The invention provides an alkali metal thermo-electric direct converter, which comprises an exhaust tube (1), a supporting seat (2), an upper cover (3), a condenser (4), a condenser sealing cover (5), an upper cavity I (6), a capillary core (7), an upper cavity II (8), a base (9), a capillary core nut (10), a lower cavity I (11), a lower cavity II (12), an exhaust tube nut (13), a capillary core base (14), a lower cover (15) and a ceramic base I (16). The alkali metal thermo-electric direct converter is an energy conversion device in the field of power energy conversion and renewable energy utilization, and uses a BASE (beta''-Al2O3 solid electrolyte) selective permeable membrane, namely the beta'-Al2O3 is an excellent conductor of ions, and by using the characteristics of defective conductors of electrons and atoms, the heat energy absorbed by the alkali metal steam is converted into electric energy to be used by users.