The invention discloses a synthesis method of a tricyclodecenyl
propionate perfume.
Petroleum coking byproducts
dicyclopentadiene and propionic acid are used as the raw materials, under the
catalysis of loaded
solid acid, the raw materials directly have
acetylation through
electrophilic addition to prepare crude tricyclodecenyl
propionate at one step, and meanwhile, a small amount of a
propionic anhydride guard catalyst is added to prevent the crude tricyclodecenyl
propionate from having
hydrolysis reaction with a small amount of
moisture in the material; then, propionic acid is recycled for applied mechanically, and the finished tricyclodecenyl propionate product is obtained through neutralizing, washing and rectification. According to the synthesis method, the
petroleum coking byproducts used as the raw materials are easily available, the reaction condition is moderate, the reaction conversion rate is high, the technology is easier to implement, the
discharge capacity of three wastes generated in the production process is low, the product yield is greatly increased, and the synthesis method belongs to technology of
cleaner production. In addition, the content of tricyclo[5, 2, 1, 0<2.6>]-3-
decene-9-yl acetate with delicate fragrance and fragrance and
sweetness of anise is more than 92%, and the product
green wood is pure, fine and mild in fragrance. The invention further provides a synthesis device special for the synthesis method of a tricyclodecenyl propionate perfume.