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59 results about "Formaldehyde product" patented technology

Formaldehyde is a colorless chemical compound released during the process of chemical combustion. It is also an ingredient widely used in the manufacturing business. There are many formaldehyde products, made for both indoor and outdoor use. One of the most common uses of formaldehyde products is in building materials.

Colour development methyl aldehyde adsorption material and preparation method thereof

The invention discloses a chromogenic formaldehyde adsorbing material and a preparation method thereof. The adsorbing material consists of a carrier, a high molecular organic amine polymer, a polylol polymer and a formaldehyde reaction indicator, wherein the high molecular organic amine polymer and the polylol polymer account for 1 to 50 percent of formaldehyde adsorbent, the formaldehyde reaction indicator is little, and the balance being the carrier. The preparation method thereof comprises the following steps: mixing the high molecular organic amine polymer and the polylol polymer according to mass, adding deionized water to dilute the mixture so as to prepare formaldehyde reagent; mixing the formaldehyde reagent and the formaldehyde reaction indicator; and spraying or dipping the mixed solution onto the surface of the carrier, and drying the carrier and so on. The adsorbing material and the preparation method can quickly, thoroughly and continuously remove formaldehyde pollution in indoor air until the content of the formaldehyde is reduced to safe concentration, are nontoxic, pollution-free, safe and environment-friendly to use, and can intuitively show the reaction degree of the formaldehyde.
Owner:718TH RES INST OF CHINA SHIPBUILDING INDAL CORP

Benzaldehyde preparation method

The invention discloses a natural benzaldehyde preparation method. According to the invention, one oxide or two or three composite oxides from V, Ti, Ag, Ba, and Mg can be taken as a catalyst, O2 or air is introduced as an oxygen source, cinnamaldehyde is atomized through compressed air or oxidation, and then is introduced into a fixed bed reactor, a gas-solid phase catalysis continuous reaction is carried out under normal pressure at the temperature of 120-200 DEG C, a product continuously passes through a molecular distillation apparatus, molecular distillation is carried out at the temperature of 60 DEG C under 100 Pa, and the natural benzaldehyde product is obtained. The natural benzaldehyde preparation method has the advantages of simple and novel process, simple operation, no requirement of solvent, simple separation, and fast reaction rate, excessive oxidation of cinnamaldehyde is prevented, a reaction process is environmentally friendly, the natural degree of benzaldehyde is good, and the product purity is high.
Owner:GUANGXI UNIV

Apparatus and method to co-produce formaldehyde and UFC (urea-formaldehyde concentrate) by iron-molybdenum process

An apparatus to co-produce formaldehyde and UFC (urea-formaldehyde concentrate) by iron-molybdenum process comprises a methanol evaporator, a methanol oxidizer and an absorbing column; fresh air and methanol vapor are mixed in the methanol evaporator, and formaldehyde is generated in the methanol oxidizer; formaldehyde vapor enters the absorbing column via the methanol evaporator; in the absorbingcolumn, the formaldehyde vapor is liquefied, and a liquid formaldehyde product is attained from the bottom; urea and an alkali liquid are added into the absorbing column to react with the formaldehyde to obtain UFC. The apparatus has the advantages that consumption indexes are good, single consumption of formaldehyde is 0.422-0.426 t, byproduct vapor specification is high, up to 22 bar 0.75 t / t,oxidation temperature is controlled to 245-380 DEG C, the methanol oxidizer has designed life up to 20 years and longer, the whole apparatus has designed life of not shorter than 35 years, the apparatus is suitable for flexibly producing formaldehyde products having a concentration of 37-55%, UFC can be produced just by proportionally adding an alkali liquid, and in order to further increase absorbing efficiency of process water, sodium hydroxide solution can be injected into the system to remove the byproduct, formic acid.
Owner:江苏道尔顿石化科技有限公司

New process for producing glyoxal by using complex silver catalyst to oxidize glycol

