A preparation method of a novel alcohol ether environment friendly fuel includes the following steps: 1) purchasing the following raw materials, according to mass part, aromatic hydrocarbon, methylbenzene, methanol, tert-butanol, isobutanol, isopropanol, benzyl alcohol, ethanol, petroleum ether, ethyl ether, isopropyl ether, isooctane, dimethoxymethane, 3-dihydroxybutane, octane, diethyl carbonate, ethyl 2-ethyldioxyacetate, dibutyl phosphite, ethyl acetate, ethyl-propyl ketone, 501 antioxidant, a di-tert-butyl compound and a corrosion inhibitor; 2) mixing the methanol, the tert-butanol, the isobutanol, the isopropanol, the benzyl alcohol and the ethanol to obtain a mixture (A); 3) mixing the petroleum ether, the ethyl ether, the isopropyl ether, the isooctane, the dimethoxymethane, the 3-dihydroxybutane and the octane to obtain a mixture (B); 4) mixing the diethyl carbonate, the ethyl 2-ethyldioxyacetate, the dibutyl phosphite, the ethyl acetate, the ethyl-propyl ketone, the 501 antioxidant, the di-tert-butyl compound and the corrosion inhibitor to obtain a mixture (C); 5) mixing the mixtures (A) and (B) with aromatic hydrocarbon and the methylbenzene to obtain a mixture (D); and 6) uniformly mixing the mixtures (C) and (D) to prepare the fuel.