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40results about How to "High electro-optic coefficient" patented technology

Dendrimer Based Terahertz Generator

A high efficiency electro-optic dendrimer based technology for nanophotonic integrated circuit devices is presented. In particular, a high power terahertz (THz) source is implemented using an electro-optic dendrimer via electro-optic rectification. Electro-optic rectification provides inherent power scalability, because, pump-THz conversion is not limited either by emission saturation or by heat dissipation. Low dielectric loss and high electro-optic coefficient of dendrimer along with a waveguide structure provides higher output power and tunable THz power generation. A dendrimer fiber array is also disclosed by means of which the input / output signals are connected to multiple components and devices.
Owner:APPLIED RES & PHOTONICS

Second-order nonlinear optical chromophore with D-pai-A structure and synthetic method and use thereof

The invention relates to the field of organic second-order nonlinear optical materials, in particular to a second-order nonlinear optical chromophore with a D-pai-A structure of a high-performance aminobenzene electron donor, a thiophene pai electron bridge and a tricyano-pyrrolidine electron acceptor and a synthetic method and a use thereof. The thiophene pai electron bridge synthesized in the synthetic method of the invention can effectively improve the conjugate transmission capacity of electrons, reduce the interaction force among molecules and improve the first-order molecular hyperpolarizability (beta) of the molecules of the chromophore. The second-order nonlinear optical chromophore with the high-performance D-pai-A structure has important application prospects in the field of signal modulation as the second-order nonlinear optical material.
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI

Dendrimer based terahertz generator

A high efficiency electro-optic dendrimer based technology for nanophotonic integrated circuit devices is presented. In particular, a high power terahertz (THz) source is implemented using an electro-optic dendrimer via electro-optic rectification. Electro-optic rectification provides inherent power scalability, because, pump-THz conversion is not limited either by emission saturation or by heat dissipation. Low dielectric loss and high electro-optic coefficient of dendrimer along with a waveguide structure provides higher output power and tunable THz power generation. A dendrimer fiber array is also disclosed by means of which the input / output signals are connected to multiple components and devices.
Owner:APPLIED RES & PHOTONICS

High-speed wavelength tuning laser made of lithium niobate material

The invention discloses a high-speed wavelength tuning laser made of lithium niobate material. The laser comprises a lithium niobate thin film chip (i.e. LNOI chip); a first spot size converter (SSC)arranged on the lithium niobate thin film chip; and a composite resonant cavity connected with the first spot size converter, wherein the composite resonant cavity adopts the lithium niobate material.The composite resonant cavity adopts the lithium niobate material and has good electro-optic effect. The electro-optic coefficient r33 of the X-cut lithium niobate thin film can reach 30.8 pm / V whenthe optical mode propagates along the y direction and the electric field direction is the z direction. The wavelength tuning speed of the laser can reach ns level and the tuning range can be more than10nm so that the laser can be used in an optical switching network to reduce network congestion and enable information transmission to be faster.
Owner:ZHEJIANG UNIV

Organic second-order nonlinear optical chromophore having double-donor structure, and synthesis method and application thereof

The invention provides an organic second-order nonlinear optical chromophore having a double-donor structure. The organic second-order nonlinear optical chromophore having the double-donor structure has a structure as shown below in the specification, wherein R1 is methyl or trifluoromethyl; and R2 is alkyl or phenyl. After an electron donor having the double-donor structure, a conjugate pi electron bridge and an electron acceptor, which are used by the invention, are combined together, the intramolecular electron transmission capability is enhanced, and the electrooptic coefficient can be increased. Besides, the synthesized chromophore has the double-donor structure, thereby effectively reducing the intermolecular interaction force. The organic second-order nonlinear optical chromophore is doped with amorphous polycarbonate to realize synthesis of a polymer film, and the polymer film can be used as a synthetic optical signal modulation material.
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI

Sodium bismuth titanate-barium titanate lead-free transparent electro-optic ceramic and preparation method thereof

