195results about "Electrode with substrate and coating" patented technology

The present invention discloses porous covalent organic frameworks (COF) supported noble metal-free nanoparticles which are useful as electrocatalysts for a water splitting system, and to the process for preparation of such electrocatalysts. The covalent organic frameworks (COF) supported noble metal-free nanoparticles have general formula (I):COF_AxBy(M)n  (Formula I)wherein COF is selected from a Tris (4-formylphenyl)amine terephthaldehyde polymer or a benzimidazole-phloroglucinol polymer;‘A’ and ‘B’ each independently represent a transition metal selected from the group consisting of Ni, Co, Fe, Mn, Zn, and mixtures thereof; or ‘A’ and ‘B’ together represent a transition metal selected from the group consisting of Ni, Co, Fe, Mn, Zn, and mixtures thereof;‘M’ represents hydroxide or a nitride ion;‘x’ and ‘y’ represent the weight % of the metal loadings; or a ratio of x:y is between 0:1 and 1:0; and‘n’ is an integer 1 or 2 or 3.

An anion-conducting polymeric membrane comprises a terpolymer of styrene, vinylbenzyl-Rs and vinylbenzyl-Rx. Rs is a positively charged cyclic amine group. Rx is at least one constituent selected from the group consisting Cl, OH and a reaction product between an OH or Cl and a species other than a simple amine or a cyclic amine. The total weight of the vinylbenzyl-Rx groups is greater than 0.3% of the total weight of the membrane. In a preferred embodiment, the membrane is a Helper Membrane that increases the faradaic efficiency of an electrochemical cell into which the membrane is incorporated, and also allows product formation at lower voltages than in cells without the Helper Membrane.

Titania is a semiconductor and photocatalyst that is also chemically inert. With its bandgap of 3.0, to activate the photocatalytic property of titania requires light of about 390 nm wavelength, which is in the ultra-violet (UV), where sunlight is very low in intensity. A method and devices are disclosed wherein stress is induced and managed in a thin film of titania in order to shift and lower the bandgap energy into the longer wavelengths that are more abundant in sunlight. Applications of this stress-induced bandgap-shifted titania photocatalytic surface include photoelectrolysis for production of hydrogen gas from water, photovoltaics for production of electricity, and photocatalysis for detoxification and disinfection.

The present invention relates to the unexpected discovery of systems for capturing carbon dioxide and producing hydrogen gas. In certain embodiments, the system treats wastewater. In certain embodiments, the system captures and sequesters CO2 as carbonate salts.

A hybrid three dimensional (3D) hydrogen evolution reaction (HER) catalyst that is formed from a porous Ni foam support, a NiSe2 scaffold positioned on the support; and layered transition metal dichalcogenide (LTMDC) or first-row transition metal dichalcogenide particles positioned on the NiSe2 scaffold. The catalyst provides a low onset potential, large cathode current density, small Tafel slopes, and large exchange current densities, similar in catalytic power to Pt HER catalysts.

The invention provides electro-catalyst compositions for an anode electrode of an acid mediated proton exchange membrane-based water electrolysis system. The compositions include a noble metal component selected from the group consisting of iridium oxide, ruthenium oxide, rhenium oxide and mixtures thereof, and a non-noble metal component selected from the group consisting of tantalum oxide, tin oxide, niobium oxide, titanium oxide, tungsten oxide, molybdenum oxide, yttrium oxide, scandium oxide, cooper oxide, zirconium oxide, nickel oxide and mixtures thereof. Further, the non-noble metal component can include a dopant. The dopant can be at least one element selected from Groups III, V, VI and VII of the Periodic Table. The compositions can be prepared using any solution based methods involving a surfactant approach or a sol gel approach. Further, the compositions are prepared using noble metal and non-noble metal precursors. Furthermore, a thin film containing the compositions can be deposited onto a substrate to form the anode electrode.

The invention provides new methods and compositions for synthesizing hydrogen fuel using simple and inexpensive materials.

Disclosed is a non-precious metal based water electrolysis catalyst represented by CoX / C (X is at least one selected from the group consisting of P, O, B, S and N) for evolution of hydrogen and oxygen at a cathode and anode, respectively, at the same time, the catalyst including a cobalt-containing compound fixed to a carbon carrier.

The present invention relates to the electrolytic splitting of water using a carbon-supported manganese oxide (MnOx) composite. Specifically, the present electrolytic splitting of water is carried under neutral electrolyte conditions with a high electrolytic activity, while using an oxygen evolution reaction (OER)-electrode comprising the present carbon-supported MnOx composite. Next, the present invention relates to a process for producing such a carbon-supported MnOx composite as well as to a composite obtainable by the present process for producing the same and to an OER-electrode comprising the carbon-supported MnOx composite obtainable by the present process.

An electrolytic electrode having an interlayer having more excellent peeling resistance and corrosion resistance and longer electrolytic life than conventional electrolytic electrodes and capable of flowing a large amount of current at the industrial level and a process of producing the same are provided. The electrolytic electrode includes a valve metal or valve metal alloy electrode substrate on the surface of which is formed a high-temperature oxidation film by oxidation, and which is coated with an electrode catalyst. The high-temperature oxidation film is integrated with the electrode substrate, whereby peeling resistance is enhanced. Further, by heating the high-temperature oxidation film together with the electrode catalyst, non-electron conductivity of the interlayer is modified, thereby making it possible to flow a large amount of current.

