The invention belongs to a method for extracting lead-zinc oxide through oxygen enriched combustion by utilizing zincilate volatilization kiln. The process comprises the steps such as burdening, oxygen preparation, oxygen pressure storage, gas mixing, concentration adjusting, air supply and the like, wherein in the burdening link, the mass ratio of leaching slag to coal is 1:(35-45) and the mixture comprises 12-16wt% of carbon; in the volatilization process, slaked lime accounting for 5-10wt% of the mixture is added; in the gas mixing link, oxygen with the volume concentration of more than 90% and the oxygen supply pressure of 0.4-0.5Mpa is introduced, oxygen is mixed in a gas mixing tank at the head of the kiln, and the volume concentration of the mixed gas is controlled to be 25-45%; and in the volatilization link, lead-zinc oxide smoke is controlled to be volatilized and output at the temperature of 200-1350 DEG C. According to the invention, the carbon combustion condition of the volatilization kiln can be improved, the fuel consumption can be greatly reduced, the concentration of the oxygen in the volatilization kiln can be reasonably promoted, the carbon combustion efficiency can be improved, energy conservation can be achieved, the cost is lowered, and the metal volatilization ratio can be improved.