The invention discloses a
silane-substituted two-dimensional conjugated
polymer and a preparation method thereof, and application of the
silane-substituted two-dimensional conjugated
polymer to a photovoltaic device. The two-dimensional conjugated
polymer has a
structural formula as shown in a formula I. In the formula I, Ar1 is a conjugate aromatic ring or a condensed ring constructed by the conjugate aromatic ring, and the conjugate aromatic ring is
thiophene, bithiophene, a phenyl ring,
furan or selenophene; and R1, R2 and R3 are independently selected from a group consisting of a silyl group, H,
halogen, an alkyloxy group and an alkylthio group, and at least one
substituent of R1, R2 and R3 is the silyl group which is a straight-chain or branched-chain silyl group with a
carbon atom number of 1 to 30. The
silane-substituted two-dimensional conjugated polymer provided by the invention has greatly improved photoelectric properties and good charge transfer performance and an appropriate
electronic energy level, and is applicable as an
electron donor material for matching with a
narrowband N-type micromolecular
receptor material to a non-
fullerene polymer solar cell device.