The invention provides a dental self-acid etching adhesive with a remineralization effect, and a preparation method thereof. The dental self-acid etching adhesive comprises 8.0-10.5% of a resin matrix, 5-7% of an acid releasing agent, 0.7-1.2% of a photoinitiator, 2.8-4.1% of a remineralization component and the balance of auxiliary materials. According to the self-acid-etching adhesive, the remineralization component is added into the self-acid-etching adhesive and has a synergistic effect with the acid releasing agent, so that remineralization of dentin is realized on the basis of reducing dentin sensitivity, and tooth allergy caused by dentin exposure due to excessive acid etching or mechanical damage in the use process of the self-acid-etching adhesive can be avoided; meanwhile, dentin remineralization can be continuously guided for a long time, and dentin hypersensitivity can be prevented for a long time. On the one hand, the self-acid-etching adhesive does not contain fluoride, the product is safer, on the other hand, the self-acid-etching adhesive is a single-bottle self-acid-etching adhesive, the chemical stability is good, the bonding strength is high, and the ideal effect can be achieved when the self-acid-etching adhesive is used in cooperation with dental materials such as pit and fissure sealing agents.