The invention relates to a new process for producing glyoxal by using a complex silver catalyst to oxidize glycol. The process comprises the following steps: adopting a high-pressure steam-spraying and far-infrared combining heating mode to gasify glycol; uniformly mixing the gasified glycol, steam, preheated filtrated air and circulating air in a tertiary mixer before entering a grid-type oxidation furnace integrated with a feed gas-purifying and refining device and filled with an Ag-P-Se / ceramic catalyst; carrying out a catalytic oxidation reaction; rapidly quenching the reacted gas; sendingthe gas to an absorption tower for repeated absorption; and decoloring the gas to obtain a glyoxal product. The process uses the Ag-P-Se / ceramic catalyst with strong activity and has high glyoxal yield up to 85 percent and small impurity formaldehyde product; a grid-type supporting plate overcomes the defects of easily deformed and crack catalyst bed and decreases the resistance of the bed; and the process integrates the purifying and refining device and the oxidation furnace and adopts the high-pressure steam-spraying and far-infrared combining heating mode to gasify the glycol to save energy and shorten the process flows.
Owner:HUBEI HONGYUAN PHARMA +1

Device for continuous production of melamine-formaldehyde resin

The invention discloses a device for continuous production of melamine-formaldehyde resin, and belongs to the technical field of chemical equipments. The device comprises a mixture bin, a material pump, a first screw machine, a static mixer and a second screw machine which are connected in sequence, wherein the mixture bin is connected with a melamine high-order bin and a paraformaldehyde high-order bin respectively, an alkali liquor feed inlet is formed in the feed end of the first screw machine, and auxiliary material feed inlets are formed in the feed end, the middle end or the tail end of the first screw rod. The production device disclosed by the invention is high in utilization rate of raw materials, low in energy consumption, high in yield, free of three wastes (waste gases, waste water and waste residues) in the production process of the melamine-formaldehyde resin, and can continuously produce the melamine-formaldehyde resin with stable quality, and furthermore, melamine-formaldehyde resin products are good in quality.
Owner:郑州峰泰纳米材料有限公司

Novel method for concentration-improving alcohol removing of alcohol-containing thin formaldehyde solution

The present invention discloses a novel method by concentrating the diluted formaldehyde solution containing alcohol and eliminating the alcohol, belonging to the technological field of the concentration and elimination of the alcohol of the diluted formaldehyde solution containing alcohol; the diluted formaldehyde solution containing alcohol with the alcohol of 0.5 to 15 percent and the aldehyde of 1 to 30 percent is sent into the pressurization and rectification tower for rectification; the product with the formaldehyde concentration of 1.5 to 65 percent can be got on the top of the pressurization and rectification tower; the product on the bottom of the tower is the organic wastewater; the products on the top of the pressurization and rectification tower are sent to the heat exchanger and are cooled to be at the temperature between 80 and 120 DEG C; then the products are sent to the alcohol-doffing tower for the continuous rectification; the methanol solution with the concentration of 40 to 80 percent can be got on the top of the alcohol-doffing tower; the formaldehyde solution with the concentration of 2 to 67 percent can be got on the bottom. The present invention is of the large output and the high rectification efficiency; the formaldehyde can be diluted to have the concentration of the conventional formaldehyde product; at the same time, the separated methanol can be recycled used for the formaldehyde production and so on.
Owner:ZHEJIANG SANPO POLYMER

Environmental-protection cleaning technology for producing hydrocyanic acid derivatives by comprehensive utilization of coke oven gas

The invention provides an environmental-protection cleaning technology for producing hydrocyanic acid derivatives by comprehensive utilization of coke oven gas. The environmental-protection cleaning technology is characterized in that 1, through the environmental-protection cleaning technology, coke oven gas is processed into relatively concentrated methane gas having relatively-low quality requirements by separation processes of pressure swing adsorption and the like, and the methane gas as a raw material is used for production of hydrocyanic acid derivatives; and 2, the environmental-protection cleaning technology concretely comprises the following steps that coke oven gas is separated by the separation processes of pressure swing adsorption and the like so that methane gas, hydrogen, carbon monoxide and tail gas are obtained; methane gas is synthesized into hydrocyanic acid mixed gas by ammonium oxidation or ammoniation dehydrogenation, and the hydrocyanic acid mixed gas reacts with a sodium hydroxide aqueous solution to produce sodium cyanide for synthesis of downstream hydrocyanic acid derivatives, or the hydrocyanic acid mixed gas and formaldehyde or other aldehydes are synthesized into hydroxyacetonitrile or other derivatives for synthesis of downstream hydrocyanic acid derivatives, or the hydrocyanic acid mixed gas is absorbed by water or other solvents and the solution is purified into high-purity hydrocyanic acid for synthesis of downstream hydrocyanic acid derivatives; hydrogen is used for synthesis of ammonia; and carbon monoxide and tail gas are used for synthesis of methanol and the synthesized methanol can be further oxidized into a formaldehyde product.
Owner:李宽义

