A battery is provided with a hexacyanometallate
cathode. The battery
cathode is made from hexacyanometallate particles overlying a
current collector. The hexacyanometallate particles have the
chemical formula AXM1MM2N(CN)Z.d[H2O]ZEO.e[H2O]BND. where A is a
metal from Groups 1A, 2A, or 3A of the
Periodic Table, where M1 and M2 are each a
metal with 2+ or 3+ valance positions, where “ZEO” and “BND” indicate zeolitic and
bound water, respectively, where d is 0, and e is greater than 0 and less than 8. The
anode material may primarily be a material such as hard carbon, soft carbon, oxides, sulfides, nitrides,
silicon, metals, or combinations thereof. The
electrolyte is non-aqueous. A method is also provided for fabricating hexacyanometallate with no zeolitic
water content in response to
dehydration annealing at a temperature of greater than 120 degrees C. and less than 200 degrees C.