The invention relates to a device and process for secondarily utilizing coked crude
benzene separation water. Separation water distilled by a debenzolization
tower for a crude
benzene coking procedure serves as a
raw material, crude
benzene separation water separated by a light benzene control separator is introduced into a final
cooling tower as updating supplementation water through a pipeline, and a trace amount of a NaOH solution with the concentration of 40 percent for
ammonia still is supplemented into the final
cooling tower, so that the separation water and the NaOH solution are mixed to form an alkaline solution; after final cooling circulation, the redundant solution is directly fed into a surplus
ammonia water tank from an outlet of a
circulating pump and enters an
ammonia still
system. The separation water serves as the supplemented water, so that a great amount of industrial new water is saved, acid mist carried in
coal gas can be absorbed and neutralized by supplementing the trace amount of the NaOH solution, packing supporting of the final
cooling tower is prevented, and
corrosion prevention of equipment is realized; moreover, part of benzene in the separation water in contact with the
coal gas is volatilized, directly enters the
coal gas, and reaches a benzene washing
tower, and part of light benzene in the separation water is recycled. The process is simple in operation, environmentally-friendly, energy-saving, low in
investment cost, and safe and reliable to operate.