93 results about "Cyclooctane" patented technology

The invention relates to the photoinitiator technical field, in particular to an oxime ester photoinitiator and a preparation method thereof. A carbazole oxime ester photoinitiator has a structural general formula as the right formula, R=formula (1), n=0-5, m=3 or 4, R radical is aliphatic ketone with cyclane, the cyclane is cycloaliphatic ring from cyclopropane to cyclooctane, branched-chain aliphatic hydrocarbon connects the cyclane and the ketone, and the chain usually has 0-6 carbon atoms. The carbazole oxime ester photoinitiator with the structure is a brand-new compound with good photoinitiator performance, and solves the problem of poor sensitivity, thermal stability and solubility of the existing carbazole oxime ester photoinitiators.

The invention discloses a preparing method of blonanserin intermediate. The method is processed according to the following two steps of: (a) producing 3-(4-fluorophenyl)-3 oxo-propanamide through the reaction of 3-(4-fluorophenyl)-3 oxypropionitrile; and (b) obtaining 4-(4-fluorophenyl)-5,6,7,8,9,10-hexahydro cyclooctane pyridine-2-(1H)-ketone through the reaction between the 3-(4-fluorophenyl)-3 oxo-propanamide and cyclooctanone. The yield coefficient of the 4-(4-fluorophenyl)-5,6,7,8,9,10-hexahydro cyclooctane pyridine-2-(1H)-ketone prepared by using the method is increased to about 80 percent from 17 percent.

The invention relates to the photoinitiator technical field, in particular to an oxime ester photoinitiator and a preparation method thereof. A carbazole oxime ester photoinitiator has a structural general formula as the right formula, R=formula (1), n=0-5, m=3 or 4, R radical is aliphatic ketone with cyclane, the cyclane is cycloaliphatic ring from cyclopropane to cyclooctane, branched-chain aliphatic hydrocarbon connects the cyclane and the ketone, and the chain usually has 0-6 carbon atoms. The carbazole oxime ester photoinitiator with the structure is a brand-new compound with good photoinitiator performance, and solves the problem of poor sensitivity, thermal stability and solubility of the existing carbazole oxime ester photoinitiators.

3-[4-(Methylsulfonyl)-2-chlorobenzoyl]bicyclo[3.2.1]-octane-2,4-dione is an intermediate for synthesizing rice field herbicides. The invention discloses a A method for synthesizing 3-[4-(methylsulfonyl)-2-chlorobenzoyl]bicyclo[3.2.1]-octane-2,4-dione, comprising the following steps: taking norbornene as a raw material, After the addition and ring expansion reaction of dichlorocarbene, the hydrolysis reaction generates 3-chlorobicyclo[3.2.1]-3-octen-2-ol; then oxidizes allyl alcohol to obtain α,β-unsaturated ketone; Then react with sodium hydroxide under the action of a catalyst to obtain bicyclo[3.2.1]octane-2,4-dione, and finally undergo acylation reaction to obtain the target product. The raw materials and reagents used are cheap and easy to obtain, the synthesis method is simple and the reaction conditions are mild.

The invention belongs to the technical field of polyurethane, and particularly relates to heat-conducting polyurethane with excellent insulating and flame-retardant properties. The invention providesheat-conducting polyurethane with insulating and flame-retardant properties, which comprises the following components in parts by weight: 20-25 parts of polyisocyanate, 38-42 parts of polyol, 5-7 parts of a chain extender, 0.2-1 part of an antioxidant, 8-12 parts of a filler, 16-22 parts of a flame retardant and 0.2-0.6 parts of an auxiliary agent. The polyurethane disclosed by the invention has excellent insulating property (the insulating resistance is greater than 10<12> ohm cm), flame retardant property and heat-conducting property, and is low in hardness. The isocyanate, the polyhydric alcohol and the chain extender generate a polyurethane material, the flame-retardant effect of the polyurethane obtained through mutual cooperation of decabromodiphenyl ethane, bis (hexachlorocyclopentadiene) cyclooctane, Sb2O3 and zinc borate reaches UL94-V0, and aluminum oxide and silicon nitride are uniformly dispersed in the polyurethane, so that the hardness and the heat-conducting property ofthe polyurethane are improved.

The invention relates to thermohardenable epoxy resin-based compositions, (aminomethyl)-cyclohexane-propanamine and 1,4(5)-cyclooctane-dimethanamine.

