, and method of analyzing titanium oxide crystal structure

InactiveUS20110011459A1High-efficient photoelectric conversionElectrolytic capacitorsFinal product manufactureSolar cellTitanium oxide
There is provided a hybrid and / or complex material or the like which can realize a high-efficient photoelectric conversion material or the like. One aspect of the present invention lies in a dye-sensitized solar cell device 10, characterized by including: a first substrate 11; a first conductive layer 12 formed on the first substrate; a Pt catalyst layer formed on the first conductive layer; an electrolyte layer 13 formed on the Pt catalyst layer; a dye-adsorbed metal oxide layer 14 formed on the electrolyte layer in which 7,7,8,8-tetracyanoquinodimethane is adsorbed to an anatase type titanium oxide; a second conductive layer 15 formed on the dye-adsorbed metal oxide layer; and a second substrate 16 formed on the second conductive layer. According to this composition above, there is obtained a high-efficient dye-sensitized solar cell device in which light can be converted efficiently over wide wavelengths.
Owner:THE UNIV OF TOKYO +1

Method for detecting diethyl chlorophosphate gas and/or sarin toxic gas based on charge transfer complex

The invention relates to a method for detecting diethyl chlorophosphate gas and / or sarin toxic gas based on a charge transfer complex. The method comprises the steps that a first compound containing aN,N dimethyl aromatic amine structure and a second compound containing a tetracyanoquinodimethane structure interacts through intermolecular charge transfer in a solvent to obtain a solution of the charge transfer complex; a sensing material is loaded on the surface of an electrode to form a sensor piece; and the sensor piece is put into the atmosphere containing the diethyl chlorophosphate gas and / or the sarin toxic gas to be detected. According to the method, through the charge transfer complex formed by mixing of the first compound and the second compound in the solvent, the high electronmobility and high hole mobility are achieved, the independent chemical physical properties of the first compound and the second compound are maintained while complexing is conducted, the charge transfer complex can serves as an electrochemical sensing probe to detect the sarin toxic gas, and the problems that in the prior art, detection sensitivity of the sarin toxic gas is low, specificity is low, the means is complex, and the cost is high are solved.
Owner:SHANGHAI INST OF MICROSYSTEM & INFORMATION TECH CHINESE ACAD OF SCI

Organic light-emitting device and preparation method thereof

InactiveCN103427024ATransmission rate controlChances of Avoiding Compound LuminescenceSolid-state devicesSemiconductor/solid-state device manufacturingMixed materialsElectron
An embodiment of the invention discloses an organic light-emitting device. The organic light-emitting device comprises an anode substrate, a quantum well layer, an electron transport layer, an electron injection layer and a cathode. The quantum well layer comprises at least two layers of p-type doping hole transporting layers stacked in sequence and light-emitting layers arranged between the two layers of adjacent p-type doping hole transporting layers, the p-type doping hole transporting layers are made of a mixed material formed by hole transporting material doping p-type materials, and the p-type materials are 2,3,5,6-tetrafluoro-7,7,8,8-tetracyanoquinodimethane and 4,4,4-tri (naphthyl-1-phenyl-ammonium) triphenylamine or 4,4,4-tri (naphthyl-1-phenyl-ammonium) triphenylamine. In addition, the embodiment of the invention further discloses a preparation method of the organic light-emitting device. According to the organic light-emitting device, the hole and electron recombination probability is effectively improved by adjusting the hole transmission speed, and the goal of improving light-emitting efficiency is achieved finally.
Owner:OCEANS KING LIGHTING SCI&TECH CO LTD +1

Cyanine-TCNQ complex dye data storage media and manufacturing method thereof

This invention provides a data storage media comprising at least a cyanine-TCNQ complex dye having the structural formula: wherein Q and Q' denote aromatic or polyaromatic, R1 and R2 are selected from the group consisting of alkyl, arylester, alkoxy, alkylthio, and alkoxythio etc., n represents an integer of 0, 1, 2, and 3, TCNQ-m represents 7,7',8,8'-tetracyanoquinodimethane or its derivatives, and m is an integer of 1 or 2. The data storage media comprising the cyanine-TCNQ complex dye includes a reflection optical recording media and a non-reflection fluorescent optical recording media suiting the requirement.
Owner:IND TECH RES INST +1

Photoelectric device and preparation method thereof

The invention discloses a device capable of producing a photoelectric effect and electroluminescence simultaneously and a preparation method thereof. The photoelectric device is acquired through packaging a cadmium sulfide / cadmium telluride heterogeneous junction nano-rod, and specifically comprises an anisotropic conductive film, an Al electrode, ZnO, a heterogeneous junction nano-rod, 2, 3, 5, 6-tetrafluoro-7, 7', 8, 8'-tetracyanoquinodimethane, TCNQF4 and the like. The invention further discloses a preparation method of the photoelectric device.
Owner:苏州市皎朝纳米科技有限公司

Organic electroluminescent device and preparation method thereof

An organic electroluminescent device comprises an anode, a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer, an electron injection layer, and a cathode, all of which are sequentially stacked. The cathode layer is composed of a doped layer and a metal layer. The doped layer includes a metal sulfide material, a hole doped object material, and a passivation material. The metal sulfide material includes at least one selected from zinc sulfide, cadmium sulfide, magnesium sulfate, and copper sulfide. The hole doped object material includes at least one selected from 2, 3, 5, 6-polytetrafluoroethylene-7, 7, 8, 8-tetracyanoquinodimethane, 4, 4, 4-tri(naphthyl-1-phenyl-ammonium)triphenylamine, and dinaphthyl-N, N'-diphenyl-4, 4'-benzidine. The organic electroluminescent device has high luminous efficiency. The invention further provides a method for preparing the organic electroluminescent device.
Owner:OCEANS KING LIGHTING SCI&TECH CO LTD +2

Charge-transporting varnish

Provided is a charge-transporting varnish that includes a monodisperse charge-transporting organic compound (A), a dopant (B), and an organic solvent (C). The dopant (B) includes: an aryl sulfonic acid ester compound (B1); and halogenated tetracyanoquinodimethane (B2) or halogenated or cyanated benzoquinone (B3).
Owner:NISSAN CHEM IND LTD
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