42results about How to "Stripping is easy" patented technology

The invention relates to a technology for separating rare earth element by extraction system added with modifier, which comprises using potassium dihydrogen phosphate and its sulfo-derivative as the extractant, wherein the potassium dihydrogen phosphate or its sulfo-derivative is bis-(2-ethylhexyl)phosphate (P204), 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (P507), bis(2, 4, 4-trimethylpentyl)phosphinic acid (Cyanex272), bis(2, 4, 4-trimethylpentyl) dithiophosphinic acid (cyanex301), bis(2, 4, 4-trimethylpentyl) monothiophosphinic acid (Cyanex302), using ROH as addition agent, R is C4-C10 alkyl, using alkane or aromatic hydrocarbon as thinning agent, forming 1.0-1.5M potassium dihydrogen phosphate - 5-30% ROH - alkane or aromatic hydrocarbon extraction architecture, using chlorinated or nitrated rare earth solution as feed liquid, using hydrochloric acid or nitric acid as inverse acid, determining single rare earth in raffinate or strip liquor through EDTA titration, and determining mixed rare earth through plasma atom emission spectrometric method.

The invention provides a process method for separating and purifying rare earth elements by solvent extraction. The method takes a mixed rare earth sulfate solution obtained from a rare earth ore treated by sulphuric acid as a raw material, directly adopts a nonsaponifiable P507 extraction agent or a synergistic extraction agent containing the P507 to completely extract rare earth in a material liquid into an organic phase, and then takes the organic phase as a rare earth material liquid to extract, separate and purify the rare earth or directly backextract to produce mixed chlorinated rare earth or rare earth nitrate. The process method is simple and flexible, does not saponify the organic phase during the extraction and separation process, does not produce ammonia nitrogen waste water, is easy to backextract middle and heavy rare earths, and has less consumption of acid and base and low production cost.

The invention relates to a technological method for extracting and separating quadrivalent cerium, thorium, fluorine and less-cerium trivalent rare-earth from rare earth sulfate solution. The rare earth sulfate solution, which is obtained through processing the rare-earth ores and contains high-valence cerium, the fluorine, the thorium and ferrum, is used as raw material; synergistic extraction agent basing on P507 and P204 is adopted for extracting and separating; the cerium (1V), the thorium, the fluorine, and the ferrum are extracted into an organic phase, then selective washing and back extraction are performed step by step to obtain three products that are the cerium, the fluorine, and the thorium, the trivalent rare-earth is left in a water phase, and then unsaponifiable P507 or thesynergistic extraction agent basing on P507 is adopted to perform multistage fractional extraction to separate single rare earth elements. The technological method has the characteristics that the synergistic extraction agent basing on P507 and P204 is adopted, the thorium is easy to perform the back extraction, and extraction capacity is large, and the emulsification is not generated during the extraction process; the cerium (1V), the thorium, the fluorine, the ferrum and the trivalent rare-earth are extracted and separated in the same extraction system; both extraction and the separation adopt unsaponifiable extraction agent, and ammonia-nitrogen wastewater is not generated; in addition, the thorium and the fluorine are recovered as products, and the pollutions caused by thorium-containing waste residue, fluoride-containing wastewater and the ammonia-nitrogen wastewater are eliminated from headstream. Therefore, the technological method has the advantages of simple procedures, greenenvironmental protection, and low manufacturing cost.

The invention relates to a technological method for extracting and separating quadrivalent cerium, thorium, and less-cerium trivalent rare-earth from rare earth sulfate solution. The rare earth sulfate solution, which is obtained through processing the rare-earth ores and contains the thorium and high-valence cerium, is used as raw material; synergistic extraction agent basing on P507 and P204 is adopted for extracting and separating; the cerium (4) and the thorium are extracted into an organic phase, then selective washing and back extraction are performed step by step to obtain the products including pure cerium and pure thorium, the trivalent rare-earth is left in a water phase, and then unsaponifiable P507 or the synergistic extraction agent basing on P507 is adopted to perform multistage fractional extraction to separate single rare earth elements after impurity removal. The technological methodn has the characteristics that the synergistic extraction agent basing on P507 and P204 is adopted, the thorium is easy to perform the back extraction, and extraction capacity is large, and the emulsification is not generated during the extraction process; the cerium (4), the thorium and trivalent rare-earth are extracted and separated in the same extraction system; both extraction and the separation adopt unsaponifiable extraction agent, and ammonia-nitrogen wastewater is not generated; in addition, the thorium is recovered as products, and the pollutions caused by thorium-containing waste residue and the ammonia-nitrogen containing wastewater are eliminated from headstream. Therefore, the technological method has the advantages of simple procedures, green environmental protection, and low manufacturing cost.

