1240results about "Secondary cell details" patented technology

The present invention provides a multi-component hybrid electrode for use in an electrochemical super-hybrid energy storage device. The hybrid electrode contains at least a current collector, at least an intercalation electrode active material storing lithium inside interior or bulk thereof, and at least an intercalation-free electrode active material having a specific surface area no less than 100 m2 / g and storing lithium on a surface thereof, wherein the intercalation electrode active material and the intercalation-free electrode active material are in electronic contact with the current collector. The resulting super-hybrid cell exhibits exceptional high power and high energy density, and long-term cycling stability that cannot be achieved with conventional supercapacitors, lithium-ion capacitors, lithium-ion batteries, and lithium metal secondary batteries.

A secondary battery comprising an electrode assembly having a positive electrode plate, a negative electrode plate, and a separator between the positive and negative electrodes is provided. The secondary battery further comprises a case for containing the electrode assembly, and a cap assembly connected to the case. The cap assembly comprises positive and negative terminals electrically connected to the positive electrode plate and the negative electrode plate, respectively. Lead connectors are electrically connected to the positive and negative electrode plates and the positive and negative terminals. A support is connected to each end of the electrode assembly and surrounds the lead connectors. The supports are adapted to fit between the electrode assembly and the case.

A high capacity, high charge rate lithium secondary cell includes a high capacity lithium-containing positive electrode in electronic contact with a positive electrode current collector, said current collector in electrical connection with an external circuit, a high capacity negative electrode in electronic contact with a negative electrode current collector, said current collector in electrical connection with an external circuit, a separator positioned between and in ionic contact with the cathode and the anode, and an electrolyte in ionic contact with the positive and negative electrodes, wherein the total area specific impedance for the cell and the relative area specific impedances for the positive and negative electrodes are such that, during charging at greater than or equal to 4C, the negative electrode potential is above the potential of metallic lithium. The current capacity per unit area of the positive and negative electrodes each are at least 3 mA-h / cm2, the total area specific impedance for the cell is less than about 20 Ω-cm2, and the positive electrode has an area specific impedance r1 and the negative electrode has an area specific impedance r2, and wherein the ratio of r1 to r2 is at least about 10.

Articles, systems, and methods related to the configuration of electrically non-conductive materials and related components in electrochemical cells are generally described. Some inventive electrochemical cell configurations include an electrically non-conductive material (e.g., as part of the electrolyte) that is configured to wrap around the edge of an electrode to prevent short circuiting of the electrochemical cell. In some embodiments, the electrically non-conductive material layer can be arranged such that it includes first and second portions (one on either side of an electrode) as well as a third portion adjacent the edge of the electrode that directly connects (and, in some cases, is substantially continuous with) the first and second portions. The electrically non-conductive material layer can be relatively thin while maintaining relatively high electrical insulation between the anode and the cathode, allowing one to produce an electrochemical cell with a relatively low mass and / or volume. The arrangements described above can be formed, for example, by forming a multi-layer structure comprising an electrode and an electrically non-conductive material layer (e.g., as a coating), and folding the multi-layer structure such that the electrically non-conductive material covers the convex surface portion of the resulting crease.

Chargers which can be connected to batteries with different charging requirements and which have an identification device for identification of the different batteries are disclosed. With these chargers, the different types of batteries are recognized by a magnetic identification device. In a first exemplary embodiment, the identification device comprises at least one magnetic sensor, which is arranged in or on the charger and detects at least one magnetic parameter of a magnetic element, which is mounted in or on the battery. In a second exemplary embodiment, the identification device has at least one magnetic element and at least one magnetic sensor for detection of at least one magnetic parameter of the at least one magnetic element. The battery comprises a shielding and / or amplifying device, which alter(s) the at least one magnetic parameter of the at least one magnetic element.

To provide a lithium secondary cell, which is excellent in productivity since a cell structure is simple and easy for assembly. Provided is a lithium secondary cell having: an internal electrode body including a positive electrode plate, a negative electrode plate, the positive electrode plate and the negative electrode plate being wound and laminated around an external periphery wall of a hollow cylindrical winding core, and inside the internal electrode body a nonaqueous electrolyte solution being impregnated, a cylindrical cell case contained in this internal electrode body 1 with both ends being opened, and two electrode caps sealing the above described internal electrode body 1 at both the open ends of this cell case. The electrode cap has a plate member sealing the internal electrode body and disposed so as to seal both the open ends of the above described cell case, an external terminal member protruding onto the surface of the electrode caps to lead out currents to outside, and an internal terminal member brought into connection with the internal electrode body and taking out currents from the internal electrode body, and an elastic body and at least two of the above described plate member, the external terminal member and the internal terminal member are joined together for construction. Furthermore, there is also provided an assembly of lithium secondary cells.

