The invention discloses a zwitter-ion-containing all-solid-state polymer electrolyte membrane, and a preparation method and use thereof. An all-solid-state polymer electrolyte disclosed by the invention is prepared from poly(methyl hydrogen silicomethane), N,N-dimethylallylamine, allyl capped polyether, 1,3-propyl sultone, lithium salt and a cross-linking agent. The preparation method comprises the following steps of: sufficiently mixing PHMS, PEO with DMAA in methylbenzene, and reacting by adding a chloroplatinic acid catalyst; reacting a prepared product with 1,3-PS again; and, mixing the lithium salt and the cross-linking agent in the reacted product in an acetonitrile solvent, crosslinking and forming a membrane in a vacuum oven after sufficiently stirring, and then, obtaining the zwitter-ion-containing all-solid-state polymer electrolyte membrane. The conductivity of the zwitter-ion-containing all-solid-state polymer electrolyte disclosed by the invention is greatly increased; the conductivity is up to 3.39*10<-4>Scm<-1>; an electrochemical window is beyond 5 V; and thus, the zwitter-ion-containing all-solid-state polymer electrolyte can be used for a lithium secondary battery.