The invention discloses a ternary cross-linked hydrogel
electrolyte, a preparation method and applications thereof, wherein
polyvinyl alcohol, a bis-
catechol derivative,
boric acid,
potassium hydroxide and water are used as raw materials, a macromolecular cross-linking agent D-B is obtained through a
condensation reaction between the
boric acid and the o-hydroxyl in the bis-
catechol, and the
polyvinyl alcohol is cross-linked with the macromolecular cross-linking agent D-B to form a cross-linked
network structure, so that the rapid self-repairing hydrogel is obtained. According to the invention, the synthesis method has characteristics of simple process, mild condition, easy operation and no product post-treatment; by changing the use amounts of the
polyvinyl alcohol and the cross-linking agent, the hydrogel electrolytes with different self-repairing capacities, mechanical strengths and conductivities are obtained, and can generate
viscosity and lose
viscosity under electrical stimulation, wherein the
viscosity responsiveness can be regulated by regulating the electrical stimulation time and the
voltage; and the self-repairing hydrogel has important applications in the fields of soft robots, artificial ligaments, flexible devices,
surface response materials,
wall climbing robots, controllable coatings, automobile intelligent sensors and the like.