A lithium secondary battery includes an electrode assembly having a positive electrode (1), a negative electrode (2) having a negative electrode current collector and a negative electrode active material layer formed on a surface of the negative electrode current collector and composed of a binder and negative electrode active material particles containing silicon and / or a silicon alloy, and a separator (3) interposed between the electrodes. The electrode assembly is impregnated with a non-aqueous electrolyte. The binder contains a polyimide resin represented by the following chemical formula (1):where R contains at least a benzene ring, and n is within the range of from 10 to 100,000, and the negative electrode active material particles have an average particle size of 5 μm or greater.

The present invention provides a battery cell, comprising: (a) an anode comprising an active metal or a metal ion storage material (e.g., an intercalation compound that accommodates lithium ion); (b) a cathode structure; and (c) an ionically conductive protective layer on a surface of the anode and interposed between the anode and the cathode structure. This protective layer comprises a porous membrane having pores therein and a soft matter phase disposed in at least one of the pores, wherein the soft matter phase comprises oxide particles dispersed in a non-aqueous alkali, alkaline, or transition metal salt solution. Most preferably, this battery cell is a lithium metal secondary cell that is essentially free from dendrite and exhibits a safer and more stable cycling behavior. Such a high-capacity rechargeable battery is particularly useful for powering portable electronic devices and electric vehicles.

A method of operating a lithium-ion cell comprising (a) a cathode comprising a carbon or graphitic material having a surface area to capture and store lithium thereon; (b) an anode comprising an anode active material; (c) a porous separator disposed between the two electrodes; (d) an electrolyte in ionic contact with the two electrodes; and (e) a lithium source disposed in at least one of the two electrodes to obtain an open circuit voltage (OCV) from 0.5 volts to 2.8 volts when the cell is made; wherein the method comprises: (A) electrochemically forming the cell from the OCV to either a first lower voltage limit (LVL) or a first upper voltage limit (UVL), wherein the first LVL is no lower than 0.1 volts and the first UVL is no higher than 4.6 volts; and (B) cycling the cell between a second LVL and a second UVL.

A secondary battery includes a case, a rolled electrode assembly disposed within the case, and an electrode assembly fixing member receiving a portion of the rolled electrode assembly so that expansion and contraction of the rolled electrode assembly can be suppressed during charging and discharging operations of the battery, and deformation of the rolled electrode assembly caused by outer impact can be prevented. The electrode assembly fixing member comprises a cap fitted onto at least one of upper and lower ends of the rolled electrode assembly. The electrode assembly fixing member further comprises a gripper holding the rolled electrode assembly.

The present invention is drawn to a high power electrochemical energy storage device, comprising at least one stackable, monolithic battery unit. The monolithic battery unit includes at least two electrochemical energy storage cells. The cells have a lithium ion insertion anode and a lithium ion insertion cathode, a bipolar current collector between cells and end plate current collectors at the opposing ends of each battery unit. A frame may be associated with the perimeter of the current collector. The current collector comprises a high-conductivity metal. The device also has the at least two storage cells substantially aligned adjacent one another, a separator material associated between the anode and the cathode within each cell; and an electrolyte within each cell.Additionally, the present invention is drawn to a device combining two or more of the monolithic units, either in series or in parallel or any combination thereof, so as to create a high power, high voltage energy storage device.

The present invention relates to stacks comprising separators and electrodes stacked alternately one on top of the other and fixed, the stack having, on at least one side and / or edge of the stack, at least one adhesive bond comprising an organic adhesive, which bond adhesively bonds the electrodes and separators of the stack to one another, and a method for the production thereof and the use of these stacks in Li batteries.

A negative active material for a rechargeable lithium battery includes a core including an active material being capable of performing reversible electrochemical oxidation and reduction, and a coating layer on the surface of the core. The coating layer includes a reticular structure including —O-M-O— wherein M is selected Si, Ti, Zr, Al, or combinations thereof and an organic functional group linked to the M as a side chain. The organic functional group is selected from the group consisting of an alkyl group, a haloalkyl group, a substituted or unsubstituted aryl group, and combinations thereof. The negative active material for a rechargeable lithium battery according to the present invention can be applied along with an aqueous binder, and improve high capacity, good cycle-life, and particularly high capacity during charge and discharge at a high rate.

