37results about How to "Suitable for expanding production requirements" patented technology

The invention provides a thorium coordination polymer, its preparation method and its application in propyne storage. The chemical formula of the thorium coordination polymer is [Th 6 o 4 (OH) 4 (C 14 h 4 f 4 o 4 ) 6 (H 2 O) 6 ], C 14 h 4 f 4 o 4 It is the molecular formula of 3,3',5,5'-tetrafluorobiphenyl-4,4'-dicarboxylic acid with two carboxyl protons removed. It belongs to the cubic crystal system and the space group is Fm‑ 3m ; the unit cell parameter is a =28~28.1 Angstroms, b =28~28.1 Angstroms, c =28~28.1 Angstroms, =90º, =90º, =90º, Z =4. The preparation method of the thorium coordination polymer comprises the following steps: mixing thorium salt, 3,3',5,5'-tetrafluorobiphenyl-4,4'-dicarboxylic acid, nitric acid and solvent, and then transferring to a reaction kettle , and then react under the condition of 358~373 K to obtain the thorium coordination polymer. The thorium coordination polymer can be used to store propyne gas.

The invention provides an electrocatalytic coupling advanced oxidation system. The system can degrade organic pollutants into carbon dioxide and the carbon dioxide is synchronously electrocatalytically reduced to a hydrocarbon. In the catalytic system, three-dimensional hexagram-shaped Co3O4 and nano-sheet stack flower-shaped CuO are respectively used as an anode material and a cathode material, and the two electrode materials are prepared by a solvothermal method. In the three-electrode system electro-catalytic process, the Co3O4 electro-anode can thoroughly mineralize p-nitrophenol to CO2 and H2O, and the CuO electro-cathode can synchronously reduce the generated carbon dioxide into the useful hydrocarbon. When the additionally-applied bias voltage is 0.8V vs Ag / AgCl, the material has anoptimal catalytic effect, the removal rate of the p-nitrophenol can reach 98% or more, and the yields of methanol and ethanol reach 49.145 micromol / L / h and 20.475 micromol / L / h, respectively.

The invention relates to the field of materials, in particular to a copper-containing zinc oxide / graphene quantum dot catalyst and a preparation method. By preparing metal copper (Cu) nanoparticles doped ZnO composite film, the separation rate of photogenerated electrons and holes can be improved, and the photocatalytic performance can be improved. At the same time, GQDs aqueous solution is spin-coated on the surface of the composite film to prepare The copper-containing zinc oxide / graphene quantum dot dual semiconductor catalyst system can not only effectively prevent the photocorrosion of ZnO, but also use GQDs as semiconductors to generate electron-hole pairs by themselves under the excitation of ultraviolet light, thereby providing more The highly active free radicals are conducive to the degradation of organic matter.

The invention relates to a material CdS / Ba0.4Sr0.6TiO3 for producing hydrogen by photocatalytically decomposing water, which is a heterostructure catalyst formed by supporting CdS onto Ba0.4Sr0.6TiO3. The catalyst is prepared by a one-step hydrothermal process. When the mole ratio of the CdS to the Ba0.4Sr0.6TiO3 is 0.4:1, the expression is 40%CdS / Ba0.4Sr0.6TiO3, and the material has the optimal catalytic effect. Under simulated sunlight, by using Na2S / Na2SO3 as a sacrifice reagent, the hydrogen production efficiency by photocatalytically decomposing water of the 40%CdS / Ba0.4Sr0.6TiO3 is up to 1268.4 mu mol.h<-1>.g<-1> under the condition of no noble metal for cocatalysis. The one-step hydrothermal process is directly used for synthesizing the catalyst, is simple to operate, has the advantages of low production cost, higher synthesis yield, higher purity and favorable repetitiveness, and is suitable for the requirement for scale-up production; the catalyst has high stability and is convenient for reutilization; and the catalyst has very high photocatalytic hydrogen production ratio under simulated sunlight.

