Provided are a molded article of a polymer electrolyte composition, which has an excellent proton conductivity even under low humidity and low temperature conditions, yet shows a high chemical stability, a good mechanical strength and a good fuel shutoff ability, and, when used in a solid polymer type fuel cell, can achieve a high output, a high energy density and a long-term durability, and a solid polymer type fuel cell using the same. The molded article of the polymer electrolyte composition, which comprises a block copolymer having one or more ionic group-containing hydrophilic segments (A1) and one or more ionic group-free hydrophobic segments (A2) together with an additive, is characterized in that the molded article forms a co-continuous or lamellar phase separation structure and the additive has a hydrophilic nature.