The invention discloses a high-
voltage-resistant
solid-state battery composite positive
electrode and a preparation method thereof, and belongs to the technical field of all-
solid-state battery systems. In order to solve the problems of low
cut-off
voltage of a battery and difficulty in matching with a high-
voltage positive
electrode caused by a voltage window of an all-
solid-state
polymer electrolyte, the method comprises the following steps: weighing two
polymer monomers and
lithium salt, adding into a
reagent bottle, adding an
acetone solvent, stirring for dissolving, stirring for 12-24 hours, and filtering to obtain a filtrate; adding azoisobutyronitrile which accounts for 1% of the total
mass of the
polymer monomer as a thermal initiator, and continuously stirring for 12-24 hours; adding a ternary LiNi0. 8Co0. 1Mn0. 1O2 positive active material and a
carbon nanotube into a container, then adding the segmented
copolymer binder precursor solution obtained in the step 1, and stirring on a stirrer for 24-36 hours to uniformly mix; and preparing the
pole piece. According to the invention, the traditional
lithium ion battery positive
electrode binder is replaced by the segmented
copolymer electrolyte with good
lithium ion conductivity, so that the lithium
ion diffusivity in the positive electrode is enhanced.