The invention relates to a sodium bismuth titanate-barium titanate lead-free transparent electro-optic ceramic and a preparation method thereof; the electro-optic ceramic has the chemical composition of (1-x)(Na0.5Bi0.5)TiO3-xBaTiO3, wherein 0.05<=x<=0.08; the preparation method includes the steps: batching Na2CO3, Bi2O3, TiO2 and BaCO3 as raw materials according to the stoichiometric ratio, carrying out ball milling, and mixing evenly to obtain a powder; carrying out heat preservation on the powder for 2-4 h at the temperature of 850-950 DEG C, and thus obtaining a synthetic material; crushing the synthetic material, sieving, carrying out ball milling, adding a binder, and carrying out press molding to obtain a blank; next, placing the blank in a sintering furnace, heating up from room temperature to 800 DEG C-850 DEG C at the speed of 200 DEG C-250 DEG C / h, and carrying out heat preservation for 0.5-1.5 h; and heating up at the speed of 100 DEG C / h and gradually pressurizing to 200-250 MPa, followed by keeping the pressure unchanged, heating up to 1000 DEG C-1050 DEG C, then carrying out heat preservation for 2 h, then heating up to 1100 DEG C-1200 DEG C at the speed of 50 DEG C / h, carrying out heat and pressure preservation for 8-24 h, then releasing the pressure, cooling to 900 DEG C at the speed of 100 DEG C / h, and cooling to room temperature along with a furnace, wherein oxygen is introduced with the flow quantity of 3-5 L / minute when the heating is started and introduction of oxygen is stopped when the pressure is released.
Owner:中国科学院上海硅酸盐研究所苏州研究院

Integrated optic chip for three-axis fiber optic gyroscope

The invention provides an integrated optic chip for a three-axis fiber optic gyroscope, in which an input optical waveguide, a first direction coupler, a second direction coupler, a third direction coupler, an optical waveguide attenuator with a Mach-Zehnder structure, an output optical waveguide, a first Y-branch coupler, a second Y-branch coupler, a third Y-branch coupler and a designed metal electrode are integrated. The chip is prepared by low-loss organic polymer optical waveguide material and organic polymer electrooptical material. In comparison with a conventional discrete device optical system, a plurality of waveguide devices with key functions are uniformly integrated on the chip; the multifunctional chip can implement functions, such as modulation, attenuation, splitting, wave combination and the like, on light beams; and the multifunctional chip has the advantages of excellent consistency, high stability, low power, small volume, light weight and the like, and can be used for developing the three-axis fiber optic gyroscope.
Owner:SOUTHEAST UNIV

High-speed low-voltage electrooptical modulator based on lithium niobate-silicon wafer

ActiveCN111175999ACompact demultiplexing functionIncrease energy distributionNon-linear opticsModulation functionHigh energy
According to the high-speed low-voltage electrooptical modulator based on the lithium niobate-silicon wafer, the silicon wafer is located above the lithium niobate wafer, the silicon waveguide is etched to form the lithium niobate-silicon mixed waveguide, and the structure of the silicon waveguide is changed to enable light waves to have different energy distributions in the lithium niobate-silicon mixed waveguide. When the silicon waveguide has more energy distribution, the silicon waveguide is suitable for realizing a compact wave splitting function, a wave combining function and a thermo-optical modulation function; and when the lithium niobate waveguide has higher energy distribution, the lithium niobate waveguide is suitable for realizing a high-speed and low-voltage electro-optical modulation function. The advantages of a lithium niobate material platform and a silicon material platform are brought into play respectively, and the method is suitable for high-speed low-voltage electro-optical modulation.
Owner:SHANGHAI JIAO TONG UNIV +1

Photoelectric AC/DC voltage transducer based on Pockels effect

The invention belongs to the technical field of electric power detection and provides a photoelectric AC / DC voltage transducer based on the Pockels effect. The photoelectric AC / DC voltage transducer is not affected by environment temperature change, measurement precision is high, signal transmission is convenient, safety performance is high, power supply is not needed at a measurement point, and optical fiber signal transmission is immune to electromagnetic interference. The photoelectric AC / DC voltage transducer comprises a laser source, a transducer component, transmission fiber, a photoelectric detector and a backward-stage signal processing system, wherein the transducer component comprises a laser collimator I, a polarizer, a 1 / 4 wave plate, a crystal, an analyzer and a laser collimator II which are arranged along an optical path in sequence, the crystal is a cuboid, the length direction of the crystal is the light passing direction, the upper surface and the lower surface, perpendicular to the light passing direction, of the crystal are plated with metal layers serving as detection electrodes, the metal layers are used for loading voltage to be measured, the voltage direction is perpendicular to the light passing direction, and the backward-stage signal processing system obtains the voltage to be measured through a signal output by the photoelectric detector.
Owner:CHONGQING UNIV

