The invention relates to a
methacrylate polymer solid phase micro extraction
fiber and a preparation method thereof, in particular to a
solid phase micro extraction. A
fiber is provided with a stainless steel substrate which is a
stainless steel wire, and one end of the
stainless steel wire is provided with a
methacrylate polymer coating. The preparation steps of the invention are that: one end of the
stainless steel wire is cleaned with water and dried after being ultrasonically cleaned by an
acetone solvent and an
ethanol solvent;
trimethylolpropane trimethacrylate, toluol and azodiisobutyronitrile are added to the
methacrylate in sequence, then ultrasonic blending process and
nitrogen flushing and deoxygenizing process are conducted, and then a prepolymerization blended solution is obtained; the prepolymerization blended solution is injected to a glass point sampling capillary by a microliter
syringe, then the stainless steel wire is vertically inserted into the central part of the point sampling tube, and the two ends of the point sampling tube are sealed by rubber, then the point sampling tube is placed into an oven for polymerizing and cross linked at a certain temperature. After a
polymer solution is solidified at the surface of the
fiber, the point sampling tube is soaked in a
hydrofluoric acid solution for a certain period, then the
glass tube wall is removed, and then the
solid phase micro extraction fiber is obtained.