The invention discloses an
alkaline etching solution recycling regeneration method. The
alkaline etching solution recycling regeneration method comprises the following steps that (1) an
etching wastesolution is produced; (2) extraction is carried out, specifically, the
etching waste solution is mixed with an extraction agent,
copper ions are separated from the
etching waste solution to form a loaded
copper oil phase, and a regenerated solution is stored in a regenerated solution bucket; (3) component adjustment is carried out, specifically, Cu2+, NH4+, Cl- and PH value are assayed for the regenerated solution, the amount of
ammonia and
ammonium chloride to be added is determined by the assayed results, and then the regenerated solution flows back to an etching
production line; (4) primarywashing is carried out, specifically, primary washing is carried out on the loaded
copper oil phase, and an aqueous phase is separated from the loaded copper
oil phase; (5) back extraction is carriedout, specifically, the loaded copper oil phase is transferred into a back extraction solution, and a loaded extractant in the loaded copper oil phase has a
contact reaction with a H2SO4 solution, thecopper ions are separated from the extractant, and a CuSO4 solution is formed and enters the aqueous phase; (6) an electrodeposition is carried out, specifically, the CuSO4 solution is added to an
electrolyte, the CuSO4 solution is electrolyzed by the
electrolyte, the coarse copper is deposited at a
cathode,
oxygen is generated at an
anode, and after the CuSO4 solution is electrodeposited, the solution flows back into a back extraction cylinder.