The invention relates to a method for zinc protoporphyrin promoted catalyzed oxidation of cycloalkanes. The method comprises the following steps: mixing the cycloalkanes, a main catalyst and a cocatalyst, carrying out a reaction for 2 to 48 hours under the condition that the temperature is 100 DEG C to 160 DEG C and the O2 pressure is 0.8MPa to 2MPa, then, subjecting a reaction solution to aftertreatment, thereby obtaining oxidation products, i.e., alkyl diacid, cycloalkyl alcohol and cycloalkyl ketone. According to the novel method for catalyzed oxidation of the cycloalkanes, provided by theinvention, the selectivity of the oxidation products is high, the reaction temperature is low, and the consumption of catalysts is low; O2 serves as an oxidant, so that the method is environmentally friendly, and the catalyzed oxidation of the cycloalkanes is achieved in a high-selectivity manner; the novel method for catalyzed oxidation of the cycloalkanes further has the advantages that the operation is simple, no organic solvent is used, and the like.