The invention provides a method for extracting palladium from high-level liquid waste, which belongs to the technical field of radioactive waste after treatment. The high-level liquid waste adopts nitric acid system, and the method comprises the following concrete steps of: a, adequately mixing the high-level liquid waste with extract phase; b, separating extract phase containing palladium from the mixture after extraction equilibrium; c, washing the separated extract phase containing palladium; d, repeating steps b and c 1 to 5 times; e, adding stripping agent to the washed extract phase containing palladium to perform back extraction; and the method is characterized in that triisobutyl phosphine sulfide (TiBPS) is adopted as extracting agent, and thinning agent is added for preparing the extract phase. The method has the following advantages: a, the extracting ratio of palladium in the nitric acid system is high by using TiBPS as extracting agent; b, the concentration range of adaptable nitric acid is wide, Purex process can be directly linked, mixtion is not required in the extraction process, and waste minimization and processing equipment simplification can be realized; c, the selectivity is good; and d, back extraction is easy.

The invention discloses benzo-heterocyclic type compounds and application thereof, and particularly provides a compound shown in a formula (I) in the text. An extraction agent composed of the type ofcompounds has a high extraction rate towards lithium ions and a high separation coefficient towards lithium isotopes, and can realize efficient extraction and separation of the lithium isotopes. Please see the specification for the formula (I).

The invention discloses a heavy rare earth and light rare earth separation method and a heavy rare earth and light rare earth separation extraction agent. The method includes the step of conducting extraction on a rare earth element and nitrate mixed aqueous solution through imidazolyl ionic liquid where the extraction agent is dissolved or chloroform where the extraction agent is dissolved or a 1-pentanol diluent where the extraction agent is dissolved so that heavy rare earth elements can be extracted and yttrium and light rare earth elements can be kept in the aqueous phase, wherein the extraction agent which is used is 1-methylimidazole shown in the chemical formula 1 or 2-methylimidazole shown in the chemical formula 2 when the diluent is the imidazolyl ionic liquid or the chloroform, and the extraction agent which is used is 2-methylimidazole shown in the chemical formula 2 when the diluent is the 1-pentanol diluent. The heavy rare earth and light rare earth separation method and the heavy rare earth and light rare earth separation extraction agent have the advantages that the extraction agent is low in price and can be easily obtained, the extraction system is simple, the extraction efficiency is high, the amount of the extraction agent which is used is small, and the specificity is strong.

The extraction and separation method for rare-earth element comprises: with rare-earth solution contained a plurality of rare-earth elements as material, preparing mixed extractant with the non-saponifiable P204 and one or two from P507, P229, P350, TBP, C272, C301, C302 and HEOPPA; in the mixed solution with rare-earth sulfate solution, or rare-earth sulfate and rare-earth chloride solution and rare-earth nitrate solution, extracting and separating rare-earth elements. This invention eliminates saponification to overcome pollution, reduces acidity to improve rare-earth concentration, and decreases the main material consumption more than 30% compared with the technique with NH4HCO3 and P507.

The invention discloses an extraction system and application thereof. The extraction system comprises a compound and a modifier shown in the formula (I), and the molar ratio of the compound shown in the formula (I) to the modifier shown in the formula (I) is 0.2:1-5:1. When the extraction system contains diluents, the application preferably comprises the following steps that an organic phase is used for extracting a lithium containing solution obtained after waste battery wet processing, and an organic phase loaded with lithium ions is obtained. According to the extraction system and the application thereof, the recycling rate of the extraction process is high, the balance time is short, reverse extraction and operation are easy, and good practicability and economical efficiency are achieved. Through the extraction system, rapid and efficient extraction of the lithium ions can be achieved; and as is shown in the embodiment, the single-level extraction recycling rate of the lithium canreach 89%, and the multi-level total recycling rate can reach 99%. The formula is shown in the specification.

