The invention relates to a novel ceramic ink-jet ink and a production process thereof. The novel ceramic ink-jet ink is prepared from the following components by percentage by weight: 38%-42% of water-soluble metal salt, 7%-9% of a complexing agent, 14%-25% of a surfactant, 29%-34% of a water-soluble organic solvent, 1%-4% of an auxiliary material and 0.05%-0.1% of a pH value regulator. The novel ceramic ink-jet ink has strong stability, the influences caused by other substances such as solvents are small, the solubility range is relatively wide, the liquidity and the color development property are stable, and the pH value is neutral, so that the corrosion damage caused to a spray head is avoided; the novel ceramic ink-jet ink can directly infiltrate by 5mm-10mm into a tile blank, infiltration color development is formed, and the infiltration effect is good; the color development effect of metal salt is rich and stable, and after novel ceramic ink-jet ink infiltrates into the surface of a tile, the color is relatively fine and bright; the novel ceramic ink-jet ink can be subjected to 1260 DEG C high-temperature sintering with the tile blank, can meet the high-temperature sintering requirements of the tile blank and can reach Moh's hardness 6-7, and the hardness is obviously improved; lots of water grinding fineness processes are not required, the machining process is relatively environmentally friendly, and the energy consumption is relatively low.