The invention discloses a method for extracting monomeric EGCG from fresh tea, belonging to the technical field of chemistry of natural products. The method comprises the following concrete steps: S1, soaking; S2, centrifugation; S3, primary adsorption; S4, MVR concentration; S5, CF filtration; S6, secondary adsorption; S7, concentration; S8, rinsing; S9, dehydration; S10, drying; and S11, deironing. According to the invention, fresh tea is used as a raw material; the disadvantages of easy pasting and uneasy filtration during extraction of crushed and sieved dry tea at a high temperature in the prior art is overcome; purified water is used as a medium for direct separation of EGCG monomer, and leaching of a plurality of fat-soluble pesticides is reduced; in the process of purification, an LX-8 resin is used for adsorbing EGCG, and an HZ818 resin is used for adsorbing caffeine; crystallization, rinsing and drying are carried out so as to obtain the EGCG monomer; the obtained EGCG monomer is off-white or white powder, and yield of the monomer reaches about 99%. The method has the advantages of simple operation, high separation efficiency, low cost, a short production period and high product purity and is suitable for industrialized large-scale production.