The invention relates to preparation of positive material for
lithium ion batteries, and in particular relates to a preparation method of
lithium cobaltate positive material coated with nanometer aluminum
oxide solid phase. The method comprises the following steps: 1, preparing
lithium cobaltate, namely, mixing tricobalt tetroxide with
lithium carbonate, feeding 1400-1500ppm of basic
magnesium carbonate,
sintering the mixture at the temperature of 950-980 DEG C, naturally cooling in a furnace, and crushing to obtain lithium cobaltate; and 2, enabling lithium cobaltate to be coated with the nanometer aluminum
oxide solid phase, namely, firstly feeding lithium cobaltate and nanometer aluminum
oxide powder having the particle size D50 of 20-22nm into a
ball mill, feeding
grinding balls with the
mass twice that of the material,
sintering the material treated by ball-milling at the temperature of 780-800 DEG C, then naturally cooling in the furnace, and crushing the cooled material in a
crusher to obtain the lithium cobaltate positive material coated with the nanometer aluminum oxide
solid phase. After the preparation method is adopted, the cycle performance and the high-temperature performance of the lithium cobaltate positive material can be effectively improved, the
coating uniformity of the lithium cobaltate positive material is good, and the product performance is stable.