The invention belongs to the technical field of physical and chemical test, and concretely relates to an apparatus for measuring the PCT curve of a material by using a solid state proton conductor, and a method thereof. The apparatus for measuring the PCT curve of a material by using a solid state proton conductor comprises a solid state proton conductor container, a DC source, a voltmeter, a transfer switch and an electric resistance furnace; when the material is measured, a DC voltage is applied to two electrodes of a proton conductor to measure the change curve of the current intensity of a circuit with the time, hydrogen in atmosphere electro-migrates to a material to be measured and capable of adsorbing hydrogen, and the hydrogen voltage can be calculated by measuring the electromotive force of a hydrogen concentration cell according to the principle of a conductor hydrogen concentration cell; and the content of hydrogen in the material can be calculated by measuring the change curve of the current according to a principle of charge conservation. The apparatus and the method enables the hydrogen pressure and the hydrogen content which are difficult to measure to be directly converted into electric signals, so it is easy to acquire and analyze data, thereby the apparatus and the method have the advantages of fast measurement, low cost and reliable data.