Electro-optical polarized polymer containing nano ferroelectric crystals, and preparation method

In the method, ferroelectric nonocrystal is distributed uniformly in transparent film polymer as ferroelectric material is made from strontium barium niobate, lead zirconate titanate, lanthanum doped lead zirconate titanate, BaTiO3, LiNbO3, or LiTaO3 with nanocrystal particle diameter of 20-80 nm; polymer base material is made from polymethyl methyl acrylate, polycarbonate, polyimide sort and thermoplastic polyamic acid. The prepare process includes polymerizing ferroelectric nanocrystal in the polymer in polymerization procedure of dissolving nanocrystal and polymer in polar solvent and depositing film by soaking or spinning.
Owner:NANJING UNIV

Rubidium lithium titanium germanate compound, rubidium lithium titanium germanate non-linear optical crystal and preparation methods and application thereof

The invention discloses a rubidium lithium titanium germanate compound, a rubidium lithium titanium germanate non-linear optical crystal and preparation methods and application thereof. A chemical formula of the rubidium lithium titanium germanate compound is Rb4Li2TiGe4O13; a chemical formula of the rubidium lithium titanium germanate non-linear optical crystal is Rb4Li2TiGe4O13; the rubidium lithium titanium germanate non-linear optical crystal is non-centrosymmetrical structure, belongs to the tetragonal system and has a space group P4nc, is prepared by adopting a co-solvent method. The invention further discloses the rubidium lithium titanium germanate non-linear optical crystal to application of a laser non-linear optical compound functional device, an electro-optical crystal device or a laser device. The rubidium lithium titanium germanate non-linear optical crystal provided by the invention has a relatively great non-linear optical effect, a high electro-optical coefficient anda wide transmission range, has good mechanical properties and does not deliquesce; the frequency-doubled effect is 3 to 5 times of KDP (potassium dihydrogen phosphate).
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI

Electro-optical polymer waveguide mode conversion switch for mode multiplexing technology

InactiveCN110174782AFast electro-optic responseFast mode switching speedNon-linear opticsGratingOptical polymers
The invention discloses an electro-optical polymer waveguide mode conversion switch for a mode multiplexing technology, and is applied to the field of optical communication. Aiming at the problems ofinsufficient stability, structure complexity, relatively slow conversion speed, insufficient working wavelength range and the like of an existing reconfigurable mode converter, a mode switch of voltage control and electric tuning is achieved by electro-optical effects of a long-period grating structure and an electro-optical polymer, and a novel electro-optical mode converter is constructed; and the device has the advantages of rapid conversion speed, low half-wave voltage, low cost and the like and has good actual application value.
Owner:UNIV OF ELECTRONICS SCI & TECH OF CHINA

Organic second-order nonlinear optical double chromophore catalyzed and prepared by using Cu(I) as well as preparation method and application thereof

The invention discloses an organic second-order nonlinear optical double chromophore prepared by Cu(I) catalyzed click reaction. The organic second-order nonlinear optical double chromophore has a structure shown as a formula (I) in description, wherein R1 is hydrogen, fluorine, chlorine, bromine, iodine, hydroxyl, alkyl or alkoxy; R2 is a alkyl chain, acyl or alkoxy; R3 is an alkyl chain or acyl;R4 is chromophores with a D-pi-A structure shown as formulas (2) to (7) as in the description, wherein X represents a connection position of double chromophore and the chromophore of the D-pi-A structure; R5 is an alkyl chain; R6 is methyl or trifluoromethyl; R7 is alkyl, phenyl, substituted phenyl, substituted thienyl or hydroxyalkyl; R8 is hydrogen, alkyl, alkoxy, alkyl sulphanyl, hydroxyalkylor hydroxyalkyl protected by silane; R9 is hydrogen, alkyl, alkoxy, alkyl sulphanyl, hydroxyalkyl or hydroxyalkyl protected by silane; R10 is alkyl, hydroxyalkyl or hydroxyalkyl protected by silane.
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI

(Bi1-x-yLnxCey)3TeBO9 compound, (Bi1-x-yLnxCey)3TeBO9 nonlinear optical crystal, (Bi1-x-yLnxCey)3TeBO9 scintillation crystal, preparation method and application thereof

