The invention discloses a solution regeneration apparatus for a solution deep dehumidifying system, comprising a first solution tank, a heat exchanger, a solar photovoltaic cell, a solution preprocessor, a membrane regenerator, a second solution tank, a third solution tank, a storage battery, a first anticorrosion solution pump, a second anticorrosion solution pump and a regulating valve. The apparatus of the invention heats the dehumidifying solution by the heat exchanger, and then primarily regenerates the dehumidifying solution by the solution preprocessor, which increase the concentration of the inlet solution of a regeneration chamber and a desalination chamber of the membrane regenerator, thereby raising the regeneration effect of the membrane regenerator. Finally, high-concentration dehumidifying solution for the solution deep dehumidifying system is obtained. The apparatus of the invention effectively utilizes the complementarity of solar photovoltaic and photo-heat, thereby raising the running stability of the solar solution deep dehumidifying system, and simultaneously, the apparatus stores energy by the night low-ebb and low-price electric energy, thereby alleviating the peak-valley difference of the electrical loads, and raising the economy of the system.