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A method for preparing 2,3,3,3-tetrafluoroprop-1-ene comprising (a) providing a starting composition comprising at least one compound having a structure selected from Formulae I, II and III:CX2═CCl—CH2X  (Formula I)CX3—CCl═CH2  (Formula II)CX3—CHCl—CH2X  (Formula III)wherein X is independently selected from F, Cl, Br, and I, provided that at least one X is not fluorine;(b) contacting said starting composition with a first fluorinating agent to produce a first intermediate composition comprising 2-chloro-3,3,3-trifluoropropene and a first chlorine-containing byproduct; (c) contacting said first intermediate composition with a second fluorinating agent to produce a second intermediate composition comprising 2-chloro-1,1,1,2-tetrafluoropropane and a second chlorine-containing byproduct; and (d) catalytically dehydrochlorinating at least a portion of said 2-chloro-1,1,1,2-tetrafluoropropane to produce a reaction product comprising 2,3,3,3-tetrafluoroprop-1-ene.

A farm implement for applying a product to a row crop or a row seeded field wherein the implement has a plurality of spaced-apart product dispensers mounted thereon, each of which is individually automatically controlled. The rate of product being dispensing from each of the product dispensers is automatically operated dependent upon the ground speed of the individual product dispensers or dependent on other criteria.

A no-till drill with a novel walking beam assembly that allows the drill to be pulled over severe terrain conditions that include large rocks, fallen limbs and other large obstructions. The inventive walking beam assembly includes two independent pivot points that allow the cutting and opening disks to maintain substantially constant or continuous contact with the ground, such that the length of the furrow formed and seed deposited therein are maximized. A closing disk assembly is suspended from the rear of the drill independently from the walking beam assembly. This independent suspension allows the walking beam assembly to function without interference from the closing disks.

Processes for producing hydrocarbons in the gasoline and jet fuel range. The processes involve the thermal decarboxylation of fatty acids, which can be derived from the hydrolysis of triglycerides, which triglycerides can be vegetable oils, animal fats, or combinations thereof. The resulting hydrocarbons can be hydrocracked, and, optionally, isomerized and / or hydrotreated, to yield hydrocarbons in the jet fuel or gasoline range. Where the resulting hydrocarbons include olefinic double bonds, they can alternatively be combined with low molecular weight olefins, and subjected to olefin metathesis to yield hydrocarbons in the jet fuel or gasoline range.

In at least one embodiment of the present invention, a method for producing liquid hydrocarbons from biomass is provided. The method comprises pyrolizing the biomass with hydrogen (H2) to form bio-oil. The bio-oil comprises alkanes, alkenes, alcohols, aldehydes, ketones, aromatics, hydrocarbons or mixtures thereof. The H2 is formed from a carbon-free energy source.

A process for isomerization dewaxing of a hydrocarbon feed which includes contacting the hydrocarbon feed with a large pore size, small crystal size, crystalline molecular sieve and an intermediate pore size, small crystal size, crystalline molecular sieve to produce a dewaxed product with a reduced pour point and a reduced cloud point. In a preferred embodiment, the feed is contacted with the molecular sieves sequentially, first with the large pore sieve followed by the intermediate pore sieve.

The present invention provides a process to remove the germ from the endosperm of a corn kernel. The apparatus of the present invention comprises frictional cylindrical rollers, each roller rotating about an axis, the axis of the rollers substantially parallel, and the direction of rotation being opposing. The roller bodies having a rubberized covering, rotate with differing surface velocities and are tensioned such as to impart low-impact friction forces to corn kernels drawn between the roller covers. The process of the present invention includes a tempering step comprising adding an amount of moisture to the corn by wetting and soaking the corn; a polishing step for removing bran layers from the corn; a second tempering step comprising adding an additional amount of moisture to the corn by wetting and soaking the corn; and a friction step to remove germ from the endosperm.