The present invention provides a solid-state sodium-based secondary cell (or rechargeable battery). While the secondary cell can include any suitable component, in some cases, the secondary cell comprises a solid sodium metal negative electrode that is disposed in a non-aqueous negative electrolyte solution that includes an ionic liquid. Additionally, the cell comprises a positive electrode that is disposed in a positive electrolyte solution. In order to separate the negative electrode and the negative electrolyte solution from the positive electrolyte solution, the cell includes a sodium ion conductive electrolyte membrane. Because the cell's negative electrode is in a solid state as the cell functions, the cell may operate at room temperature. Additionally, where the negative electrolyte solution contains the ionic liquid, the ionic liquid may impede dendrite formation on the surface of the negative electrode as the cell is recharged and sodium ions are reduced onto the negative electrode.

Provided are a pouch-type secondary battery having improved safety, and a battery pack including the pouch-type secondary battery. When inner pressure of a pouch is increased by an overdischarge, the pouch is deformed to separate electrode leads from electrode tabs. When the secondary battery is manufactured, an additional material or device is unnecessary. In addition, since the pouch-type secondary battery fundamentally cuts off electric current when gas is generated therein, the service life and safety of the secondary battery can be significantly improved, and the manufacturing costs and the weight thereof can be reduced. Furthermore, the shape of the secondary battery can be easily modified.

A high capacity, high charge rate lithium secondary cell includes a high capacity lithium-containing positive electrode in electronic contact with a positive electrode current collector, said current collector in electrical connection with an external circuit, a high capacity negative electrode in electronic contact with a negative electrode current collector, said current collector in electrical connection with an external circuit, a separator positioned between and in ionic contact with the cathode and the anode, and an electrolyte in ionic contact with the positive and negative electrodes, wherein the total area specific impedance for the cell and the relative area specific impedances for the positive and negative electrodes are such that, during charging at greater than or equal to 4C, the negative electrode potential is above the potential of metallic lithium. The current capacity per unit area of the positive and negative electrodes each are at least 3 mA-h / cm2, the total area specific impedance for the cell is less than about 20 Ω-cm2, and the positive electrode has an area specific impedance r1 and the negative electrode has an area specific impedance r2, and wherein the ratio of r1 to r2 is at least about 10.

A polyolefin separator having an heat-resistant ultrafine fibrous layer and a secondary battery using the same, in which the separator has a shutdown function, low thermal contraction characteristics, thermal endurance, excellent ionic conductivity, excellent cycling characteristics at the time of battery construction, and excellent adhesion with an electrode. The present N invention adopts a very simple and easy process to form an ultrafine fibrous layer through an electrospinning process, and at the same time, to remove solvent and to form pores. Accordingly, the separator of the present invention is useful particularly for electrochemical devices used in a hybrid electric automobile, an electric automobile, and a fuel cell automobile, requiring high thermal endurance and thermal stability.

Amorphous lithium lanthanum zirconium oxide (LLZO) is formed as an ionically-conductive electrolyte medium. The LLZO comprises by percentage of total number of atoms from about 0.1% to about 50% lithium, from about 0.1% to about 25% lanthanum, from about 0.1% to about 25% zirconium, from about 30% to about 70% oxygen and from 0.0% to about 25% carbon. At least one layer of amorphous LLZO may be formed through a sol-gel process wherein quantities of lanthanum methoxyethoxide, lithium butoxide and zirconium butoxide are dissolved in an alcohol-based solvent to form a mixture which is dispensed into a substantially planar configuration, transitioned through a gel phase, dried and cured to a substantially dry phase.

A pouch type secondary battery has a safety vent which prevents explosion and fire by removing a sealing mechanism of a pouch casing when the internal temperature increases due to overcharging, overdischarging or over-heating, and which exhausts internal gas before explosion and fire of the battery when the internal gas pressure excessively increases due to overcharging, overdischarging or internal short-circuit. The pouch type secondary battery includes an electrode assembly having positive and negative electrode plates with a separator interposed therebetween, and positive and negative electrode terminals extending from the positive and negative electrode plates, respectively, a pouch casing having a space in which the electrode assembly is housed to be sealed, a seal portion provided at the periphery of the space, and at least one of the positive and negative electrode terminals exposed to the seal portion, and at least one opening member disposed at the seal portion and made of a resin material having a lower melting point than a melting point of the seal portion of the pouch casing.

A flow battery includes a membrane having a thickness of less than approximately one hundred twenty five micrometers; and a solution having a reversible redox couple reactant, wherein the solution wets the membrane.