Method for producing ultralow-acid formaldehyde

The invention relates to a method for producing ultralow-acid formaldehyde. The method comprises the following steps: a, pumping 37% formaldehyde obtained by a catalytic oxidation reaction into a first anion exchange resin adsorption tower, adsorbing formic acid in the 37% formaldehyde by using weakly basic anion exchange resin in the first anion exchange resin adsorption tower, and conveying thefinished formaldehyde product obtained after the adsorption into a formaldehyde storage tank; b, timely switching a transfer pump to a second anion exchange resin adsorption tower (2) when the detected acid content of formaldehyde is equal to or more than 0.005%, continuously adsorbing the formic acid in the 37% formaldehyde by the weakly basic anion exchange resin, and conveying the finished formaldehyde product obtained after the adsorption into the formaldehyde storage tank; and c, regenerating the first anion exchange resin adsorption tower by a 3-5% NaOH solution in a forward flow manner,washing the first anion exchange resin adsorption tower with desalinated water, and continuously putting the regenerated first anion exchange resin adsorption tower into production and use. The method has the advantages of continuousness in production of the ultralow-acid formaldehyde, and meeting the needs of the market.
Owner:ANHUI JINGHE IND

Flame-retardant textile and flame-retardant adhesive for flame-retardant textile and preparation method of flame-retardant adhesive

The invention discloses a flame-retardant textile and a flame-retardant adhesive for the flame-retardant textile and a preparation method of the flame-retardant adhesive. The flame-retardant adhesive is prepared from a waterborne white modified emulsion, a water-soluble polymer thickener, a foaming agent, a foam stabilizer, zinc borate, a halogen-free phosphorous nitrogen ammonia-based flame-retardant powder and softened water; the method comprises the steps of weighing a certain amount of softened water and waterborne white modified emulsion in a stirring tank; fully stirring, sequentially adding the foaming agent and the foam stabilizer; weighing the zinc borate, slowly and uniformly adding the halogen-free phosphorous nitrogen ammonia-based flame-retardant powder to a mixture, and stirring while adding; and adding the water-soluble polymer thickener, fully stirring, filtering and discharging to obtain the flame-retardant adhesive. By adopting the halogen-free phosphorous nitrogen ammonia-based flame-retardant powder, the flame-retardant adhesive does not contain halogen and does not cause secondary pollution to the air environment during combustion; since no formaldehyde is added, a product is more environment-friendly; the zinc borate plays a flame-retardant synergistic role as an auxiliary flame retardant; and the flame-retardant adhesive has the advantages of being simple in preparation technology, good in use effect and low in cost.
Owner:青岛博时阻燃织物有限公司

Method for producing formaldehyde and urea formaldehyde pre-concentrated liquid on super-large scale

The invention relates to a method for producing a formaldehyde and urea formaldehyde pre-concentrated liquid. The method comprises steps as follows: S101: methanol is gasified and mixed raw gas is obtained; the mixed raw gas contains methanol with the concentration being 6%-11%, oxygen with the concentration being 9%-13% and the balance of inert gas; S102: the raw gas is sent into a reactor and subjected to a reaction at the temperature of 200-400 DEG C under the action of an iron-molybdenum catalyst; S103: a reaction product is sent into an absorption system to be absorbed by a preset solution, and the formaldehyde or urea formaldehyde pre-concentrated liquid is obtained finally. The provided process for producing oxidation-method (namely, an iron-molybdenum method) formaldehyde on a super-large scale has the outstanding advantages of being high in conversion rate, yield, product concentration and energy recovery degree, excellent in product quality, free of liquid wastes and solid wastes during normal production and the like and is particularly suitable for demands of the large modern chemical industry, the dilemma of extended monopoly of abroad iron-molybdenum method formaldehyde processes is thoroughly broken through, and the blank of the independent intelligent property right of the process in China is filled up.
Owner:赵达扬 +1