A catalyst layer for an electrochemical device comprises a catalytically active element and an ion conducting polymer. The ion conducting polymer comprises positively charged cyclic amine groups. The ion conducting polymer comprises at least one of an imidazolium, a pyridinium, a pyrazolium, a pyrrolidinium, a pyrrolium, a pyrimidium, a piperidinium, an indolium, a triazinium, and polymers thereof. The catalytically active element comprises at least one of V, Cr, Mn, Fe, Co, Ni, Cu, Sn, Zr, Nb, Mo, Ru, Rh, Pd, Ag, Cd, Hf, Ta, W, Re, Ir, Pt, Au, Hg, Al, Si, In, Tl, Pb, Bi, Sb, Te, U, Sm, Tb, La, Ce and Nd. In an electrolyzer comprising the present catalyst layer, the feed to the electrolyzer comprises at least one of CO2 and H2O.

The invention relates to an electrode for electrochemical generation of hypochlorite. The electrode comprises a valve metal substrate coated with a catalytic system consisting of two super-imposed layers of distinct composition and having a different activity towards hypochlorite anodic generation from chloride solutions. The electrode has a high duration in cathodic operation conditions, imparting self-cleaning characteristics thereto when used in combination with an equivalent one with periodic polarity reversal. Moreover, the deactivation of the electrode at the end of its life cycle occurs in two subsequent steps, allowing to schedule the substitution thereof with a significant notice period.

An anion-conducting polymeric membrane comprises a terpolymer of styrene, vinylbenzyl-Rs and vinylbenzyl-Rx. Rs is a positively charged cyclic amine group. Rx is at least one constituent selected from the group consisting Cl, OH and a reaction product between an OH or Cl and a species other than a simple amine or a cyclic amine. The total weight of the vinylbenzyl-Rx groups is greater than 0.3% of the total weight of the membrane. In a preferred embodiment, the membrane is a Helper Membrane that increases the faradaic efficiency of an electrochemical cell into which the membrane is incorporated, and also allows product formation at lower voltages than in cells without the Helper Membrane.

The invention relates to an electrode for electrochemical generation of hypochlorite. The electrode comprises a valve metal substrate coated with a catalytic system consisting of two super-imposed layers of distinct composition and having a different activity towards hypochlorite anodic generation from chloride solutions. The electrode has a high duration in cathodic operation conditions, imparting self-cleaning characteristics thereto when used in combination with an equivalent one with periodic polarity reversal. Moreover, the deactivation of the electrode at the end of its life cycle occurs in two subsequent steps, allowing to schedule the substitution thereof with a significant notice period.

An object is to provide an electrode for electrolysis capable of generating ozone water with a high efficiency by electrolysis of water at a low current density. An ozone generating electrode includes: a substrate; and a surface layer formed on the surface of the substrate and including a dielectric material, the surface layer includes holes which inwardly continuously extend from the surface of the surface layer, and a distance from the hole closest to the surface of the substrate to the surface of the substrate is more than 0 and 2000 nm or less.

A method for the operation of an SOEC stack reactor (Solid Oxide Electrolyser Cell), according to which, in the absence of electricity, synthesis gas H2+CO or a mixture H2+CO2 is injected at the cathode inlet of the reactor in such a way as to produce methane inside the reactor. Since the catalytic methanation reaction is exothermic, the stack reactor can therefore be held at temperature, without loss of fuel. The fuel used for the methanation (synthesis gas or hydrogen) can advantageously be that which has been previously produced during the operating phases with available electricity.

Disclosed are cathodes comprising a conductive support substrate having a catalyst coating including Ni5P4 nanocrystals. The conductive support substrate is capable of incorporating a material to be reduced, such as water or hydrogen cations. Also disclosed are methods for generating hydrogen gas from water via an electrolysis reaction or from the reduction of hydrogen cations, wherein the catalyst is part of a conductive support within a cathode, including (a) placing an anode and the inventive cathode in an electrolyte, (b) placing the anode and cathode in conductive contact with an external source of electricity, (c) providing a source of water to the cathode, and (d) using the external source of electricity to drive an electrolysis reaction at the cathode, whereby the hydrogen gas is generated from water. In certain embodiments, the reaction uses a free catalyst, wherein the catalyst is placed in proximity to the cathode.

Provided is a semiconductor photoelectrode comprising a conductive substrate; a first semiconductor photocatalyst layer provided on a surface of the conductive substrate; a second semiconductor photocatalyst layer provided on a surface of the first semiconductor photocatalyst layer. The semiconductor photoelectrode has a plurality of pillar protrusions on the surface thereof. A surface of each of the pillar protrusions is formed of the second semiconductor photocatalyst layer.

