A surface-modified fibrous material is provided for incorporation in a thermoplastic matrix to form a fiber-reinforced composite article. Good binding between the fibrous material and the thermoplastic matrix is achieved through the presence of finely roughened surfaces on the fibers of nanoparticles of an inorganic material. Such nanoparticles are provided from an alkaline aqueous size composition containing the nanoparticles dispersed therein (as described). The fibrous material may be provided in continuous or discontinuous form. In a preferred embodiment glass fibers are initially provided in continuous form followed by cutting into discontinuous lengths and drying with the retention of the nanoparticles on the surfaces of the fibers. The surface-roughened fibrous material is incorporated in a thermoplastic matrix as fibrous reinforcement with the application of heat whereby the thermoplastic matrix is rendered melt processable. In preferred embodiments injection or compression molding is utilized. Improved long-fiber thermoplastics also may be formed to advantage.
A textilesize composition is prepared from modified starch (20-90%) and specia nano material (0.05-5%) which is chosen any one of SiO2, TiO2, Al2O3 and ZrO2. Its advantages are high stability, shortdissolving time and high effect of benefiting weaving.
A sizing composition for reinforcement fibers that includes one or more film forming agents, a silanecoupling agent package, and at least one lubricant surfactant is provided. Optional components such as rheology modifiers, fillers, biocides, and pH modifiers may also be included. Preferred film forming polymers are amide-based polymers. Additionally, the sizing composition is free of polyvinyl alcohol. The absence of polyvinyl alcohol in the size composition reduces or eliminates the production of precipitates from white water in wet-laid processes. The size composition is applied to reinforcement fibers and formed into chopped strand, wet-laid mats that can be used for a variety of purposes, including roofing products. Chopped strand mats formed from fibers sized with the inventive sizing composition maintains or improves the dry tear and tensile strengths compared to chopped strand mats made from fibers sized with a commercial sizing composition that does not contain polyvinyl alcohol.
A sizing composition and method for manufacturing such, which is suitable for use in manufacturing fiber-reinforced composites which have desirable properties such as high strength, high resistance to water and chemical degradation, and improved coloring. This is achieved in part by good adhesion of the sizing composition to the reinforcing fibers and the polymer matrix. The sizing composition includes an emulsion having a grafted polyolefin, two or more saturated fatty acids, and one or more silanecoupling agents. When reinforcing fiber materials sized according to the invention are used in a molding process, the resulting composites are observed to show minimal discoloration.
The invention relates to a manufacturing method of a sandstone oilfield whole rock mineral simulated core. The manufacturing method is as follows. Firstly, required mineral raw materials are weighted quantitatively according to the component content, the size composition and the physical parameters of the sandstone oilfield blocks, and the is evenly mixed and sieved. Then, prepared cementing agent and the well mixed mineral raw materials are proportionally prepared, and are fully well mixed and sieved. Under the conditions of 6MPa-22MPa manufacturing pressure and 5min-10min manufacturing time, the solid-liquid mixture after sieving is made into simulated core through a fixing die forming method. The simulated core is dried under the temperature-changing with time-fixing conditions. The drying temperature with consumed time is from 40 degrees Celsius with 8 hours, 80 degrees Celsius with 16 hours, 120 degrees Celsius with 8 hours, 160 degrees Celsius with 16 hours to 200 degrees Celsius with 8 hours. The method is simple, safe and easy to be operated. The manufactured simulated core is equipped with not only the pore throat characteristics and seepage properties of a natural core, but also the sensitive properties of the natural core.