The invention discloses a high-voltage lithium nickel manganese oxide / graphite lithium ion battery and a manufacturing method thereof, and proposes modifying the surface of the negative electrode with an organic acid ester to change the components of the SEI film and strengthen the stability of the interface between the electrolyte and the electrode. So as to effectively curb the rapid decline of capacity. In the present invention, by optimizing the electrolyte, adding functional additives to the traditional organic electrolyte, the initial efficiency of the battery is improved, the self-discharge of the battery is suppressed, the specific capacity of the battery is increased, and a battery with a high specific capacity and a long cycle is realized. In order to further stabilize the efficient operation of the LNMO / graphite lithium-ion battery with high specific capacity and long cycle life, and further improve the stability of the battery, the present invention also proposes to modify the positive electrode. The LNMO@LTO cathode material is prepared by coating LNMO with Li4Ti5O12. The coating layer can effectively avoid the direct contact between the electrolyte and the active material body, reduce the overflow of Mn from the cathode material, and reduce the further catalytic effect of Mn on the SEI film, making the system more stable.