The invention discloses a combination device for physicochemical treatment of black liquid. The combination device comprises
chemical storage tanks, chemical feed tanks, an oxygenolysis bin, a coagulation polycondensation bin, a
dehydration separator bin, a turning
slag extractor bin and a clear water recycle bin all integrated. The oxygenolysis bin is connected with the coagulation polycondensation bin, a set of
chemical storage tank and chemical
feed tank are arranged at upper part, the oxygenolysis bin and coagulation polycondensation bin are be provided with a separating plates, with the lower parts being communicated, each bin is divided into two chambers, each chamber is provided with a set of stirring device, and the liquid is fed and discharged at the upper part. The coagulation polycondensation bin is connected with the
dehydration separator bin, which is provided with a micro-filtering dehydrator at the upper part and with a water tank
water pipe communicating with the clear water recycle bin at the lower part, the upper dehydrator communicates with the turning
slag extractor bin, which is provided with a moving board for
sludge discharge and connected with the clear water recycle bin, and a clear water bin is provided with a sloped tube
sediment layer for
sedimentation to obtain clear water and
discharge into a
water storage tank. The combination device adopts a black liquid lifting pump and chemical liquid, to rapidly decompose nano-
lignin and perform polycondensation to obtain bulk-shaped
solid substance with no
viscosity, high
dehydration speed and efficiency, chemical
oxygen consumption removal up to 95% and chroma removal up to 98%. The combination device has reasonable design, high device integration level, small floor area, energy saving and environment friendliness, and can be matched with alkali
recovery process to trap diluted black liquid for physicochemical treatment, and realize zero
discharge of black liquid.