The invention relates to calcium silicate high-filling polymer modified paper, which is compounded and formed by three layers of non-plant fiber calcium silicate substrates, wherein the first layer and the third layer are prepared from 2 to 6 percent of ethylene bis stearamide, 8 to 23 percent of high-density polyethylene, 3 to 9 percent of metallocene polyethylene, 0 to 1 percent of low-molecular polyethylene, 50 to 60 percent of activated calcium silicate, 10 to 25 percent of calcium silicate inorganic powder and 0 to 3 percent of addition agents, the first layer and the third layer accounts for 25 percent of the weight of the paper, the second layer is prepared from 50 to 60 percent of activated calcium silicate powder, 10 to 25 percent of calcium silicate, 2 to 9 percent of styrene-butadiene block copolymer, 7 to 21 percent of high-intensity polyethylene materials, 4 to 8 percent of linear low-intensity polyethylene and 0 to 3 percent of addition agents, and the second layer accounts for 50 percent of the weight of the paper. The modified paper has the same appearance, whiteness, sizing degree, opacity, strength, toughness and rigidity as plant fiber paper and has simple production processes, no bacteria and poison; and because the product is used for packing paper and can replace the traditional plastic packing paper, a great amount of petroleum can be saved.