The invention discloses a bromine-free flame-retardant nylon which comprises the following raw materials by weight percent: 40-85% of nylon, 12-25% of bis (hexachlorocyclopentadiene) cyclooctane, 3-10% of synergist, 0-35% of enhancer and 0-1% of antioxidant. The bromine-free flame-retardant nylon which is prepared from the specific raw materials has excellent flame retardance and good electrical properties. Because the flame-retardant synergist can be one or more of the zinc oxide, the diantimony trioxide, the zinc borate and the ferric oxide, the complete dependence on the diantimony trioxide is avoided. The problems that high flame retardance and low cost of the existing fire-retardant nylon are difficult to meet at the same time are solved.

The invention relates to the technical field of fine chemical engineering, and discloses a novel synthesis method of 2-butyl-1,2-benzothiazol-3-one. The method comprises the following specific steps:allowing N-butyl-2-methyl(thiobenzamide) to react with 1-chloromethyl-4-fluoro-1,4-diazoniabicyclo[2.2.2]octane bis(tetrafluoroborate) in the presence of N,N-dimethyl-formamide for six hours at 60 DEGC, so as to obtain 2-butyl-1,2-benzothiazol-3-one. Compared with the prior art, the method has the advantages that no metal ions or chlorine-containing toxic reagents are introduced, and the yield ishigh, the operation is simple, the influence on the environment is small, the potential industrial value is achieved, and the method is worthy of popularization and application.

The invention discloses an ultrathin wearing layer normal-temperature asphalt modifier and a preparation method thereof. The ultrathin wearing layer normal-temperature asphalt modifier is prepared from the following raw materials in parts by mass: 55-65 parts of cyclooctane, 30-35 parts of modified epoxy resin glue, 0.6-1 part of a dispersant and 5-10 parts of a coupling agent. The preparation method comprises the following steps: putting the cyclooctane, the modified epoxy resin glue and the dispersant into a stirring kettle according to a ratio, heating to 100+ / -5 DEG C, mixing, and uniformly stirring for 4-6 hours; further putting a coupling agent into the materials in the stirring kettle, and continuously stirring for 4-6 hours, thereby obtaining the product. By adopting the modifier,the rotary viscosity of asphalt at 60 DEG C can be reduced to 2.2-3.0Pa*s, and a mixed asphalt material can be spread for 1.0-2.0cm by using a common spreading machine within 50-60 DEG C; the construction temperature can be greatly reduced when being compared with a conventional construction temperature, and both the construction cost is reduced and the construction quality is ensured.

The invention discloses a method for preparing cyclooctanol and cyclooctanone through cyclooctane oxidation. The method comprises the following steps: (1) cyclooctane, a catalyst and an oxygen-containing gas are continuously delivered into an oxidation reactor, such that a reaction is carried out, wherein tail oxygen concentration is controlled at within 5% through controlling the input amount of the oxygen-containing gas, the usage amount of the catalyst is 5-10000ppm of the total weight of cyclooctane, a reaction temperature is 120-250 DEG C, a reaction pressure is 0.1-2.0MPa, and an oxidation reactor average retention time calculated according to liquid-phase substances is 0.4-6h, such that oxidation reaction liquid containing cyclooctanol and cyclooctanone is obtained; (2) the oxidation reaction liquid obtained in the step (1) is continuously delivered into a rectification tower; a light component comprising cyclooctane is obtained at the tower top, and is recycled in the oxidation reactor; cyclooctanol and cyclooctanone crude products are obtained at the tower bottom; and the crude products are respectively purified, such that cyclooctanol and cyclooctanone products are obtained. The method provided by the invention is green and environment-friendly, and has the advantages of mild reaction conditions, high product yield, and good selectivity.

A lithographic projection apparatus uses a volume of a second liquid to confine a first liquid to a space between the projection system and the substrate. In an embodiment, the first and second liquids are substantially immiscible and may be a cycloalkane, such as cyclooctane, decalin, bicyclohexyl, exo-tetrahydro-dicyclopentadiene and cyclohexane, another high-index hydrocarbon, a perfluoropolyether, such as perfluoro-N-methylmorpholine and perfluoro E2, a perfluoroalkane, such as perfluorohexane, or a hydrofluoroether; and water, respectively.

The present invention relates to the field of clean energy sources, particularly to an energy-saving synergetic combustion supporting agent, dimethyl ether synthesis fuel gas, and dimethyl ether synthesis fuel oil, wherein the raw materials of the energy-saving synergetic combustion supporting agent comprise ethyl acetate, camphor, castor oil, dicycloheptadiene, liquid-state paraffin, cyclooctane and methanol. According to the three classes of the dimethyl ether synthesis fuel gases and the dimethyl ether synthesis fuel oil for vehicles, the ordinary dimethyl ether is adopted as the mother liquor and modification is performed with the energy-saving synergetic combustion supporting agent, such that the problems of incomplete combustion, coking, carbon deposition, strong volatility, easy machine wear, low heat value, insufficient power and the like of the ordinary dimethyl ether adopted as the civilian use fuel gas, the vehicle fuel gas, the industrial fuel gas and the vehicle fuel oil are overcome.