The invention discloses a (Bi1-x-yLnxCey)3TeBO9 compound, (Bi1-x-yLnxCey)3TeBO9 nonlinear optical crystal, (Bi1-x-yLnxCey)3TeBO9 scintillation crystal, a preparation method and an application thereof. The compound crystal with its chemical formula being Bi3TeBO9 is a non-centrosymmetrical structure and belongs to the hexagonal system, and space group is P63. The invention also discloses (Bi1-x-yLnxCey)3TeBO9 compound crystal doped with different rare earth elements, wherein Ln=La-Lu or Y; X is less than 1 and greater than or equal to 0; and Y=0 or Y is less than or equal to 0.2 and greater than or equal to 0.0001. By a flux method, high-quality and large-sized (Bi1-x-yLnxCey)3TeBO9 crystal can grow, has good mechanical property is good, is deliquescence-free, and can be used for manufacturing nonlinear optical devices. A laser manufactured by the use of the crystal can be used in fields of spectroscopy, biomedicine, military and the like. The material of the invention also can be used as high-density fast-attenuation scintillation crystal.
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI

Tunable FP optical filter based on lithium niobate film

InactiveCN112394543AMake full use of the photoelectric effectHigh electro-optic coefficientNon-linear opticsOptical coefficientLithium niobate
The invention belongs to the technical field of thin-film narrow-band filters, and particularly relates to a tunable FP optical filter based on a lithium niobate film. The tunable FP optical filter comprises a substrate, a first metal layer, an electro-optic tunable lithium niobate film light transmission layer and a second metal layer. By controlling the voltage between the first metal layer andthe second metal layer, the central wavelength of the tunable FP optical filter of the present invention of a tunable filter can be adjusted. The lithium niobate film is used as the cavity material ofa half-wave resonant cavity in an optical interference film, has a wide light transmission window, a high electro-optical coefficient and good temperature stability, can greatly reduce the optical loss of the narrow-band tunable filter, and realizes the tunable central wavelength. According to the invention, the problems of large optical loss, low tuning speed, temperature sensitivity and the like of an existing MEMS thermo-optical tuned filter can be effectively improved, and the MEMS thermo-optical tuned filter has a good application prospect in the field of optical sensing.
Owner:TIANJIN JINHANG INST OF TECH PHYSICS

Poled fiber, a method of fabricating the poled fiber, and a dispersion compensator

A method of fabricating a poled fiber and a dispersion compensator. The method including patterning to cover an etching-resistant material on the body portions of the cladding and on one end or both ends of the optical fiber excluding the portions to be grooved in the longitudinal direction, etching the bare portions of the cladding excluding the portions covered with the etching-resistant material, evaporating electrodes on the etched portions and applying a voltage to the electrodes, and inducing periodic poling generating optical phenomenon of the second-order nonlinearity to the optical fiber through the patterned electrodes. The compensator including a periodic poled fiber to generate a phase conjugate wave of a difference frequency between a pump light and a signal light received from a fiber coupler, and a filter to pass the phase conjugate wave coming out from the periodic poled fiber.
Owner:ELECTRONICS & TELECOMM RES INST

Electro-optical polarized polymer containing nano ferroelectric crystals, and preparation method

In the method, ferroelectric nonocrystal is distributed uniformly in transparent film polymer as ferroelectric material is made from strontium barium niobate, lead zirconate titanate, lanthanum doped lead zirconate titanate, BaTiO3, LiNbO3, or LiTaO3 with nanocrystal particle diameter of 20-80 nm; polymer base material is made from polymethyl methyl acrylate, polycarbonate, polyimide sort and thermoplastic polyamic acid. The prepare process includes polymerizing ferroelectric nanocrystal in the polymer in polymerization procedure of dissolving nanocrystal and polymer in polar solvent and depositing film by soaking or spinning.
Owner:NANJING UNIV

Poling method for relaxor ferroelectric single crystal as nonlinear optical material

