The invention relates to a synthetic method of an LDH@SiO2 shell-nuclear nano composite material. The method comprises the following steps: I, magnetically stirring and uniformly mixing anhydrous ethanol, deionized water and ammonia water, then, adding ethyl orthosilicate, continuously stirring, standing, centrifuging, collecting precipitates, washing to neutral and drying; II, dissolving NaOH and NaOH3 in deionized water with CO2 removed and dispersing SiO2 nano particles therein to obtain liquid A; III, dissolving 15-20g of Mg(NO3)3.6H2O and 10-12g of Al(NO3)3.9H2O in deionized water without CO2 to obtain liquid B; and IV, dropwise adding the liquid B into the liquid A while stirring, stirring at constant temperature, washing the precipitates by using the deionized water without CO2, and drying in vacuum to obtain the material. The material provided by the invention is uniform in particle size distribution and easy to control, simple in preparation process, relatively low in production cost and easy for scaled production.