The invention relates to a preparation method of low-molecular-weight
halogen flame-retardant
polycarbonate, which is characterized by comprising the following steps: a. adding polyhalo
bisphenol A into a
sodium hydroxide solution-
haloalkane mixed
system, completely dissolving by stirring at normal temperature, and meanwhile, adding a catalyst; b. introducing
phosgene, meanwhile, dropwisely adding a
sodium hydroxide solution to keep the pH value of the
system at 7-14, and carrying out prepolymerization reaction at 0-20 DEG C for 0.2-1.5 hours; c. increasing the
reaction temperature to 10-40 DEG C, adding a blocking agent, and meanwhile, dropwisely adding a
sodium hydroxide solution to keep the pH value of the
system at 7-14; d. after the reaction finishes, standing to stratify to obtain an organic phase, adding
fatty alcohol, washing to obtain a white
solid, filtering, and
drying to obtain the product. By strictly controlling the prepolymerization and
polycondensation reaction temperatures and the pH value of the
reaction system, the synthesized product has small fluctuation of the molecular weight, and the molecular weight can be fixed within a certain range. The synthesis technique has the advantages of short period, simple operating technique and high efficiency.