The invention discloses a poling method for a relaxor ferroelectric single crystal as a nonlinear optical material. The method comprises an annealing process and a polarization process; the relaxor ferroelectric single crystal comprises a binary (1-x)Pb(Mg1 / 3Nb2 / 3)O(3-x)PbTiO3 system and a ternary (1-x-y)Pb(In1 / 2Nb1 / 2)O(3-x)Pb(Mg1 / 3Nb2 / 3)O(3-y)PbTiO3 system; according to the annealing process, the relaxor ferroelectric single crystal after grinding and polishing is subjected to annealing treatment in atmosphere, stress caused by machining is removed, and spontaneous strain produced in a ferroelectric phase forming process is released to the great degree through quite slow cooling, so that the probability of cracking caused by electrically induced domain rotation in the crystal poling process is reduced. Besides, after an electric field is removed, a remaining depolarization field can be induced to form a nanometer domain structure. In order to guarantee formation and stability of a single-domain structure, the remaining depolarization field can be compensated by bulk shielding effect formed through electrode injection, the relaxor ferroelectric single crystal with high poling performance and stable performance is obtained, and the material has the characteristics of small half-wave voltage, large photo damage threshold, large electro-optic coefficient and the like and is far better than BBO, KTP, LN and other materials.
Owner:XI AN JIAOTONG UNIV

Fluorine-containing polyimide electro-optical material and preparation method thereof

InactiveCN101851332BImprove performanceImprove film-forming processabilityNon-linear opticsTransmission lossStructural formula
The invention relates to a fluorine-containing polyimide electro-optical material, which has high nonlinear optical response, high thermal stability, low optical transmission loss and good film forming property. Fluorine-containing polyimide is prepared first by dianhydride monomer 6FDA, dianhydride monomer 10FEDA and diamine monomer 6FHP through condensation polymerization, and then lambda-shaped heterocyclic azo chromophore and hydroxyl-containing fluorinated polyimide are etherified to obtain the material. The general structural formula is shown as the accompanying drawing, wherein m and ndenote degree of polymerization, the m is within 1-1000 and the n is within 1-1000. NLO denotes the lambda-shaped heterocyclic azo chromophore and the general structural formula is shown as the accompanying drawing.
Owner:SOUTHEAST UNIV

Internally modulated terahertz source based on waveguide structure and its internal modulation method

The invention discloses an internal modulation terahertz source based on a waveguide structure and an internal modulation method thereof. The internal modulation terahertz source comprises a pumping source, a laser beam combiner, a coupler and a waveguide structure, all of which are sequentially arranged, wherein the pumping source is composed of two independent fiber lasers; the waveguide structure is formed by tightly adhering an organic electro-optical material cladding, a lithium niobate core layer and a quartz substrate from top to bottom through optical cement, a control circuit is arranged in the organic electro-optical material cladding, and a wedge-shaped structure is arranged on the outer side of the organic electro-optical material cladding. The refractive index of the organic electro-optical material cladding is modulated through the control circuit, so that waveguide structure internal modulation terahertz output is obtained; therefore, the higher core layer internal energy conversion efficiency is achieved, and the generated terahertz energy can be efficiently coupled and outputted. According to the internal modulation terahertz source based on the waveguide structure and the internal modulation method thereof, integrated optical modulated terahertz radiation with high efficiency and a simple and compact structure can be achieved, and the invention is suitable for subsequent application and research on the fields of wireless communication, imaging, radar and the like.
Owner:TIANJIN UNIV

Titanium rubidium lithium germanate compound, titanium rubidium lithium germanate nonlinear optical crystal, preparation method and application thereof

The invention discloses a rubidium lithium titanium germanate compound, a rubidium lithium titanium germanate non-linear optical crystal and preparation methods and application thereof. A chemical formula of the rubidium lithium titanium germanate compound is Rb4Li2TiGe4O13; a chemical formula of the rubidium lithium titanium germanate non-linear optical crystal is Rb4Li2TiGe4O13; the rubidium lithium titanium germanate non-linear optical crystal is non-centrosymmetrical structure, belongs to the tetragonal system and has a space group P4nc, is prepared by adopting a co-solvent method. The invention further discloses the rubidium lithium titanium germanate non-linear optical crystal to application of a laser non-linear optical compound functional device, an electro-optical crystal device or a laser device. The rubidium lithium titanium germanate non-linear optical crystal provided by the invention has a relatively great non-linear optical effect, a high electro-optical coefficient anda wide transmission range, has good mechanical properties and does not deliquesce; the frequency-doubled effect is 3 to 5 times of KDP (potassium dihydrogen phosphate).
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI

