The invention relates to a high-capacity SiOx based composite negative
electrode material, a preparation method and a battery, wherein the negative
electrode material comprises a
silicon oxide material, a carbon material and an
amorphous carbon coating layer; the
silicon oxide material is
silicon oxide or
silicon oxide material modified in a
carbon coating manner; surfaces of carbon material particles are coated with the
silicon oxide material. A preparation method of the high-capacity SiOx based composite negative
electrode material comprises the steps of performing physical
processing or
carbon coating modification on a
silicon oxide raw material, thus obtaining a micron-sized silicon oxide material; and then mechanically fusing,
coating with a
solid phase and
sintering at a high temperature to obtain the high-capacity negative
electrode material. Through the high-capacity SiOx based composite negative
electrode material, the effect of uniform dispersing and
coating of the micron-sized silicon oxide particles on the surfaces of the carbon material particles can be achieved by virtue of the combination of mechanical fusion and
solid-phase coating processes. The silicon oxide particles are well dispersed on the surface of the carbon material particle; the strength of bonding between the silicon oxide particles and the carbon material particles is high; the recycling performance of the material can be greatly improved; and meanwhile, the high-capacity SiOx based composite negative
electrode material is high in first efficiency (breaking through the theoretical efficiency of SiOx), low in
expansion rate, long in service life, environmental-friendly,
pollution-free and low in cost.