The invention discloses a Ti-Zr-Cu-Be four-element amorphous composite with the processing hardening capacity and a preparation method thereof. The composite is a type of amorphous alloy composite containing a dendritic crystal phase, wherein the dendritic crystal phase is prepared from the chemical components of 59-60 parts of Ti, 38-39 parts of Zr and 1-3 parts of Cu, the volume fraction of the dendritic crystal phase is 5-95%, and an amorphous matrix is prepared from the chemical components of 33-34 parts of Ti, 35-36 parts of Zr, 8-9 parts of Cu and 21-24 parts of Be. The dendritic crystal phase has the deformation-induced Martensite phase transformation characteristic, the composite shows excellent comprehensive mechanical properties of high strength, high plasticity, processing hardening and the like under the actions of tension and compression loads, for example, under the tension load, the processing hardening behavior is remarkable, the plastic deformation capacity is 6-15%, and the strength is 1100-1900 MPa. Meanwhile, by means of Martensite phase transformation, the composite has the super-elastic characteristic under the tension load through cyclic loading, for example, elastic deformation can be 2.7-3%. As for the composite, the chemical composition is simple, the chemical components of the second phase are relatively stable, and structural design and controllable preparation of the composite are facilitated.