The invention provides a method for preparing crystal form A of medicament 2-ethylpiperazine-4-(4-fluorobenzene)-5,6,7,8,9,10-hexahydro cyclooctane pyridine for treating atypical psychosis. The method is characterized by comprising the following steps of: ensuring that the 2-ethylpiperazine-4-(4-fluorobenzene)-5,6,7,8,9,10-hexahydro cyclooctane pyridine is dissolved in acetone, isopropanol or ethyl acetate by heating, and then obtaining the crystal form A through recrystallization. The total relevant material (PHLC determination) of the crystal form A of the 2-ethylpiperazine-4-(4-fluorobenzene)-5,6,7,8,9,10-hexahydro cyclooctane pyridine prepared through the method can reach lower than 0.3 percent, and single impurity is lower than 0.1 percent.

The invention discloses 1,2-oxinane pyrazolidone compounds and a preparation method and applications thereof. The 1,2-oxinane pyrazolidone compounds are shown in a formula III or a formula IV. The preparation method comprises the following steps: uniformly mixing a compound shown in a formula I and a compound shown in a formula II in a solvent and reacting in the presence of a phosphine catalyst to obtain the compounds shown in the formula III or the formula IV. The invention provides a new, simple and feasible method for synthesizing the 1,2-oxinane pyrazolidone compounds; the synthesized compounds are new compounds which are not reported in literatures; in the method disclosed by the invention, the cycloaddition reaction is adopted and the method belongs to the atom economic reaction; and the method uses organic phosphine as the catalyst rather than a transition metal catalyst, thus the product does not have heavy metal residual pollutants and has weeding effect on crabgrass and barnyard grass.

The invention relates to a cycloalkane catalytic oxidation method promoted by iron porphyrin. O2 is taken as an oxidant, Co (II) porphyrin and Mn (II) porphyrin are taken as main catalysts, and Fe (II) porphyrin is taken as a cocatalyst to carry out reacting at a temperature of 100-160 DEG C and pressure of 0.8-2.0MPa under a solvent-free condition to realize catalytic oxidation of cycloalkanes. The cycloalkanes mainly comprise cyclopentane, cyclohexane, cycloheptane, cyclooctane and cyclononane, and the corresponding oxidation products mainly comprise cycloalkyl alcohols, cycloalkyl ketones and alkyl diacids. The cycloalkane catalytic oxidation method has the advantages of high selectivity of cyclopentanone, cyclohexanol, cycloheptanone and cyclooctanone, small catalyst consumption and simple operation, and environmental friendliness is achieved by taking clean O2 as the oxidant. The disclosesd cycloalkane catalytic oxidation method promoted by iron porphyrin is a cycloalkane catalytic oxidation method with high product selectivity, simple operation and environmental friendliness.

In an optical recording medium, a recording layer is formed by coating a substrate with a solution of coloring matter comprising a coloring matter dissolved in a solvent comprising a mixture of cyclooctane and at least one hydrocarbon having 6 to 9 carbon atoms other than cyclooctane. The obtained optical recording medium enables suppressing the leakage of land prepit signal for address information into RF signal for recorded data at the time of recorded data reproduction, thereby attaining a lowering of error rate.

The invention discloses a pinene cyclopropane compound, which has the following structure as described in the specification named as 2, 7, 7-trimethyl tricyclo[4.1.1.0<2,4>]octane, or thestructure as described in the specification named as 6,6-dimethylspiro[bicyclo[3.1.1]heptane-2, 1'-cyclopropane]. The invention also discloses a preparation method and application of the pinene cyclopropane compound.

The invention relates to a construction method of anti-rutting and anti-stripping asphalt concrete pavement, which comprises the following steps: firstly, preparing modified asphalt of anti-rutting agent: adding 40-50 parts by weight of ethyl acetate into a flask,and increasing the temperature to 50-55 DEG C, adding 10-15 parts of cyclooctane and stirring for 5-10 minutes, increasing the temperature to 60-65 DEG C, dropwise adding 3-7 parts of hydroxyl-terminated polybutadiene with stirring at the same time of dropping, wherein the dropping acceleration is controlled at 3-5 ml / min, that anti-stripping agent of the invention remarkably improve the adhesion performance of the asphalt and other materials of the asphalt concrete, improve the Marshall stability of the asphalt concrete and the tensile strength of freeze-thaw splitting, and improves the service life of the asphalt concrete at the same time.

