The invention discloses an electrodynamic method for removing
fluorine contaminant in soil, which is as follows: an anion-exchange membrane is arranged between the
anode and the contaminated soil to prevent the H+ generated by the
anode from entering the electrolyzer so as to avoid the increase of the acidity of the contaminated soil;
sodium acetate solution is put in an
anode chamber to be used as
electrolyte, deionized water is put in a
cathode chamber to be used as
electrolyte, and the liquid levels of the anode chamber and the
cathode chamber are maintained to be parallel; in the rehabilitating process, the electrolytes circulate constantly to be stirred evenly so as to bring away the H2 and O2 which are generated by the anode and the
cathode; the
sodium acetate solution added in the anode chamber supplies OH- which neutralizes the H+ generated by the anode, and the surplus OH- and the OH- generated by the cathode promote the adsorbed
fluorine in the soil to be desorbed to be free fluorinions; and the
fluoride in the soil is removed through the electrodynamic approaches of
electromigration, electroosmosis and the like. The method can effectively promote the adsorbed
fluoride to be desorbed from the surface of the contaminated soil particles, remarkably improves the
fluorine contaminant removal efficiency, reduces
overpotential and saves
energy consumption, and after the soil is rehabilitated, the pH value of the soil is basically maintained at the original state.