The invention belongs to the field of manufacturing of
lithium batteries, and in particular relates to a nanometer
chitosan compound /
fiber composite diaphragm for a
lithium battery and a preparation method of the diaphragm. According to the invention, an ionic
polymer membrane material is formed by loading and combining of nanometer
chitosan compound particles and natural non-woven
fiber; the natural non-woven
fiber is adopted as a support, and the nanometer
chitosan compound / fiber composite diaphragm is obtained through rolling and
drying (at 40-50 EG C), wherein the thickness of the nanometer chitosan compound / fiber composite diaphragm is 5-60 micrometers. The nanometer chitosan compound / fiber composite diaphragm has excellent three-dimensional network conformation, and the
porosity is 80% or above; the nanometer chitosan compound / fiber composite diaphragm has no stress effect or form
memory effect. The nanometer chitosan compound / fiber composite diaphragm has
chemical stability, form dimensional stability,
thermal stability, insulativity and excellent physical
mechanical strength: fracture length(Km):4.3, and annular
pressure index (kgf / 152mm / Nm / g):11.92 in
electrolyte and under -40 DEG C to 150 DEG C, and has excellent adsorption affinity with the
electrolyte. The nanometer chitosan compound / fiber composite diaphragm has positive charge characteristics, and can provide a free channel for positive electric
lithium ions.