The invention provides a crystal form B of medicament 2-ethylpiperazine-4-(4-fluorobenzene)-5,6,7,8,9,10-hexahydro cyclooctane pyridine, which is characterized in that powder diffraction occurs in the positions of approximately 7.74+ / -0.2, 15.6+ / -0.2, 19.1+ / -0.2 and 31.64+ / -0.2 of a reflecting angle 2 theta through X-ray. The invention also provides a preparing method of the crystal form B, which is characterized by comprising the following steps of: ensuring that the medicament 2-ethylpiperazine-4-(4-fluorobenzene)-5,6,7,8,9,10-hexahydro cyclooctane pyridine is dissolved in ethanol by heating, and then obtaining the crystal form B through recrystallization.

The invention belongs to the technical field of gas separation and purification, and concretely relates to a flue gas desulfurization agent, a preparation method thereof, and a desulfurization method.The technical problems to be solved by the present invention comprise low desulfurization rate and low desorption rate of existing desulfurization agents. The flue gas desulfurization agent comprises5-50 parts by weight of a main absorbent, 0.1-20 parts by weight of an activator, 25-95 parts by weight of water, and an acid; the addition amount of the acid makes the pH value of the flue gas desulfurization agent be 4.0-5.0; the main absorbent is diazabicyclooctane; and the activator is at least one selected from hydroxyethylethylenediamine, diethylenetriamine, tetraethylenepentamine, triethylenetetramine and triethylenediamine. The flue gas desulfurization agent has the advantages of good sulfur dioxide absorption effect, high absorption speed, high absorption capacity, high desorption rate and low energy consumption in desorption, and has a desorption rate of 93.91-99.56%.

The invention discloses a detection kit which is used for on-site quick detection of fluorine ions in water and capable of eliminating reagent blank influences and a preparing method of the kit. In a faintly acid medium, fluorine in water reacts with 1-chloromethyl-4-fluorine-1,4-diazoniabicyclo-2,2,2-octane bis(tetrafluoroborate) to generate a blue complex, and the shade of the blue complex is in direct proportion to the concentration of fluorine ions; a comparison with a test tube is made after the color of a fluorine ion standard color chart with reagent blank eliminated and a blank tube color are overlaid, and the concentration of fluorine ions in a water sample to be tested is obtained. The detection kit is especially suitable for on-site quick detection of fluorine ions in water.

The invention belongs to the technical field of gas separation and purification, and concretely relates to a sulfur dioxide removal composition, and a preparation method and a desulfurization method thereof. The technical problems to be solved by the present invention comprise low desulfurization rate and low desorption rate of existing desulfurization agents. The sulfur dioxide removal composition comprises 5-50 parts by weight of a main absorbent, 0.1-20 parts by weight of an activator, 0.05-5 parts by weight of a corrosion inhibitor, 25-95 parts by weight of water, and an acid; the additionamount of the acid makes the pH value of the sulfur dioxide removal composition be 4.0-5.0; the corrosion inhibitor is composed of a metal oxide and monooleic acid imidazoline; the main absorbent isdiazabicyclooctane; and the activator is at least one selected from hydroxyethylethylenediamine, diethylenetriamine, tetraethylenepentamine, triethylenetetramine and triethylenediamine. The sulfur dioxide removal composition has the advantages of good sulfur dioxide absorption effect, high absorption speed, high absorption capacity, high desorption rate and low energy consumption in desorption, and has a desorption rate of 94.08-99.28%.

The invention relates to a method for preparing a solifenacin succinate ((3R)-1-azabicyclo [2.2.2] octane-3-yl (1S)-1-phenyl-3,4-dihydroisoquinoline-2-(1H)-carboxylate succinate). The method comprises the following steps: 1) preparing a compound (S)-1-phenyl-1,2,3,4-tetrahydroisoquinoline carboxylic acid ethyl ester of formula III from a compound (S)-1-phenyl-1,2,3,4-tetrahydroisoquinoline, serving as a raw material, of formula IV; 2) synthesizing a compound (3R)-1-azabicyclo [2.2.2] octane-3-yl (1S)-1-phenyl-3,4-dihydroisoquinoline-2-(1H)-carboxylate of formula II in an ionic liquid by using the compound (S)-1-phenyl-1,2,3,4-tetrahydroisoquinoline carboxylic acid ethyl ester of formula III; and 3) salifying the compound (3R)-1-azabicyclo [2.2.2] octane-3-yl (1S)-1-phenyl-3,4-dihydroisoquinoline-2-(1H)-carboxylate of formula II in an organic solvent to obtain the compound solifenacin succinate ((3R)-1-azabicyclo [2.2.2] octane-3-yl (1S)-1-phenyl-3,4-dihydroisoquinoline-2-(1H)-carboxylate succinate) of formula I. The preparation method has the advantages that the process is simple, the method is suitable for industrialized production, the yield of the product is high and the purity of the product is high.

