The invention discloses a preparation method of self-assembled
superlattice materials of a
titanium dioxide nano rod, comprising the following steps: (1) monodispersed TiO2 nano rods are synthetized, and the synthetic reaction is based on a condition that an unstable
hydroxy derivative is produced by
oleic acid titanium under nucleophillic
attack of oil
amide, the
hydroxy derivative can be further polymerized to generate Ti-o-Ti, and produced TiO2 nano sticks are dispersed to a non-polar
solvent to make clear TiO2 solution; (2) superfluous oil acid surface activators are added into the solution, and the
superlattice materials with different structures (riband shapes and
beehive shapes) are made by controlling the concentration of the oil acid in the solution and evaporating slow solvents. The invention has the advantages of firstly expanding the preparation scope of one-dimensional
superlattice materials to the TiO2 nano rods of
anatase, utilizing superfluous oil acid surface
active agent to lead depletion attraction to adjacent TiO2 nano sticks, thereby adding
macro-control factors for self-assembled drive force of the nano sticks so as to enable the self-assembled behavior to be easily generated.