Disclosed is ternary neterogeny structural light degradation organic matter catalyst 5% TiO2-Bi2MoO6 / Bi3.64Mo0.36O6.55, which consists titanium dioxide (TiO2) and two types of dibismuth trimolybdenum dodecaoxide (Bi2MoO6 and Bi3.64Mo0.36O6.55) with different structures, wherein the titanium dioxide is 5% of total mole number of bismuth elements. The ternary neterogeny structural light degradationorganic matter catalyst 5% TiO2-Bi2MoO6 / Bi3.64Mo0.36O6.55 has the advantages that the catalyst is the ternary neterogeny structural light degradation organic matter catalyst reported for the first time; 2, the catalyst is directly synthesized by a one-step hydrothermal method, is simple in operation, low in production cost, high in synthesis yield and purity, fine in repeatability, and meets requirements of batch production; 3, the catalyst is fine in thermal stability and is high in acid resistance and alkali resistance; and 4, the catalyst has a good photocatalytic degradation organic effect, and has a higher catalysis effect as compared with single titanium dioxide, dibismuth trimolybdenum dodecaoxide (Bi2MoO6 and Bi3.64Mo0.36O6.55) and an optional combination (TiO2-Bi2MoO6, TiO2-Bi3.64Mo0.36O6.55 and Bi2MoO6 / Bi3.64Mo0.36O6.55) among the single titanium dioxide and the dibismuth trimolybdenum dodecaoxide (Bi2MoO6 and Bi3.64Mo0.36O6.55).

The invention provides a terbium coordination polymer for separating propyne / propylene mixed gas and a preparation method thereof. The chemical formula of the terbium coordination polymer is [Tb 2 ·(O 2 C‑C 6 h 2 f 2 -C 6 h 2 f 2 ‑CO 2 ) 3 ·H 2 O](O 2 C‑C 6 h 2 f 2 -C 6 h 2 f 2 ‑CO 2 Represents 3,3',5,5'-tetrafluorobiphenyl-4,4'-dicarboxylic acid), belongs to the tetragonal crystal system, and the space group is P4 1 22; Unit cell parameters are α=90°, β=90°, γ=90°, Z=4. The preparation method of the terbium coordination polymer comprises the following steps: mixing terbium salt, 3,3',5,5'-tetrafluorobiphenyl-4,4'-dicarboxylic acid and o-fluorobenzoic acid, and then putting them into a container in a reaction kettle with an organic solvent, and react at 358-373K to obtain the terbium coordination polymer. The terbium coordination polymer can be used to separate propyne / propylene mixed gas.

The invention provides a cerium oxide, graphene quantum dots and graphene-like phase carbon nitride composite photoactivate material and a preparation method thereof. The composite photoactivate material is formed by embedding cerium oxide into a graphene-like phase carbon nitride layer structure and loading the nitrogen-doped graphene quantum dots onto graphene-like phase carbon nitride. According to the composite photoactivate material, by use of doping of the nitrogen-doped graphene quantum dots, the photoresponse range of the graphene-like phase carbon nitride is expanded; through the quick photoproduction electron and hole separation effect and the electronic migration capability among the nitrogen-doped graphene quantum dots, cerium oxide and graphene-like phase carbon nitride, the composite photoactivate material has an efficient photocatalytic activity.

The invention discloses a method for preparing a graphene quantum dot / vanadium-doped mesoporous titanium dioxide composite photocatalyst. The catalyst of the invention is composed of graphene quantum dots and vanadium-doped mesoporous titanium dioxide microspheres obtained by solvothermal heat. Under simulated sunlight, the catalyst not only effectively mineralized methylene blue into CO2 and H2O, but also reduced the carbon dioxide produced by its catalytic oxidation to useful hydrocarbons. The advantages of the present invention are: 1. The doping of vanadium reduces the bandgap width of titanium dioxide, thereby improving its response range under visible light; 2. At the same time, the photosensitization and super-strong electron conduction of graphene quantum dots are utilized ability, which not only inhibits the recombination of photogenerated electrons and holes, but also improves the utilization rate of light; 3, the material of the present invention is cheap and easy to obtain, the synthesis method is simple, the synthesis yield and purity are high, and the experiment repeatability is good, suitable for Expanded production requirements.