The invention discloses an addition agent having a synergistic effect on cement.The addition agent is prepared from, by weight, 5.4-5.8 parts of nitrilotriacetic acid, 1.8-2.4 parts of ethylene diamine tetra (methylene phosphonic acid) sodium, 2.4-2.7 parts of triisopropanolamine, 3.7-4.3 parts of acrylamide, 3.2-3.5 parts of alpha-sodium-olefinsulfonate, 3.3-3.6 parts of useless lubricating oil, 3.9-4.4 parts of lauryl sodium sulfate, 4.9-5.7 parts of urea, 2.2-2.5 parts of calcium lignosulfonate, 0.6-0.8 parts of molasses, 2.6-3.0 parts of sodium thiosulfate, 2.1-2.5 parts of a silicone lubricating agent, 1.5-1.9 parts of a fluorine-containing lubricating agent, 2.1-2.5 parts of polysorbate-80 and 2.3-2.7 parts of sorbitol.The construction efficiency can be improved effectively, price is low, the enhancing effect is remarkable, fallen dust is reduced, resources are saved, the raw materials are wide in source, and the manufacturing technology is simple.