An anode catalyst suitable for use in an electrolyzer. The anode catalyst includes a support and a plurality of catalyst particles disposed on the support. The support may include a plurality of metal oxide or doped metal oxide particles. The catalyst particles, which may be iridium, iridium oxide, ruthenium, ruthenium oxide, platinum, and / or platinum black particles, may be arranged to form one or more aggregations of catalyst particles on the support. Each of the aggregations of catalyst particles may include at least 10 particles, wherein each of the at least 10 particles is in physical contact with at least one other particle. The support particles and their associated catalyst particles may be dispersed in a binder.

This titanium base material has a base material body formed of titanium or a titanium alloy, in which a Magneli phase titanium oxide film formed of a Magneli phase titanium oxide represented by a chemical formula TinO2n-1 (4≤n≤10) is formed on a surface of the base material body. Here, the Magneli phase titanium oxide film preferably contains at least one or both of Ti4O7 and Ti5O9.

An anode for alkaline water electrolysis includes a conductive substrate having at least a surface made of nickel or a nickel-base alloy and a lithium-containing nickel oxide catalytic layer formed on a surface of the substrate. The molar ratio (Li / Ni) of lithium and nickel in the catalytic layer is in the range of 0.005 to 0.15.

Electrochemical device using thin micro-porous metal sheets. The porous metal sheet may have a thickness less than 200 μm, provides three-dimensional networked pore structures of pore sizes in the range of 2.0 nm to 5.0 μm, and is electrically conductive. The micro-porous metal sheet is used for positively and / or negatively-charged electrodes by providing large specific contact surface area of reactants / electron. Nano-sized catalyst or features can be added inside pores of the porous metal sheet of pore sizes at sub- and micrometer scale to enhance the reaction activity and capacity. Micro-porous ceramic materials may be coated on the porous metal sheet at a thickness of less than 40 μm to enhance the functionality of the porous metal sheet. The ceramic coating layer of non-electrical conductivity can function as a membrane separator. The electrochemical device may be used for decomposing molecules and for synthesis of molecules such as synthesis of ammonia from water and nitrogen molecules.

Highly effective, standalone gas-diffusion electrodes (GDEs) and the methods for their manufacture and test are disclosed, Nanocataiysis are directly bonded on a gas diffusion layer, so that the integrity of the catalyst layer holds without polymer electrolyte membrane, facilitating minimization of electronic, prottmtc, and diffusion resistances in the catalyst layer. The devised embodiments provide examples showing a facile hanging-strip method for testing the standalone GDEs in a solution electrochemical cell, which removes the mA-cm−2-scale mass transport limited currents on rotating disk electrodes to allow studies of reaction kinetics on single electrode over sufficiently wide current ranges (up to A cm−2) without mass transport limitation. Ultralow-Pi-content GDEs are fabricated as the cathode for hydrogen evolution in water eiectrolyzers and as the anode for hydrogen oxidation in hydrogen fuel cells. High performance GDEs with low loadings of platinum group metals are being developed for oxygen evolution reaction at the anode of water electrolyzers and for the oxygen reduction reaction at the cathode of fuel cells.

An electrolytic electrode having an interlayer having more excellent peeling resistance and corrosion resistance and longer electrolytic life than conventional electrolytic electrodes and capable of flowing a large amount of current at the industrial level and a process of producing the same are provided. The electrolytic electrode includes a valve metal or valve metal alloy electrode substrate on the surface of which is formed a high-temperature oxidation film by oxidation, and which is coated with an electrode catalyst. The high-temperature oxidation film is integrated with the electrode substrate, whereby peeling resistance is enhanced. Further, by heating the high-temperature oxidation film together with the electrode catalyst, non-electron conductivity of the interlayer is modified, thereby making it possible to flow a large amount of current.

A hydrogen generation system comprising a solid fuel that reacts with an aqueous liquid to generate hydrogen is disclosed. The solid fuel comprises first metallic particles coated by smaller second metallic particles, such that multiple galvanic cells are formed on a surface of the first metallic particles between the metals in the first metallic particles and the second metallic particles. The first metallic particles can be further covered by smaller third particles. An example of the solid fuel is hybrid particles formed by larger magnesium particles coated by smaller iron and silicon particles. The solid fuel may also include salt such as sodium chloride and / or a fire retardant such as potassium chloride. The salt may be added to the aqueous liquid instead. The solid fuel can be formed into fuel pellets, or can be suspended in a suspension agent to form slurries or gels.

There are provided an apparatus and a method for manufacturing a vitreous silica crucible which can prevent the deterioration of the inner surface property in the manufacturing process of a vitreous silica crucible. The apparatus includes a mold defining an outer shape of a vitreous silica crucible, and an arc discharge unit having electrodes and a power-supply unit, wherein each of the electrodes includes a tip end directed to the mold, the other end opposite to the tip end, and a bent portion provided between the tip end and the other end.

The present disclosure relates to nanocomposites of CuO / Cu2O and continuous flow solar reactors. The nanocomposites can be utilized as a photocatalyst and can be incorporated into photoelectrochemical devices. The described devices, systems, and methods can be used for converting CO2 into one or more alcohols and other small organics with the use of solar energy and electricity. Other embodiments are described.