Organic optical nonlinear chromophore based on double-donor structure as well as synthesis method and application of organic optical nonlinear chromophore

The invention provides an organic optical non-linear chromophore based on a double-donor structure, and belongs to the field of optical materials, the chromophore has a structural formula shown in the abstract figure, OH groups are introduced into double donors of a second-order non-linear optical chromophore through nucleophilic reaction, and the chromophore has a structure shown in the description. The two OH groups connected to the donor end provide connection sites for further modification of the double donor, and ultraviolet absorption lambda max red shift and small band gap verify that the double donor group modified by the two OH groups has higher electron donor strength compared with the donors of most chromophores.
Owner:GUANGZHOU UNIVERSITY

Quantum light source chip based on optical superlattice and waveguide light path

A method for setting up a quantum light source chip based on an optical superlattice waveguide, which adopts the integration of a waveguide optical path, an optical superlattice, and an electro-optical modulator, and the waveguide optical path splits the incoming classical pumping laser beam through a waveguide beam splitter, splitting the beam After the laser light enters the optical superlattice region, the frequency is transferred to obtain entangled photon pairs, and then the entangled photon pairs continue to enter the interferometer for quantum interference; the phase of the interferometer is controlled by the built-in electro-optic modulator on the chip, and obtained through voltage adjustment. Several different quantum states.
Owner:NANJING UNIV

Double chromophore complex system and its synthesis method and application

The present invention relates to an organic / polymer electro-optic material, and particularly relates to a double chromophore complex system and synthesis and application thereof. The double chromophore complex system is a mixture of a side chain type subject chromophore-containing main polymer or a Y type subject chromophore-containing main polymer and an object chromophore, wherein the molar ratio of subject chromophore to object chromophore is 1:1. The growth rate of the electro-optic coefficient of the double chromophore complex system in the molar ratio is obviously superior to the growth rate of the electro-optic coefficient of the double chromophore complex system in other molar ratio. In the optimum molar ratio, the electro-optic coefficient of the double chromophore complex system can be increased to the greatest degree, by dissolving the double chromophore complex system in an organic solvent and coating, the biggest electro-optic coefficient of a prepared polarized electro-optic polymer film is 160pm / v. Therefore, the prepared polarized electro-optic polymer film can be used as an optical material, and can be applied to an electro-optic modulator, an optical sensor, an optical converter, and information transmission and other aspects.
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI

Bismuth tellurium borate compound, bismuth telluride borate nonlinear optical crystal, bismuth telluride borate scintillation crystal, preparation method and application

The invention discloses a (Bi1-x-yLnxCey)3TeBO9 compound, (Bi1-x-yLnxCey)3TeBO9 nonlinear optical crystal, (Bi1-x-yLnxCey)3TeBO9 scintillation crystal, a preparation method and an application thereof. The compound crystal with its chemical formula being Bi3TeBO9 is a non-centrosymmetrical structure and belongs to the hexagonal system, and space group is P63. The invention also discloses (Bi1-x-yLnxCey)3TeBO9 compound crystal doped with different rare earth elements, wherein Ln=La-Lu or Y; X is less than 1 and greater than or equal to 0; and Y=0 or Y is less than or equal to 0.2 and greater than or equal to 0.0001. By a flux method, high-quality and large-sized (Bi1-x-yLnxCey)3TeBO9 crystal can grow, has good mechanical property is good, is deliquescence-free, and can be used for manufacturing nonlinear optical devices. A laser manufactured by the use of the crystal can be used in fields of spectroscopy, biomedicine, military and the like. The material of the invention also can be used as high-density fast-attenuation scintillation crystal.
Owner:TECHNICAL INST OF PHYSICS & CHEMISTRY - CHINESE ACAD OF SCI

Transparent electro-optical ceramic material with high electro-optical coefficient and high temperature stability and preparation method thereof

