The present invention relates to a method for synthesizing a
electron-
ion mixed conducting material with a K2NiF4 structure of the La2-xSrxNi1-yMeyo4+
delta system. The
carbonate or
hydroxide of various component elements is mixed with
diethylenetriamine pentaacetic acid in deionized water according to the stoichiometric ratio of synthetic product, the mixture is heated and agitated so that the
carbonate or
hydroxide is dissolved completely to form clarifying and transparent solution of precursor, and then the transparent glass state
aminopolycarboxylic acid complexes precursor is obtained by means of heating and
drying; finally, the complexes precursor is heated to create the ultramicro composite
powder with single K2NiF4 structure. The present invention has a simple synthesizing technology, a low synthesizing temperature, a short synthesizing time, a controllable synthesizing process, and an excellent
repeatability. The synthetic product has a high
phase purity, fine and uniform particles, and can be widely used as the
cathode of
moderate temperature solid oxide fuel battery, and used for the electrochemical sensor and the
oxygen separation membrane, and has a broad application prospect.