A flame retardant additive composition having high thermal stability comprising (A) tetrabromocyclooctane or dibromoethyl-dibromocyclohexane or both, and (B) a halogenated aromatic epoxide and / or a mixture of halogenated aromatic oligomers, the halogen atoms in (B) are chlorine or bromine or both, and the weight ratio of (A) / (B) is about 95 / 5 to about 60 / 40. Components (A) and (B) may be included to provide flame retardancy to various polymers, particularly styrenic polymers, including foamed or expandable styrenic polymers, crystalline styrenic polymers, Impact-modified styrenic polymers and crystalline styrenic polymers, mixtures of impact-modified styrenic polymers. In all cases, the thermal stability of component (A) is significantly improved by the coexistence of component (B).

The invention discloses a method for preparing alkane base containing phosphine bridge dichloropentate cyclooctane. The method comprises the following steps: firstly, implementing reaction on an alkaline metal M with elemental phosphorus so as to obtain a reaction system containing M3P, secondly, implementing the system with alcohol and alkyl halide or halogenated naphthene so as to obtain a reaction system containing RPH2, and finally bridging RPH2 with 1,5-cyclooctadiene, thereby obtaining a final product of 9-R-9-phosphine bridge-[3.3.1]-dichloropentate cyclooctane, wherein R is an alkyl part in alkyl halide or alkyl or alcyl which is accordant to an alcyl part in alkyl halide. The method disclosed by the invention is simple and convenient in operation step, small in toxicity, low in production cost, high in final product yield, high in purity, wide in application range, and can be used as ligand applied to the field of catalysts of the terminal olefin industry.

The invention relates to a surface treating agent, in particular to a glass antifouling self-cleaning agent. The glass antifouling self-cleaning agent is prepared from the following raw materials in parts by weight: 30 to 45 parts of polymethyl methacrylate, 10 to 15 parts of di-hydroxyl terminated polysiloxane, 4 to 15 parts of trimethylolpropane, 5 to 10 parts of cyclooctane, 2 to 10 parts of phenylpropane and 10 to 20 parts of titanium dioxide. According to the glass antifouling self-cleaning agent disclosed by the invention, the surface is unlikely to be tainted with dust or other micro particles, and antifouling and self-cleaning functions are realized.

A novel catalyst-free oxidation method for cyclooctane includes the steps of adding the cyclooctane into a reaction vessel, carrying out a reaction at the temperature of 100-160 DEG C and under 0.8-2MPa for 3-48 hours, and after post-treatment of reaction liquid, performing separation to obtain oxidized products: suberic acid, pimelic acid, cyclooctanol and cyclooctanone. The novel catalyst-freeoxidation method for the cyclooctane has the advantages that the method is simple to operate and low in cost; no catalyst is used, and accordingly, transition metal pollution of the oxidized productsis prevented; clean O2 is taken as an oxidant, and environment protection is realized.

In an optical recording medium, a recording layer is formed by coating a substrate with a solution of coloring matter comprising a coloring matter dissolved in a solvent comprising a mixture of cyclooctane and at least one hydrocarbon having 6 to 9 carbon atoms other than cyclooctane. The obtained optical recording medium enables the suppression of leakage of the land prepit signal for address information into the RF signal for recorded data at the time of recorded data reproduction, thereby attaining a lowering of error rate.

The invention discloses a degradable photoresist resin monomer synthesized from trimethyl bicyclo[2.2.2]octanedione and a synthesis method of the resin monomer, and relates to the field of photoresistresin, the structural formula of the resin monomer is shown in the specification, R1 is saturated alkane or cycloalkane, R2 is hydrogen or methyl, and the synthesis method is as follows: under the protection of inert gas, making 1, 3, 3-trimethyl bicyclo[2.2.2]octane-5, 5-dione (I) react with an alkyl Grignard reagent or a cycloalkyl Grignard reagent, adding water for quenching after the reactionis finished, carrying out aftertreatment and purification to obtain an intermediate (II), reacting the intermediate (II) with acryloyl chloride or methacryloyl chloride under an alkaline condition, and carrying out aftertreatment and purification to obtain the resin monomer (III). Polymer resin formed by polymerizing the resin monomer provided by the invention and other resin monomers has betteretching resistance, is beneficial to improving the edge roughness of a developed pattern, and greatly improves the resolution of a photoetching pattern.