A separator includes a porous substrate having a plurality of pores; and a porous coating layer formed on at least one surface of the porous substrate and made of a mixture of a binder and a plurality of inorganic particles, wherein the binder includes a crosslinked binder. This separator may improve high temperature cycle performance, discharge characteristics and thermal resistance of an electrochemical device since the separator exhibits improved insolubility and impregnation to electrolyte and improved thermal resistance.

A redox flow battery having a high electromotive force and capable of suppressing generation of a precipitation is provided. In a redox flow battery 100, a positive electrode electrolyte and a negative electrode electrolyte are supplied to a battery cell including a positive electrode 104, a negative electrode 105, and a membrane 101 interposed between the electrodes 104 and 105, to charge and discharge the battery. The positive electrode electrolyte contains a manganese ion, or both of a manganese ion and a titanium ion. The negative electrode electrolyte contains at least one type of metal ion selected from a titanium ion, a vanadium ion, a chromium ion, a zinc ion, and a tin ion. The redox flow battery 100 can suppress generation of a precipitation of MnO2, and can be charged and discharged well by containing a titanium ion in the positive electrode electrolyte, or by being operated such that the positive electrode electrolyte has an SOC of not more than 90%. In addition, the redox flow battery 100 can have a high electromotive force equal to or higher than that of a conventional vanadium-based redox flow battery.

The present invention relates to a pouch type case having trimming portions formed on both sides or four corners thereof and a battery pack including the same. The trimming portions are formed on the corners of the pouch type case such that the trimming portions are indented toward an electrode assembly accommodating part to reduce a unit area so as to increase pressure applied to unit cells when a battery pack is assembled, thereby facilitating assembling of the battery pack and increasing cell capacity per unit area. Furthermore, the unit cells can be fixed in the battery pack more stably. The pouch type case reduces the unit area so as to include a relatively large number of cells for pressure applied to the cells when the battery pack is assembled to thereby increase the cell capacity.

A conductive silicon composite in which particles having a structure in which crystallites of silicon are dispersed in silicon dioxide are coated on their surfaces with carbon affords satisfactory cycle performance when used as the negative electrode material in a non-aqueous electrolyte secondary cell.

An integrated electronic device, and its method of manufacture, are provided. The integrated electronic device can include an electronic assembly, such as an active RFID assembly, that is electrically coupled to a thin printed flexible electrochemical cell. In one example, the electronic assembly and the electrochemical battery are provided on a single substrate. In one example method of manufacture, the entire cell to be made on a printing press to integrate the battery directly with the electronic assembly.

Provided herein are electrolytes for lithium-ion electrochemical cells, electrochemical cells employing the electrolytes, methods of making the electrochemical cells and methods of using the electrochemical cells over a wide temperature range. Included are electrolyte compositions comprising a lithium salt, a cyclic carbonate, a non-cyclic carbonate, and a linear ester and optionally comprising one or more additives.

A ceramic microporous polyolefin battery separator membrane, high in air permeability, low in shrinkage and improved temperature resistance addresses the safety requirements of lithium ion batteries. The separators made by the current invention consists of one or more polyolefin polymers and kaolin fillers comprised of aluminum oxide and silicon oxide. The membranes of current invention have a thickness of 5-200 microns, air permeability of 1-200 sec / 10 cc (Gurley seconds), and average pore diameter of less than 1 micron.

An energy storage stack of at least two surface-mediated cells (SMCs) internally connected in parallel or in series. The stack includes: (A) At least two SMC cells, each consisting of (i) a cathode comprising a porous cathode current collector and a cathode active material; (ii) a porous anode current collector; and (iii) a porous separator disposed between the cathode and the anode; (B) A lithium-containing electrolyte in physical contact with all the electrodes, wherein the cathode active material has a specific surface area no less than 100 m2 / g in direct physical contact with the electrolyte to receive lithium ions therefrom or to provide lithium ions thereto; and (C) A lithium source. This new-generation energy storage device exhibits the highest power densities of all energy storage devices, much higher than those of all the lithium ion batteries, lithium ion capacitors, and supercapacitors.

Disclosed is an anode material comprising a metal core layer capable of repetitive lithium intercalation / deintercalation; an amorphous carbon layer coated on the surface of the metal core layer, and a crystalline carbon layer coated on the amorphous carbon layer. The anode material not only maintains a high charge / discharge capacity, which is an advantage of a metal-based anode material, but also inhibits changes in the volume of a metal core layer caused by repetitive lithium intercalation / deintercalation in virtue of an amorphous carbon layer and a crystalline carbon layer, thereby improving the cycle life characteristics of cells.