Low-conversion-rate high-yield formaldehyde production technology and device thereof

The invention relates to the field of formaldehyde production technology, in particular to a low-conversion-rate high-yield formaldehyde production technology and device thereof. Reaction of ternary mixture with excessive methanol under action of catalyst is completed by controlling proportion of methanol in the ternary mixture, generated formaldehyde gas and other gases are cooled suddenly and fed into a primary absorption tower to be absorbed through process water, methanol-contained formaldehyde solution acquired from the primary absorption tower enters a first methanol removing device to be heated, methanol is removed in a gaseous state, the formaldehyde solution with methanol removed is used as finished formaldehyde products to be stored, the gaseous methanol removed by the first methanol removing device still contains formaldehyde in a small quantity so as to be fed into a secondary absorption tower to be absorbed and enter a second methanol removing device for removing methanol again, and the removed gaseous methanol enters a flame-retardant filter to enter a formaldehyde production system again for recycling reaction. The low-conversion-rate high-yield formaldehyde production technology has the advantages of low conversion rate, fewer negative reactions, low oxygen temperature control, long lifetime of catalyst, high yield and low material consumption.
Owner:JIANGSU KAIMAO PETROCHEM TECH

Energy-saving formaldehyde production system

The invention relates to an energy-saving formaldehyde production system which comprises an evaporator, a gas mixer, an oxidizing reaction tower, a steam separation tower, an adsorption tower and a tail gas recycling device. The evaporator is connected with the gas mixer, the gas mixer is connected with a steam source, an outlet of the gas mixer is connected with a steam inlet of the oxidizing reaction tower, and a steam outlet of the oxidizing reaction tower is connected with a steam inlet of the steam separation tower. A steam exhaust port of the steam separation tower is connected with an inlet of the adsorption tower, a tail exhaust port of the adsorption tower is connected with a tail gas recycling device, and the steam separation tower comprises a tower body. The upper portion in the tower body is provided with at least one piece of metal regular filler through a frame, a liquid suction disc is arranged on the lower portion of the metal regular filler, and a water circulating cooling pond is arranged on the lower portion of the liquid suction disc. A large amount of steam in a formaldehyde gas mixture can be effectively removed through the steam separation tower, and therefore the mass concentration of produced formaldehyde products can be effectively improved.
Owner:TIANJIN FORINT TRANSCENDENTAL TECH DEV CO LTD

Method for preparing concentrated formaldehyde from low-formaldehyde-content materials

The invention relates to a method for preparing concentrated formaldehyde from low-formaldehyde-content materials. The method includes steps: (1) adding methyl alcohol into the low-formaldehyde-content materials, and performing reaction under the catalysis action of a heteropolyacid catalyst to obtain dimethoxymethane; (2) subjecting dimethoxymethane obtained at the step (1) to catalytic oxidation to obtain products including concentrated formaldehyde, wherein a concentrated formaldehyde product being 65-66wt% in concentration is obtained finally, and the formaldehyde recovery rate in the whole process is 97% or above. The method has advantages that special equipment for concentrating of dilute formaldehyde into concentrated formaldehyde is not needed, so that cost saving and energy consumption reduction are realized; circulation of dilute formaldehyde in a device is realized, independence from production by-products such as dimethoxymethane, urotropin or the like is realized, and COD level of wastewater and wastewater treatment cost are reduced.
Owner:江苏道尔顿石化科技有限公司

Zero-aldehyde adhesive for plywood and preparation method of zero-aldehyde adhesive

The invention relates to the technical field of plywood, in particular to a zero-aldehyde adhesive for plywood and a preparation method of the zero-aldehyde adhesive. The zero-aldehyde adhesive for plywood comprises the following components in parts by weight: 10-20 parts of water glass, 5-15 parts of a promoter, 20-30 parts of sodium alginate, 10-20 parts of gelatin, 3-5 parts of sodium fluosilicate, 5-10 parts of a halogen-free flame retardant and 20-30 parts of cationic water. The adhesive is good in viscosity, does not contain formaldehydes products, does not release formaldehyde, methylbenzene, xylene or the like, and can reach fireproof A2 level; and poisonous gas or smoke is not discharged.
Owner:临沂绿醛胶业有限公司
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