The invention relates to a preparation method of low-thorium lutetium oxide, comprising the following steps of: firstly carrying out 3-10 level of primary countercurrent extraction on lutetium oxide extracted from a solvent as a raw material by adopting an isooctanol or kerosene solution of 0.5-2.0mol / L of N235 extracting agent, and then carrying out 3-10 level of countercurrent washing selectivebackextraction on organic phases of extracted thorium by adopting 0.1-2mol / L of alkali abluent solution; then separating the low-thorium lutetium oxide by a kerosene solution of 0.1-1.0mol / L of another extracting agent, carrying out 3-10 level of countercurrent washing selective backextraction on the organic phases of the extracted thorium by adopting 0.5-2mol / L of acidic abluent solution, carrying out oxalic precipitation, washing and dehydration on aqueous-phase lutetium oxide after thorium removal, and burning at the condition of 750-1000 DEG C to obtain a product, namely, the low-thorium lutetium oxide. In the method, rare earth and thorium are thoroughly separated, and the organic extracting agent is low in price.

The invention discloses a pyridinylphosphoramide compound and its preparation method and its application as a nickel-cobalt extractant. Pyridine-4-formaldehyde and alkyl primary ammonia are subjected to an amaldehyde condensation reaction to generate a Schiff base intermediate. Addition reaction between Schiff base intermediate and dialkyl phosphite to obtain pyridyl phosphoramide compound. The preparation method has the advantages of environmental protection, mild conditions, simple process, short process, etc.; the synthesized pyridyl phosphoramide compound is combined with P204 as a nickel-cobalt synergistic extractant for the extraction and separation of cations containing nickel, cobalt, and magnesium manganese. It has the characteristics of high extraction capacity, short phase separation time, excellent extraction and stripping performance, etc., and has a good industrial application prospect.

The invention relates to the technical field of separation of iron, nickel and chromium, in particular to a three-phase system and method of sugar analysis for extracting and separating iron Fe(Ⅲ), nickel Ni(II) and chromium Cr(Ⅲ), which can be used for waste Separation of iron, nickel and chromium in slag and waste liquid. The present invention first selects saponified P507 as surfactant, n-pentanol as co-surfactant, and n-heptane as organic phase to construct a microemulsion; then, constructs a three-phase system of saponified P507 microemulsion, acetonitrile and sugar solution, and creatively proposes A sugar precipitation three-phase system and method for extracting and separating iron, nickel and chromium is proposed, and the method can better realize the separation of iron, nickel and chromium. The advantages of the present invention are that the preparation process of the three-phase system is simple, and the amount of P507 and organic phase is less, the operation is simpler, the equipment is friendly, the separation speed is fast, the separation efficiency is high, the stripping step is simple, and the organic phase and sugar after stripping All can be recycled and easily used in industry on a large scale.

The invention belongs to the field of hydrometallurgy and in particular relates to a method for extracting iron and vanadium from vanadium-titanium magnetite concentrates. The method comprises the following steps of: 1) carrying out acid dissolution and leaching on vanadium-titanium magnetite concentrates and hydrochloric acid; 2) oxidizing Fe<2+> in acid leaching solution obtained in the step 1) into Fe<3+> with an oxidizing agent; 3) extracting iron from the oxidized acid leaching solution obtained in the step 2) with an extracting agent to obtain an organic phase and vanadium-containing raffinate; (4) carrying out back extraction on the organic phase obtained in the step 3) to obtain an extracting agent and an iron-containing acid solution; 5) calcining the iron-containing acid solution obtained in the step 4) to obtain hydrochloric acid and iron trioxide; and 6) treating the vanadium-containing raffinate obtained in the step 3) to obtain ammonium vanadate or vanadium pentoxide. The method has the advantages that the added values of products are high, the recovery rate of vanadium is greatly increased, and the environmental pollution can be avoided.

The invention discloses a method for comprehensively recovering rare earth from phosphate rock containing rare earth. The rare earth-containing phosphate rock is leached with nitric acid solution, and then the solid-liquid separation is obtained to obtain the rare earth-containing solution. It does not need to be neutralized. The rare-earth-containing solution can be extracted-back-extracted under strong acid conditions to recover rare earth elements. By adding nitric acid for leaching, the presence of phosphoric acid in the leaching solution increases the acidity of the leaching solution, which further promotes the extraction efficiency of rare earths. The extraction efficiency can reach more than 98%, and the phosphoric acid does not extract, and the impurity ions are almost not extracted. It realizes good separation of phosphorus and rare earth in phosphate rock, can broaden the product chain of nitrophosphate fertilizer enterprises, and creates a road of comprehensive recovery and utilization of rare earth resources, which is beneficial to the utilization of rare earth-containing phosphate rock resources.

The invention discloses a benzoheterocyclic compound and its application. Specifically, the present invention provides the compound shown in the formula (I) herein, the extraction agent composed of this type of compound has a high extraction rate for lithium ions, has a high separation coefficient for lithium isotopes, and can realize efficient extraction and separation of lithium isotopes .