ActiveCN114804873AHigh electro-optic coefficientMeet temperature stability requirementsRare-earth elementOptical coefficient
The invention relates to a transparent electro-optic ceramic material with high electro-optic coefficient and high temperature stability and a preparation method thereof. The element composition of the ceramic material is (Pb1-xLnx) [(Mg1 / 3Nb2 / 3) yTi1-y] 1-x / 4O3, Ln is a rare earth element, x is more than or equal to 0.01 and less than or equal to 0.05, y is more than or equal to 0.90 and less than or equal to 0.70, and x is more than or equal to 0.01 and less than or equal to 0.05. And the rare earth doping content in the ceramic material is in gradient distribution along the thickness direction of the ceramic material. The method comprises the following steps: firstly, synthesizing PMN-PT ceramic powder with different rare earth doping contents, sequentially stacking, filling and forming the different PMN-PT ceramic powder according to the doping contents, and carrying out hot pressed sintering in an oxygen atmosphere after glue discharging. Rare earth doping elements in the ceramic form component gradient through diffusion in the sintering process. Compared with the prior art, the method provided by the invention can be used for preparing the electro-optical ceramic with high electro-optical coefficient and high temperature stability, and can meet the requirement of an optical modulator on the temperature stability of an electro-optical material.
Owner:SHANGHAI RES INST OF MATERIALS CO LTD

Sodium bismuth titanate-barium titanate lead-free transparent electro-optic ceramics and preparation method thereof

The invention relates to a sodium bismuth titanate-barium titanate lead-free transparent electro-optic ceramic and a preparation method thereof; the electro-optic ceramic has the chemical composition of (1-x)(Na0.5Bi0.5)TiO3-xBaTiO3, wherein 0.05<=x<=0.08; the preparation method includes the steps: batching Na2CO3, Bi2O3, TiO2 and BaCO3 as raw materials according to the stoichiometric ratio, carrying out ball milling, and mixing evenly to obtain a powder; carrying out heat preservation on the powder for 2-4 h at the temperature of 850-950 DEG C, and thus obtaining a synthetic material; crushing the synthetic material, sieving, carrying out ball milling, adding a binder, and carrying out press molding to obtain a blank; next, placing the blank in a sintering furnace, heating up from room temperature to 800 DEG C-850 DEG C at the speed of 200 DEG C-250 DEG C / h, and carrying out heat preservation for 0.5-1.5 h; and heating up at the speed of 100 DEG C / h and gradually pressurizing to 200-250 MPa, followed by keeping the pressure unchanged, heating up to 1000 DEG C-1050 DEG C, then carrying out heat preservation for 2 h, then heating up to 1100 DEG C-1200 DEG C at the speed of 50 DEG C / h, carrying out heat and pressure preservation for 8-24 h, then releasing the pressure, cooling to 900 DEG C at the speed of 100 DEG C / h, and cooling to room temperature along with a furnace, wherein oxygen is introduced with the flow quantity of 3-5 L / minute when the heating is started and introduction of oxygen is stopped when the pressure is released.
Owner:江苏先进无机材料研究院

Waveguide electro-optic intensity modulation device with very low half-wave voltage

Disclosed is a waveguide electro-optic intensity modulation device with very low half-wave voltage. The modulation device comprises a substrate, optical waveguides, a micro-electrode, an external driving power supply (11); with electro-optic transparent ceramic serving as the substrate, by means of a femtosecond laser micromachining method, the optical waveguides are induced out on the electro-optic transparent ceramic substrate, the microelectrode is manufactured, a mach-zehnder electro-optic modulator is integrated, and the microelectrode is connected with the external driving power supply (11). The waveguide electro-optic intensity modulation device has the advantages of being low in half-wave voltage, high in response speed and high in extinction ratio, and can be applied in the fieldsof laser optoelectronic devices, optical communication and the like.
Owner:XIAN INSTITUE OF SPACE RADIO TECH

A waveguide light intensity modulation device with extremely low half-wave voltage

A waveguide optical intensity modulation device with extremely low half-wave voltage, including a substrate, an optical waveguide, a microelectrode, and an external driving power supply (11); the electro-optic transparent ceramic is used as the substrate, and the electro-optic transparent ceramic substrate is processed by femtosecond laser micromachining. The optical waveguide is induced on the top and the microelectrodes are fabricated to be integrated into a Mach-Zehnder electro-optic modulator, and the microelectrodes are respectively connected to an external driving power supply (11). The invention has the characteristics of low half-wave voltage, fast response speed and high extinction ratio, and can be applied to the fields of laser optoelectronic devices, optical communication and the like.
Owner:XIAN INSTITUE OF SPACE RADIO TECH
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